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      • KCI등재

        Influence of raw material grain composition on the properties of fused silica ceramics

        Qingtao Wang,Sen Li,Huaqin Yu,Fengzhi Li,Huijun Xu,Haibo Qiao,Juncheng Liu,Qingyang Du 한양대학교 세라믹연구소 2017 Journal of Ceramic Processing Research Vol.18 No.8

        Fused silica ceramics were prepared by slip casting method with various particle sizes (d50 ≈ 2.31 μm, 19.79 μm, and 71.46 μm)from three types of fused silica powder. The influence of raw material grain composition on the viscosity of slurry, bulk density,porosity, water absorption, and flexural strength of the fused silica ceramics was investigated. The slurry viscosity wasmeasured by an XND-1 viscometer. The bulk density, porosity, and water absorption of the sintered samples were obtainedby the Archimedes method. The flexural strength was measured by a three-point bending test. The phase composition andmicrostructure of the samples were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Theresults show that when the grain composition was 5 : 3 : 2, slurry viscosity was 150.79 mPa·s with solid content of 75%, thefused silica ceramic particles were packed most tightly and demonstrate bulk density of 2.02 g/cm3, porosity of 6.99%, waterabsorption of 3.47%, and flexural strength of 51.27 MPa.

      • KCI등재

        Synergy of ionic liquid and confinement in the design of supported palladium catalyst for efficient selective hydrogenation of acetylene

        Qingtao Wang,Yiqi Xu,Jing Zhou,Longyu Xu,Lu Yu,Dahao Jianga,Chunshan Lu,Zhiyan Pan,Qunfeng Zhang,Xiaonian Li 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.93 No.-

        We present here a novel fabrication of highly effective supported Pd catalysts (Pd@S-1@IL) derived fromPd@S-1 core–shell material coated with ionic liquids (ILs), [Prmim][Cl], for the selective hydrogenation ofacetylene. Catalytic testing on Pd@S-1@IL catalyst illustrated a remarkable selectivity towards semihydrogenation(over 90% for ethylene, irrespective of conversion level). Moreover, no indications ofdeactivation were observed after 800 h on stream even under relatively severe conditions. Detailedcharacterization indicated that the selectivity enhancement was ascribed to thefilter effect along withelectronic effect on the adsorption/desorption processes arising from the ionic liquids layer. The stability,which has ranked the top reported values over advanced Pd-based catalysts, is attributed to theconfinement effect of Pd NPs within the supports thus restricting the migration of metals. The fabricationof core–shell architecture combined with the advantages of ionic liquid layer offers a promising guidelinefor efficient catalytic transfer of chemical resource.

      • KCI등재

        Hierarchical chitosan/polyvinyl alcohol/polyethylene glycol/nonwoven fabric micro/nanofiber composite membrane: a potential biomaterial for wound dressing

        Ziwei Sun,Qingtao Liu,Zhen Wang,Baobao Zhao,Quan Feng,Yanyan Sun,Min Zhong 한국고분자학회 2023 Macromolecular Research Vol.31 No.12

        A hierarchical chitosan/polyvinyl alcohol/polyethylene glycol/nonwoven fabric (CS/PVA/PEG/NWF) micro/nanofiber composite membrane (CM) was prepared via electrospinning as a potential wound dressing. The polyester/viscose NWF acting as a substrate to receive the nanofiber layer was modified by alkali deweighting. Meanwhile, PEG with various additive amount was used to afford morphological regulation and control. As a result, the NWF modified with 7.5% NaOH solution exhibited a good hydrophilia and a superior dimensional stability based on smaller elongation at break and higher peel strength. In addition, the morphology of the nanofiber layer was closely related to PEG content. CS/PVA/PEG nanofiber with smaller diameter was spun when PEG content reached to 3.0%. Accordingly, the micro/nanofiber CM showed an opportune water absorption and good air permeability. Furthermore, neither hemolysis nor cytotoxicity phenomena appeared for the resultant CM, since the hemolysis rate and the cell viability were less than 5% and more than 70%, respectively.

      • KCI등재

        Application of HTB-SiHa Cells Transfected with a Recombinant Plasmid for External Quality Assessment of Chlamydia trachomatis PCR

        Kuo Zhang,Hong Huo,Yu Sun,Lunan Wang,Rui Zhang,Guigao Lin,Jiehong Xie,Qingtao Wang,Jinming Li 대한진단검사의학회 2014 Annals of Laboratory Medicine Vol.34 No.5

        Background: The participation of laboratories in external quality assessment (EQA) pro- grams is required for the quality assurance of nucleic acid amplification of Chlamydia tra- chomatis . This study aimed to construct a new quality control (QC) material applicated in EQA of C. trachomatis PCR. Methods: A QC material-HTB-SiHa cells transfected with a recombinant plasmid contain- ing the cryptic plasmid sequence-was constructed for C. trachomatis PCR detection, and four different panels, each consisting of 4 positive samples with serial dilution of the con- structed QC material and 1 negative sample, were distributed by the National Center for Clinical Laboratories among four groups of 275, 268, 317, and 304 participants across China from 2011 through 2012. A total of eight commercial kits were used for C. tracho- matis PCR detection in participants. Results: Nine laboratories reported false-positive results (0.9%). As the series dilution in- creased, the correct reporting of the data sets decreased; the lowest correct rate was 96.3% in the weakest positive samples (10 4 copies/mL). Eight laboratories reported false- positive results, and 42 laboratories reported false-negative results in the EQA detection of C. trachomatis . No significant differences were observed in the detection of the con- structed C. trachomatis positive samples (97.9%, 98.5%, 100%, 98.5%; P =0.36) and negative samples (100%, 99.0%, 100%, 99.0%; P =0.764) using four commercial kits commonly used in China. Conclusions: The results of the EQA study indicated that the constructed material pro- vides a noninfectious, stable control material with sufficient volume for PCR detection of C. trachomatis.

      • KCI등재

        Characteristics of Copper-Clad Aluminum Rods Prepared by Horizontal Continuous Casting

        Yubo Zhang,Ying Fu,Jinchuan Jie,Li Wu,Kateryna Svynarenko,Qingtao Guo,Tingju Li,Tongmin Wang 대한금속·재료학회 2017 METALS AND MATERIALS International Vol.23 No.6

        An innovative horizontal continuous casting method was developed and successfully used to prepare copper-cladaluminum (CCA) rods with a diameter of 85 mm and a sheath thickness of 16 mm. The solidification structure andelement distribution near the interface of the CCA ingots were investigated by means of a scanning electron microscope,an energy dispersive spectrometer, and an electron probe X-ray microanalyzer. The results showed that theproposed process can lead to a good metallurgical bond between Cu and Al. The interface between Cu and Al wasa multilayered structure with a thickness of 200 μm, consisting of Cu9Al4, CuAl2, α-Al/CuAl2 eutectic, and α-Al +α-Al/CuAl2 eutectic layers from the Cu side to the Al side. The mean tensile-shear strength of the CCA sample was45 MPa, which fulfills the requirements for the further extrusion process. The bonding and diffusion mechanismsare also discussed in this paper.

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