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Production of high-quality chemical materials through the catalytic pyrolysis of e-waste
( Hyunji Yim ),( Hoyeon Jang ),( Bo Sung Kang ),( Sugyeong Jeon ),( Haneul Shim ),( Youngeun Kang ),( Young-min Kim ),( Sumin Pyo ),( Young-kwon Park ) 한국폐기물자원순환학회 2022 ISSE 초록집 Vol.2022 No.-
With the recent development of electronic device manufacturing technology, the demand of electrical and electronic equipment has increased rapidly, and the amount of electronic waste (e-waste) is also increasing accordingly. Although the recycling of e-waste has increased, it is still limited as metal recovery and most of organic parts, polymers and additives, were still treated simply via incineration or landfill. Pyrolysis can be considered as an eco-friendly process not only for the effective recovery of metal but also for the chemical recycling of organic parts of e-wastes. In this research, the thermal and catalytic pyrolysis of e-wastes have investigated focused on the production of high-quality oil and chemical feedstock. The non-catalytic pyrolysis of organic part in e-waste was prepared after the elimination of inorganic part and applied the pyrolysis under inert gas atmosphere using thermogravimetric (TG) analyzer and pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS). Kinetic analysis, analyzed by a model free kinetic analysis method to the TG analysis results of organic e-waste, indicated the change of thermal degradation pattern by applying the catalytic pyrolysis. Py-GC/MS result also indicated the quality of the pyrolysis oil can be upgraded efficiently with the decrease of undesirable product, such as halogen containing chemicals and oxygen containing pyrolyzates.
단순언어장애 아동과 일반 아동의 KBPR (Korean Brief Parent Report)과 작업기억 능력 간의 관계 : 음운루프, 일화적 완충기를 중심으로
임동선(Dongsun Yim),신현지(Hyunji Shin),임나은(Naeun Lim),정예영(Yeyoung Jung),한지민(Jimin Han),양윤희(Yoonhee Yang) 한국언어청각임상학회 2021 Communication Sciences and Disorders Vol.26 No.2
배경 및 목적: Korean Brief Parent Report (KBPR)과 작업기억(음운루프, 언어 및 비언어적 일화적 완충기)의 상관관계와 아동의 언어 능력을 유의하게 예측할 수 있는 과제를 알아보고자 한다. 방법: 51-80개월(평균 63개월) 학령전기 단순언어장애 아동 21명, 일반 아동 31명을 대상으로 KBPR과 작업기억 과제(비단어 따라말하기, 단어목록회상, 대칭-비대칭 매트릭스)를 실시하였다. 결과: 첫째, 집단 간 KBPR 영역별 점수 및 총 점수에서 (b) 현재 언어 수준, (c) 행동 패턴 및 활동 선호도, 총 점수에서 집단 간 유의한 차이를 보였다. 둘째, 음운루프, 언어적 일화적 완충기에서 집단 간 유의한 차이가 있었다. 셋째, 집단 간 KBPR의 각 영역 점수 결과와 작업기억 간 상관관계는 일반 아동 집단에서 언어적 일화적 완충기(문장어순)이 (a) 영역을 제외하고 일관되게 나타났으며, 단순언어장애 아동 집단에서는 (a) 영역은 음운루프, (b) 영역은 언어적 일화적 완충기(문장어순), (c) 영역은 비언어적 일화적 완충기(대칭, 비대칭)와 유의한 상관관계를 보였다. 넷째, KBPR 총 점수에 가장 유의한 예측요인은 일반 아동 집단은 언어적 일화적 완충기(문장어순), 단순언어장애 아동 집단은 음운루프였다. 논의 및 결론: 두 집단의 KBPR 점수 및 작업기억 과제는 영역별 유의한 차이를 보였다. 또한, 각 집단 간 KBPR 총 점수를 가장 유의하게 예측할 수 있는 요인으로 단순언어장애 아동 집단은 음운루프, 일반 아동 집단은 언어적 일화적 완충기(문장어순)였다. Objectives: This study examined whether there is a significant relationship between Korean Brief Parent Report (KBPR) and Working Memory (phonological loop, episodic buffer); and investigated the significant predictor of children’s language ability. Methods: A total of 52 children from 4 to 6 years old participated in this study composed of children with Specific Language Impairment (SLI), and typically developing (TD) children. Experimental tasks including KBPR, Non-Word Repetition (NWR), Word List Recall and a Symmetric-Asymmetric Matrix were used. One-way ANOVA, correlational, and multiple stepwise regression analysis were used. Results: 1) There was a significant difference between groups in section B (Current abilities) and C (Behavior patterns and activity preferences). 2) There was a statistically significant difference in phonological loop and linguistic episodic buffer (EB). 3) The correlation between each section score of KBPR and working memory in the TD group showed consistent linguistic sentential order in the EB task with all the other sections except for section A. In the SLI group, section A had correlation with phonological loop, section B had correlation with linguistic EB, and section C had correlation with non-linguistic EB 4) The most significant predictor of the KBPR total score in the TD group was linguistic sentential order EB, and in the SLI group was phonological loop. Conclusion: Both the KBPR score and working memory task competency of the SLI and TD groups showed significant differences. In addition, the meaningful predictor in the total score of KBPR in each group respectively was NWR in the SLI group and linguistic sentential order EB in the TD group.
Lee, Woo Kyung,Lee, Seul Gi,Yim, Seung Hyuk,Kim, Daham,Kim, Hyunji,Jeong, Seonhyang,Jung, Sang Geun,Jo, Young Suk,Lee, Jandee MDPI 2018 INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES Vol.19 No.10
<P>Locally advanced thyroid cancer exhibits aggressive clinical features requiring extensive neck dissection. Therefore, it is important to identify changes in the tumor biology before local progression. Here, whole exome sequencing (WES) using tissues from locally advanced papillary thyroid cancer (PTC) presented a large number of single nucleotide variants (SNVs) in the metastatic lymph node (MLN), but not in normal tissues and primary tumors. Among those MLN-specific SNVs, a novel HHIP G516R (G1546A) mutation was also observed. Interestingly, in-depth analysis for exome sequencing data from the primary tumor presented altered nucleotide ‘A’ at a very low frequency indicating intra-tumor heterogeneity between the primary tumor and MLN. Computational prediction models such as PROVEAN and Polyphen suggested that HHIP G516R might affect protein function and stability. In vitro, HHIP G516R increased cell proliferation and promoted cell migration in thyroid cancer cells. HHIP G516R, a missense mutation, could be a representative example for the intra-tumor heterogeneity of locally advanced thyroid cancer, which can be a potential future therapeutic target for this disease.</P>
A Novel Hedgehog-Interacting Protein G516R Mutation in Locally Advanced Papillary Thyroid Cancer
Seul Gi Lee,Seung Hyuk Yim,Woo Kyung Lee,Sun Hyung Choi,Hyunji Kim,Seonhyang Jeong,Cho Rok Lee,Sang Wook Kang,Jong Ju Jeong,Kee-Hyun Nam,Woong Youn Chung,Young Suk Jo,Jandee Lee 대한외과학회 2018 대한외과학회 학술대회 초록집 Vol.2018 No.11
박수진 ( Soo Jin Park ),( Eun Ji Lee ),( Hee Su Lee ),( Junsik Kim ),( Sunwoo Park ),( Jiyeon Ham ),( Jaehee Mun ),( Haerin Paik ),( Hyunji Lim ),( Aeran Seol ),( Ga Won Yim ),( Seung-hyuk Shim ),( Beong 대한산부인과학회 2022 대한산부인과학회 학술대회 Vol.108 No.-
This study aims to evaluate the drug distribution, tissue concentrations, penetration depth, pharmacokinetic properties, and toxicities after rotational intraperitoneal pressurized aerosol chemotherapy (RIPAC) in pigs. Because relevant medical devices have not been introduced, we developed our prototype of pressurized intraperitoneal aerosol chemotherapy (PIPAC) and RIPAC by adding a conical pendulum motion device for rotating the nozzle. RIPAC and PIPAC were conducted using 150 ml of 1% methylene blue to evaluate the drug distribution and 3.5mg of doxorubicin in 50 ml of 0.9% NaCl to evaluate the tissue concentrations and penetration depth, pharmacokinetic properties, and toxicities. All agents were sprayed as aerosols via the nozzle, DreamPenVR (Dalim Biotech, Gangwon, South Korea), with a velocity of 5 km/h at a flow rate of 30 ml/min under a pressure of 7 bars, and capnoperitoneum of 12mmHg was maintained for 30 min. As a result, RIPAC showed a wider distribution and stronger intensity than PIPAC. Compared with PIPAC, RIPAC demonstrated high values of the tissue concentration in the central, right upper, epigastrium, left upper, left lower, right lower, and right flank regions (median, 375.5-2124.9 vs. 161.7- 1240 ng/ml; p_ .05), and higher values of the depth of concentrated diffusion and depth of maximal diffusion (median, 232.5- 392.7 vs. 116.9-240.1 lm; 291.2-551.2 vs. 250.5-362.4 lm; p_ .05) in all regions except for bowels. In RIPAC, the pharmacokinetic properties reflected hemodynamic changes during capnoperitoneum, and there were no related toxicities. Conclusively, RIPAC may have the potential to enhance drug delivery into the peritoneum compared to PIPAC.