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- 저자 : 임태은(Taeeun Yim) (검색결과 4 건)
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김지용,임태은,문준영,Kim, Jiyong,Tron, Artur V.,Yim, Taeeun,Mun, Junyoung 한국전기화학회 2015 한국전기화학회지 Vol.18 No.2
상온 이온성 액체인 propylmethylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PMPyr-TFSI)를 리튬이차전지 전해질 용매로 사용 시 PMPyr-TFSI 내 수분 및 브롬 불순물이 전지의 성능에 미치는 영향을 연구하였다. 고전압 양극 물질인 $LiNi_{0.5}Mn_{1.5}O_4$ 스피넬 구조 양극을 이용한 반쪽 전지의 전해질로 PMPyr-TFSI를 사용 하는데 있어, PMPyr-TFSI의 수분 함유량을 각각 12, 77, 1060 ppm으로 제어하고 전압 곡선 개형 및 쿨롱 효율 거동 추적을 통해 PMPyr-TFSI 수분량이 전지 성능에 부정적인 영향을 미치는 것을 구체적으로 확인하였다. 또한, PMPyr-TFSI 전해질 내의 브롬 이온 불순물 양 제어를 통하여, 전지 내에서 브롬 이온 불순물과 관련한 전기화학 부반응을 찾아 내었다. 이들 할로겐 불순물에 의한 초기 전지 쿨롱 효율저하는 눈에 띠었으나, 수명 저하에는 큰 변화가 없음을 확인하였다.
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상온 이온성 액체로 활성화시킨 고온 작동 가능한 Nafion 고분자 전해질
이수현(Suhyun Lee),임태은(Taeeun Yim),박영돈(Yeong Don Park),문준영(Junyoung Mun) 한국고분자학회 2018 폴리머 Vol.42 No.4
Nafion polymer electrolyte, which is essential material of polymer fuel cells, is activated by water and shows conductivity. However, such aqueous electrolyte is volatile at room temperature, and the operating temperature is limited to 100 oC. In order to overcome this problem, we tried to activate Nafion polymer electrolyte by using room temperature ionic liquids. The influence of the molecular structure of room temperature ionic liquid on conductivity is evaluated by controlling ethyl, butyl, and iso-butyl groups into an alkyl group of alkylmethylimidazolium cation. Also their anion structure is controlled with tetrafluoroborate and bis[(trifluoromethyl)sulfonyl]imide. For the high conductivity of Nafion polymer electrolytes, Nafion polymer electrolytes with high conductivity and high temperature operation are studied by mixing 60-120 wt% of room temperature ionic liquids during casting of Nafion solution.
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박지민,김다은,김해빈,배중호,이예지,명재인,황은경,임태은,송준호,유지상,류지헌,Park, Ji Min,Kim, Daeun,Kim, Hae Bin,Bae, Joong Ho,Lee, Ye-Ji,Myoung, Jae In,Hwang, Eunkyoung,Yim, Taeeun,Song, Jun Ho,Yu, Ji-Sang,Ryu, Ji Heon 한국전기화학회 2016 한국전기화학회지 Vol.19 No.3
High Ni content layered oxide materials for the positive electrode in lithium-ion batteries have high specific capacity. However, their poor electrochemical and thermal stability at elevated temperature restrict the practical use. A small amount of $Al_2O_3$ was added to the mixture of transition metal hydroxide and lithium hydroxide. The $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ was simultaneously doped and coated with $Al_2O_3$ during heat-treatment. Electrochemical characteristics of modified $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ were evaluated by the galvanostatic cycling and the LSTA(linear sweep thermmametry) at the constant voltage conditions. The nano-sized $Al_2O_3$ added materials show better cycle performance at elevated temperature than that of micro-sized $Al_2O_3$. As the added amount of nano-$Al_2O_3$ increased, the thermal stability of electrode also enhanced, but the use of 2.5 mol% Al showed the best high temperature performance.
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기능성 이온 단량체의 가교를 통하여 표면 개질된 고율 충전용 리튬 망간 산화물 양극 소재
성민지(Min Ji Seong),박소영(So Young Park),김태현(Tae-Hyun Kim),박영돈(Yeong Don Park),임태은(Taeeun Yim) 한국고분자학회 2022 폴리머 Vol.46 No.1
In this study, 3-propyl-1-vinylimidazolium tetrafluoroborate (VPI BF₄) as an ionic crosslinker is designed and synthesized to improve the high rate capability of lithium manganese oxide (LMO) cathode material. The synthesis of ionic crosslinker is confirmed by ¹H nuclear magnectic resonance and <SUP>19</SUP>F nuclear magnectic resonance spectroscopies. It is confirmed that the VPI BF₄ is successfully crosslinked through Fourier-transform infrared spectroscopy. The use of VPI BF₄ does not compromise with the electrochemical performance of the cell even at high temperature and enhances the rate capability. The analysis of electrodes after electrochemical evaluation proves that VPI BF₄ contributes to the improvement of LMO interphase properties.
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