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상호확산법에 의한 (Ti , Al)N계 복합질화물의 합성
이영기,김정열,김동건,손용운 ( Young Ki Lee,Jung Yeul Kim,Dong Kun Kim,Yong Un Sohn ) 한국열처리공학회 1997 熱處理工學會誌 Vol.10 No.2
TiN and AlN are ceramic materials with extensive applications due to its excellent mechanical and chemical properties at elevated temperature. The purpose of this research is to develop the method for the synthesis of ternary nitride powder, titanium-aluminum-nitrogen system, which have an excellent property of both TiN and AlN. The ternary nitride such as Ti₃AlN, Ti₂AlN and Ti₃Al₂N₂can be synthesized by the interdiffusion nitriding method in Ar gas, however, the ternary nitride coexist with TiN, AlN, Ti₃Al and α-Ti. The ternary nitride are stable below 1400℃ but these are gradually decomposed into TiN, Ti₃Al and AlN above 1400℃. The thermal oxidation characteristics of the Ti-Al-N compound synthesized by the interdiffusion nitriding method is superior to that of the TiN+AlN mixed powder, and the oxidation for both materials show the differential behaviors.
이영기,손용운,조영수,김용석,김석윤 ( Young Ki Lee,Yong Un Sohn,Young Soo Cho,Yong Seog Kim,Suk Yoon Kim ) 한국열처리공학회 1995 熱處理工學會誌 Vol.8 No.2
The nitridation kinetics of titanium powder were studied by isothermal and non-isothermal (dynamic) methods in high purity nitrogen under 1 atm pressure. For the comparison with nitridation, the oxidation kinetics of titanium powder were also studied in dry oxygen at 1 atm pressure. An automatic recording electrobalance was used to measure the weight gain as a function of time and temperature. For the reaction with nitrogen, the nitride was formed at over 700℃. The reaction with nitrogen followed the parabolic rate law, and the activation energy was calculated to be 31 ㎉/㏖ in the isothermal method (above 900℃). The non-stoichiometric TiNx has been synthesized by the nitridation at a proper temperature and time, followed by the homogenizing treatment above 1100℃. In comparison with the stoichiometric TiN_(1.0) and the non-stoichiometric TiNx(TiN_(0.5) and TiN_(0.65)), the hot oxidation characteristics of the former is superior to that of the latter. However, both non-stoichiometric nitrides make little difference in the hot oxidation characteristics.