Effect of Mesoporous TiO₂ in Facilitated Olefin Transport Membranes Containing Ag Nanoparticles

김상진,정정표,김동준,김종학,Kim, Sang Jin,Jung, Jung Pyu,Kim, Dong Jun,Kim, Jong Hak The Membrane Society of Korea 2015 멤브레인 Vol.25 No.5

용액-확산 메커니즘에 의해 결정되는 기존의 고분자에서와는 달리, 촉진수송은 투과도와 선택도를 동시에 향상시킬 수 있는 기술이다. 본 연구에서는 은 나노입자, 폴리비닐피롤리돈, 7,7,8,8-테트라시야노퀴노디메탄으로 구성된 촉진수송 올레핀 분리막에 있어서, 메조기공 티타늄산화물($m-TiO_2$)에 대한 영향을 연구하였다. 특히 메조기공 티타늄산화물은 폴리비닐클로라이드-g-폴리옥시에틸렌 메타크릴레이트 가지형 공중합체를 템플레이트로 하여 쉽고 대량 생산이 가능한 방법으로 제조하였다. 엑스레이 회절분석에 따르면, 제조된 메조기공 티타늄산화물은 아나타제와 루타일 상의 혼합으로 구성되어 있으며, 결정의 크기가 약 16 nm 정도 되었다. 메조기공 티타늄산화물을 첨가하였을 때, 분리막의 확산도가 증가하여 혼합기체 투과도가 1.6에서 16 GPU로 증가하였고 선택도는 45에서 37로 약간 감소하였다. 메조기공 티타늄산화물이 첨가되지 않은 분리막은 장시간 성능이 유지되었으나, 메조기공 티타늄산화물이 첨가된 분리막의 경우 시간이 지남에 따라 투과도와 선택도가 감소하였다. 이는 티타늄산화물과 은 사이의 화학적 상호작용으로 은 나노입자의 올레핀 운반체로써의 활성을 감소시키기 때문으로 사료된다. Facilitated transport is considered to be a possible solution to simultaneously improve permeability and selectivity, which is challenging in normal polymeric membranes based on solution-diffusion transport only. We investigated the effect of adding mesoporous $TiO_2$ ($m-TiO_2$) upon the separation performance of facilitated olefin transport membranes comprising poly(vinyl pyrrolidone), Ag nanoparticles, and 7,7,8,8-tetracyanoquinodimethane as the polymer matrix, olefin carrier, and electron acceptor, respectively. In particular, $m-TiO_2$ was prepared by means of a facile, mass-producible method using poly(vinyl chloride)-g-poly(oxyethylene methacrylate) graft copolymer as the template. The crystal phase of $m-TiO_2$ consisted of an anatase/rutile mixture, of crystallite size approximately 16 nm as determined by X-ray diffraction. The introduction of $m-TiO_2$ increased the membrane diffusivity, thereby increasing the mixed-gas permeance from 1.6 to 16.0 GPU ($1GPU=10^{-6}cm^3$(STP)/($s{\times}cm^2{\times}cmHg$), and slightly decreased the propylene/propane selectivity from 45 to 37. However, both the mixed-gas permeance and selectivity of the membrane containing $m-TiO_2$ rapidly decreased over time, whereas the membrane without $m-TiO_2$ had more stable long-term performance. This difference might be attributed to specific chemical interactions between $TiO_2$ and Ag nanoparticles, causing Ag to lose activity as an olefin carrier.

계지반하생강탕 및 침구치료로 호전된 기능성 소화불량 환자의 치험 1례

김상진,이재홍,고석재,박재우,Kim, Sang-jin,Lee, Jae-hong,Ko, Seok-jae,Park, Jae-woo 대한한방내과학회 2016 大韓韓方內科學會誌 Vol.37 No.2

Objective: This case presents the effects of Gyejibanhasaenggang-tang, acupuncture, and moxibustion on functional dyspepsia.Method: A patient was treated with herbal medicine, acupuncture, and moxibustion. Functional dyspepsia-related quality of life (FD-QoL), the gastrointestinal symptom rating scale (GSRS), and the gastrointestinal scale (GIS) were assessed for evaluation.Results: Symptoms of functional dyspepsia improved after the 22 days of Gyejibanhasaenggang-tang treatment.Conclusion: This case suggests that the combination of Gyejibanhasaenggang-tang, acupuncture, and moxibustion could be effective in treating functional dyspepsia.

도시 확장에 따른 온열환경의 변화

김상진,Kim, Sang-Jin 한국태양에너지학회 2007 한국태양에너지학회 논문집 Vol.27 No.2

The surface changes due to urban expansion and the increase of artificial heat releases have brought significant climate changes such as heat island phenomenon in urban area. Furthermore, these changes also have brought serious problems such as air temperature increase, wind changes, and air pollution in urban area. Comprehensive analytical technologies considering various effects are required to analyse complicated mechanism of climate changes, and review the efficient measures. In this research, the effect of the urban expansion in Tokyo and Bangkok area on urban environment will be discussed. By using CFD, urban development and the mechanism of global warming and wind change are studied in those two cities. As a result of numerical research, the surface changes of city could bring the environmental changes in urban area.

시스템엔지니어링 기술 프로세스를 적용한 지속 가능 평가모델 설계 연구 : 모바일 산업 중심으로

김상진,차우창,Kim, Sang Jin,Cha, Woo Chang 한국시스템엔지니어링학회 2021 시스템엔지니어링학술지 Vol.17 No.2

A study on the sustainability evaluation of the requirements of the mobile industry closely related to the human factor was needed. We conducted the sustainability evaluation of the mobile industry using a quantitative evaluation method with the AHP tool and a qualitative evaluation method reflecting the technological age flow of the philosophical thoughts to improve the reliability of the evaluation results of the model verification. And this evaluation is to evaluate the consistency of the connection between the national sustainability and the mobile industry. In order to draw the conclusion of the relevance, the team member Delphi 5-point scale was used. As a result, the priority was confirmed in the national sustainable development indicator and mobile industry indicator. Quantitative and qualitative evaluation was applied to the discontinued model of mobile to derive insufficient indicators, and it was confirmed that if the indicators were improved and reflected, it would be sustainable. And in order to secure reliability and accuracy, we made a proposal to apply the systems engineering process to the development of the model evaluation field. The systems engineering technology process meets the needs and requirements of stakeholders throughout the lifecycle and it is suitable for the development model of the industry's sustainability assessment.

모바일산업 지속가능 시스템 평가모델 설계를 위한 인간시스템통합 (HSI) 방법론 연구

김상진,차우창,Kim, Sang Jin,Cha, Woo Chang 한국시스템엔지니어링학회 2021 시스템엔지니어링학술지 Vol.17 No.1

The aim of this study is to propose the design suitable for sustainability evaluation model of the mobile industry considering system process (SEP). Although a quantitative evaluation was conducted on the link between the national sustainability report and the mobile industry, it was confirmed that it was difficult to identify stakeholders. So it is necessary to develop the design process suitable for the more operator-specific interfaces. The Human System Integration (HSI) methodology was proposed through linkage with work domain analysis. Agile methodology and Resilience engineering methodology were added for sustainable model design. The proposed sustainability system evaluation model is applied so that it can be easily used in all industries.

재발된 간헐외사시로 재수술한 환자의 임상분석

김상진,최동규,Sang Jin Kim,Dong Gyu Choi 대한안과학회 2007 대한안과학회지 Vol.48 No.2

Purpose: To analyze the clinical course and relationships between the factors and surgical outcomes after reoperation for recurrent intermittent exotropia. Methods: Surgical results were retrospectively investigated in 38 patients who had undergone reoperation at least 3 months after surgical correction. Recurrence was defined as an exodeviation of more than 10 prism diopters at the primary position. We investigated the recurrence rate according to the follow-up duration with survival analysis, and analyzed the relationships between the factors and surgical outcome. Results: The mean survival period was 22.7±20.2 months (range, 3 to 72 months). As the follow-up duration increased, the recurrence rate progressively increased. The hazard ratio for recurrence of a unilateral medial rectus resection as a reoperation was significantly higher than that for a unilateral lateral rectus recession and medial rectus resection (recession and resection)(p=0.021). After using unilateral recession and resection as the primary surgery, the hazard ratio for recurrence of unilateral recession and resection as a reoperation was not significantly different from that for unilateral lateral rectus recession (p=0.480). After a bilateral lateral rectus recession, the hazard ratio for recurrence of unilateral medial rectus resection was not significantly different from that for bilateral medial rectus resection (p=0.076). Conclusions: The surgical options for recurrent intermittent exotropia are contralateral recession and resection or contralateral lateral rectus recession. The procedure chosen depends on the operator`s preference after performing unilateral recession and resection as the primary surgery. After a bilateral lateral rectus recession, the hazard ratio for recurrence of unilateral medial rectus resection was not significantly higher than that for a bilateral medial rectus resection, but even so, a bilateral medial rectus resection may be more effective than unilateral medial rectus resection for recurrent intermittent exotropia.

다공성 폴리에틸렌 안와 삽입물의 피복 재료로서 신전된 폴리테트라플루오로에틸렌의 이용

김상진,곽상인,정호경-,Sang Jin Kim,Sang In Khwarg,Ho Kyung Choung 대한안과학회 2007 대한안과학회지 Vol.48 No.1

Purpose: To investigate the possibility of expanded polytetrafluoroethylene (e-PTFE) as a wrapping material for porous polyethylene orbital implant. Methods: Two groups of 6 female New Zealand albino rabbits underwent enucleation with placement of a 12 mm porous polyethylene orbital implant wrapped in simple e-PTFE in one group (group 1) and macro-porous e-PTFE in the other group (group 2). Histopathologic sections of the implants obtained at 4, 6, 8 weeks were compared on the extent of fibrovascular ingrowth, percentage of the area of proliferated vessel, and grade of fibrosis between the two groups. Results: There was no implant exposure or severe inflammation in group 1 and 2 during the observation. The extent of fibrovascular ingrowth differs only at 4 weeks. Group 1 showed less fibrovascular ingrowth (until outer 1/3) at anterior half compared with posterior one, but there was no difference between anterior and posterior half in group 2 (until middle 1/3). The percentage of the area of the proliferated vessels was higher in group 2 than group 1 at both anterior and posterior half, and the anterior/posterior ratio of the area of vessels was also higher in group 2 than group 1. The grade of fibrosis was higher in group 2 than group 1 at 4, 6, and 8 weeks. Conclusions: Macro-porous e-PTFE almost didn`t disturb fibrovascular ingrowth into the orbital implant, so macro-porous e-PTFE can be used safely as a wrapping material for porous polyethylene orbital implant.

당뇨병 돋보기 I - 당뇨병과 두통

김상진,Kim, Sang-Jin 사단법인 한국당뇨협회 2007 당뇨 Vol.215 No.-

코퍼스 기반 음성합성기를 위한 합성단위 경계 스펙트럼 평탄화 알고리즘

김상진,장경애,한민수,Kim Sang-Jin,Jang Kyung Ae,Hahn Minsoo 대한음성학회 2005 말소리 Vol.56 No.-

Speech unit concatenation with a large database is presently the most popular method for speech synthesis. In this approach, the mismatches at the unit boundaries are unavoidable and become one of the reasons for quality degradation. This paper proposes an algorithm to reduce undesired discontinuities between the subsequent units. Optimal matching points are calculated in two steps. Firstly, the fullback-Leibler distance measurement is utilized for the spectral matching, then the unit sliding and the overlap windowing are used for the waveform matching. The proposed algorithm is implemented for the corpus-based unit concatenating Korean text-to-speech system that has an automatically labeled database. Experimental results show that our algorithm is fairly better than the raw concatenation or the overlap smoothing method.

한국 경호원의 성공귀인 측정도구 개발

김상진,Kim, Sang Jin 한국융합보안학회 2017 융합보안 논문지 Vol.17 No.2

본 연구는 한국 경호상황에 맞는 경호주체의 성공귀인에 대한 요인을 제시하고, 이를 실증적으로 분석하기 위한 측정도구를 개발하는 데 있다. 이를 위하여 1차적으로 완전 개방형 질문지를 통하여 면담을 실시하여 2차적으로 반구조화 질문지를 구성하였으며, 3차적으로 폐쇄형 설문지를 제작하여 설문조사를 실시한 후 SPSS 21.0, AMOS 21.O 통계패키지를 통하여 데이터를 분석하여 척도를 개발하는 과정을 걸쳤다. 조사기간은 최초 질문지를 배포한 시점인 2014년 12월부터 2015년 6월까지 약 7개월간에 걸쳐서 실시하였으며, 예비조사를 통하여 문항의 구성타당도를 검증한 후 200명의 경호원을 대상으로 본 조사를 실시하였다. 이를 통하여 1차, 2차 분석 과정에서는 경호원의 내적자질, 경호원의 외적자질, 경호주체로써 경호원의 내적자질 유도 요인, 경호주체로써 경호원의 외적자질 유도 요인 등 네 가지 구성요소로 분류하여 경호원의 성공귀인에 관한 요인들을 구성하였다. 3차 분석에서 설문지를 구성하여 최종적으로 자료 및 데이터를 분석한 결과, 한국 경호원의 성공귀인은 '무술 및 신체능력'(4문항), '실무적 자세'(3문항), '업무환경지원'(3문항), '조직적인 실무능력'(3문항), '임무수행태도'(3문항), '위기대처능력'(2문항) 등 6개 하위요인 18문항으로 구성되어졌다. This study is for presenting the factors about success attribution that fit the korean security service conditions and developing the actual analysis of measurement tools by investigating the success factors of the security service agents. To this end, conducted a meeting from the fully open questionnaire at first, and then formed the semi-structured questionnaire, finally carried out the survey from the closed questionnaire and analyzed data from SPSS 21.0, AMOS 21.0 and developed the measurements. It was conducted from December, 2014 to June, 2015. This survey was conducted of 170 security guards after the verification of the content validity though the pilot survey and presented the success attribution factors and standards on the basis of the result form this survey. At the first and second analysis process, the success attribution factors of the guards consisted of inner qualities, external qualities, induction factors for inner qualities, and induction factor for external qualities. On analysis of the final data and documents, however, at the third analysis, the success attribution factors of the guards consisted of 'martial arts and physical ability'(4 questions), 'attitudes to work'(3 questions), 'support for the working environment'(3 questions), 'organized business skills'(3 questions), 'attitudes to the duty'(3 questions), and 'coping with crises(2 questions).