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      • KCI등재

        Controlled fabrication and electrochemical corrosion behavior of ultrathin Ni-Cu alloy foil

        Linping Yu,Long Chen,Qizhi Chen,Luli Feng,Ziyi Xu,Bo Nan,Xiyue Kang,Yuehui He 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.103 No.-

        Cost-effective ultrathin alloy foils (<20 lm) are highly expected with the development of electronicindustry and micro-system technology. In this paper, electrodeposition combined with vacuum sinteringis used to fabricate a Ni-Cu alloy foil with thickness of 12.0 (±0.2) lm. For the ultrathin Ni-Cu alloy foil, adensified structure without pores can be achieved by prolonging sintering duration at 900 ℃ for 3 h. Under the current density of 10 mA cm 2, 700 s is the optimal electrodeposition time to obtain the highesttensile strength (187 MPa) with the Ni content of 41.5 wt.% in the alloy foil. Compared with Cu foil, Ni-Cu alloy foil shows superior corrosion resistance in 3.5 wt.% NaCl solution and also HCl solutions (0.5 mol/L, 1.0 mol/L, 2.0 mol/L), respectively. The uniform composition and defect-free surface, excellent tensilestrength and corrosion resistance together exhibits the great application potential of the obtained Ni-Cualloy foil, which may provide an inspiration for future development of integrated electronic or medicaldevices.

      • KCI등재

        Promoting N2 electroreduction to ammonia by fluorine-terminating Ti3C2Tx MXene

        Ding Yu,Zhang Junbo,Guan Anxiang,Wang Qihao,Li Si,Al-Enizi Abdullah M.,Qian Linping,Zhang Lijuan,Zheng Gengfeng 나노기술연구협의회 2021 Nano Convergence Vol.8 No.14

        Two-dimensional MXene-based materials are potential of presenting unique catalytic performances of electrocatalytic reactions. The surface functionalization of MXene-based catalysts is attractive for developing efficient electrocatalysts toward nitrogen reduction reaction. Herein, we reported a Ti 3 C 2 T x MXene with a medium density of surface functionalized fluorine terminal groups, as an excellent N 2 reduction reaction electrocatalyst with enhanced adsorption and activation of N 2 . The Ti 3 C 2 T x MXene catalyst showed a production rate of ammonia as 2.81 × 10 –5 μmol·s −1 ·cm −2 , corresponding to a partial current density of 18.3 μA·cm −2 and a Faradic efficiency of 7.4% at − 0.7 V versus reversible hydrogen electrode in aqueous solutions at ambient conditions, substantially exceeding similar Ti 3 C 2 T x MXene catalysts but with higher or lower densities of surface fluorine terminal groups. Our work suggests the capability of developing surface functionalization toolkit for enhancing electrochemical catalytic activities of two-dimensional MXene-based materials.

      • KCI등재

        In Situ Synthesis and Strengthening of Powder Metallurgy High Speed Steel in Addition of LaB6

        Weijun Shen,Linping Yu,Zhi Li,Yuehui He,Qiankun Zhang,Huibin Zhang,Yao Jiang,Nan Lin 대한금속·재료학회 2017 METALS AND MATERIALS International Vol.23 No.6

        A novel technology which was characterized by the vacuum solid state sintering was developed for powder metallurgyhigh speed steels production. During sintering, both the WC and Mo2C reacted with Fe and transformed toW and Mo rich M6C carbides which were the common hard phases in high speed steels. Also, a high number of W,Mo and Fe were dissolved in VC, forming the MC carbides. The densification of the material mainly relied on thesolubility effect during the M6C and MC carbides formation. By alloying with a 0.1 wt% of LaB6 to the steel, thebending strength and the fracture toughness were improved from 3290 MPa and 25.6 MPam1/2to 4018 MPa and29.4 MPam1/2, respectively. The TEM analysis demonstrated three types of reaction products by the LaB6 addition:the amorphous phase, the core-shell structure and the La2O3 phase. The impurity elements such as the Mg, Al,Si, S, Ca, and O were absorbed following the LaB6 addition. Moreover, the deoxidization effect caused by the LaB6addition promoted the sintering at a high-temperature period which contributed to the bending strength and fracturetoughness improvement.

      • KCI등재

        Hydrophobic modification of silica/exfoliated graphite nanoplatelets aerogel and its application as supporting material for form-stable phase change materials

        Ni Tan,Yang Feng,Ping Hu,QiLin Ding,Chuan-Huang Lin,Yu-Hao Ning,Hao-Nan Zhou,Linping Yu,Zhong Cao,Ju-Lan Zeng 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.99 No.-

        Hydrophobic modified silica/exfoliated graphite nanoplatelets aerogel (M-SiO2/xGnP) were successfullyprepared via surface modification of silica/xGnP alcogel and followed by ambient pressure drying. Afterwards, form-stable PCMs in which capric–palmitic acids eutectic (CA–PA) was confined in theprepared aerogels were obtained by vacuum infiltration. Characterization of the prepared form-stablePCMs revealed that both the hydrophobic modification and the doping of xGnP could effectively improvethe loading of CA–PA in the aerogel. The unmodified silica aerogel could not adsorb CA–PA, while theloading of CA–PA in the surface modified pure silica aerogel supported form-stable PCM and theunmodified silica/xGnP aerogel supported form-stable PCM were 24.2 wt% and 44.4 wt%, respectively. Besides, the hydrophobic modification and the doping of xGnP showed significant synergistic effect. Theloading of CA–PA in the M-SiO2/xGnP supported form-stable PCM (FPCM/xGnP-20-48) could attain78.9 wt% when the M-SiO2/xGnP was obtained by modifying the alcogel with 20 vol% trimethylchlorosilane for 48 h. The FPCM/xGnP-20-48 not only had high latent heat and good thermal reliability,but also exhibited significantly improved thermal conductivity and alleviated supercooling due to theeffective thermal conductive network formed by xGnP and the promoted heterogeneous nucleation ofCA–PA at interfaces with aerogel.

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