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신세진,안종명,김민영,장지근,Shin, Se-Jin,Ahn, Jong-Myung,Kim, Min-Young,Jang, Ji-Geun 한국반도체디스플레이기술학회 2007 반도체디스플레이기술학회지 Vol.6 No.1
The effects of plasma treatment on the ITO/glass substrate before deposition of organic materials were investigated in the fabrication of green light emitting organic devices with $Alq_3-C545T$ fluorescent system. In our experiments, the optimum plasma treatment was obtained at the power and time of 150W and 2 minutes under the $Ar(50%)/O_2$ ambient of 1 mTorr. The green OLED with plasma treatment at 150W for 2 minutes showed the luminance and efficiency of $4700\;cd/m^2$ and 8 lm/W at 10V, respectively. On the contrary, the same structured device without plasma treatment showed much lower performance with the luminance of $2600\;cd/m^2$ and the efficiency of 3.6 lm/W at 10 V.
TMP-BiP 호스트와 DJNBD-1 도펀트를 이용한 청색 OLED의 제작과 특성평가
장지근,안종명,신상배,장호정,공수철,신현관,공명선,이칠원,Chang, Ji-Geun,Ahn, Jong-Myoung,Shin, Sang-Baie,Chang, Ho-Jung,Gong, Su-Choel,Shin, Hyun-Kwan,Gong, Myung-Sun,Lee, Chil-Won 한국반도체디스플레이기술학회 2007 반도체디스플레이기술학회지 Vol.6 No.2
The blue emitting OLEDs using TMP-BiP[(4'-Benzoylferphenyl-4-yl)phenyl-methanone-Diethyl(biphenyl-4-ymethyl) phosphonate] host and DJNBD-1 dopant have been fabricated and characterized. In the device fabrication, 2-TNATA [4,4',4"-tris(2-naphthylphenyl-phenylamino)-triphenylamine] as a hole injection material and NPB [N,N'-bis(1-naphthyl)N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] as a hole transport material were deposited on the ITO(indium tin oxide)/glass substrate by vacuum thermal evaporation method. Followed by the deposition, blue color emission layer was deposited using TMP-BiP as a host material and DJNBD-1 as a dopant. Finally, small molecule OLEDs with structure of $ITO/2-TNATA/NPB/TMP-BiP:DJNBD-l/Alq_3/LiF/Al$ were obtained by in-situ deposition of $Alq_3$, LiF and Al as the electron transport material, electron injection material and cathode, respectively. The effect of dopant into host material of the blue OLEDs was studied. The blue OLEDs with DJNBD-1 dopant showed that the maximum current and luminance were found to be about 34 mA and $8110\;cd/m^2$ at 11 V, respectively. In addition, the color coordinate was x=0.17, y=0.17 in CIE color chart, and the peak emission wavelength was 440 nm. The maximum current efficiency of 2.15 cd/A at 7 V was obtained in this experiment.
장지근,김민영,안종명,신세진 한국반도체디스플레이기술학회 2007 반도체디스플레이기술학회지 Vol.6 No.1
The effects of plasma treatment on the ITO/glass substrate before deposition of organic materials were investigated in the fabrication of green light emitting organic devices with Alq3-C545T fluorescent system. In our experiments, the optimum plasma treatment was obtained at the power and time of 150W and 2 minutes under the Ar(50%)/O2 ambient of 1 mTorr. The green OLED with plasma treatment at 150W for 2 minutes showed the luminance and efficiency of 4700 cd/m2 and 8 lm/W at 10V, respectively. On the contrary, the same structured device without plasma treatment showed much lower performance with the luminance of 2600 cd/m2 and the efficiency of 3.6 lm/W at 10 V.
장지근,신상배,안종명,장호정,이학민,공명선,김민영,김준우,Chang, Ji-Geun,Shin, Sang-Baie,Ahn, Jong-Myoung,Chang, Ho-Jung,Lee, Hak-Min,Gong, Myoung-Sun,Kim, Min-Young,Kim, Jun-Woo 한국반도체디스플레이기술학회 2007 반도체디스플레이기술학회지 Vol.6 No.2
For the fabrication of blue color organic light emitting diodes(OLED) with a high performance, 2-TNATA [4,4',4"-tris (2-naphthylphenyl-phenylamino)-triphenylamine] as hole injection material and NPB [N,N'-bis (1-naphthyl) -N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] as hole transport material were deposited on the ITO (indium tin oxide)/glass substrate by the vacuum thermal evaporation. After then, blue color emission layer was deposited using TPM-BiP[(4'-Benzoylferphenyl-4-yl)phenyl-methanone-Diethyl(biphenyl-4-ymethyl)phosphonate] and GDI602 as a light emitting organic material. Finally, the two kinds of OLEDs with the structure of $ITO/2-TNATA/NPB/TPM-BiP/Alq_3/LiF/Al and ITO/2-TNATA/NPB/GDI602/Alq_3/LiF/Al$ were prepared by in-situ deposition. The maximum current density and luminance were found to be about $588\;mA/cm^2\;and\;5239\;cd/m^2$ at 12V for the OLED sample with the structure of $ITO/2-TNATA/NPB/TPM-BiP/Alq_3/LiF/Al$. Color coordinate of blue OLED was x=0.18, y=0.18 (at llV) and the maximum current efficiency was 2.82 cd/A (at 6V) with the peak emission wavelength of 440 nm.
$Alq_3$-C545T시스템을 이용한 고성능 녹색 유기발광다이오드의 제작과 특성 평가
장지근,김희원,신세진,강의정,안종명,임용규,Jang Ji-Geun,Kim Hee-Won,Shin Se-Jin,Kang Eui-Jung,Ahn Jong-Myong,Lim Yong-Gyu 한국마이크로전자및패키징학회 2006 마이크로전자 및 패키징학회지 Vol.13 No.1
[ $Alq_3$ ]-C545T 형광 시스템을 이용하여 녹색 발광 고성능 OLED를 제작하고 그 특성을 평가하였다. 소자 제작에서 ITO(Indium Tin Oxide)/glass 위에 정공 주입층으로 2-TNATA [4,4',4'-tris(2-naphthyl-phenyl-phenylamino)-triphenylamine]를, 정공수송층으로 NPB [N,N-bis(1-naphthyl)- N,N'-diphenyl-1,1'-biphenyl-4,4-diamine]를 진공 증착하였다. 녹색 발광층으로는 $Ahq_3$를 호스트로, 545T [10-(2-benzo-thiazolyl)-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-[1]/benzopyrano[6,7,8-ij]-quinolizin-11-one]를 도펀트로 사용하였다. 또한, 전자 수송층으로는 $Alq_3$를 전자 주입층으로는 LiF를 사용하여 ITO/2-TNATA/NPB/$Alq_3$:C-545T/$Alq_3$/LiF/Al 구조의 저분자 OLED를 제작하였다. 본 실험에서 제작된 녹색 OLED는 521 nm의 중심 발광 파장을 가지며, CIE(0.29, 0.65)의 색순도, 그리고 12V의 동작전압에서 7.3 lm/W의 최대 전력효율을 나타내었다. The green emitting high performance OLEDs using the $Alq_3$-C545T fluorescent system have been fabricated and characterized. In the device fabrication, 2-TNATA [4,4',4'-tris(2-naphthylphenyl-phenylamino)-triphenylamine] as a hole injection material and NPB [N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] as a hole transport material were deposited on the ITO(indium thin oxide)/glass substrate by vacuum evaporation. And then, green color emission layer was deposited using $Alq_3$ as a host material and C-545T[10-(2-benzothiazolyl)-1,1,7,7- tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-[1]/benzopyrano[6,7,8-ij]-quinolizin-11-one] as a dopant. Finally, small molecule OLEDs with structure of ITO/2-TNATA/NPB/$Alq_3$:C545T/$Alq_3$/LiF/Al were obtained by in-situ deposition of $Alq_3$, LiF and Al as the electron transport material, electron injection material and cathode, respectively. Green OLEDs fabricated in our experiments showed the color coordinate of CIE(0.29, 0.65) and the maximum power efficiency of 7.3 lm/W at 12 V with the peak emission wavelength of 521 nm.
고효율 $CBP:Ir(ppy)_3$-PhOLEDs의 제작과 특성 연구
장지근,신상배,신현관,안종명,장호정,유상욱,Jang, Ji-Geun,Shin, Sang-Baie,Shin, Hyun-Kwan,Ahn, Jong-Myoung,Chang, Ho-Jung,Ryu, Sang-Ouk 한국마이크로전자및패키징학회 2008 마이크로전자 및 패키징학회지 Vol.15 No.2
고효율 녹색 인광 유기발광다이오드를 개발하기 위해 소자 구조를 ITO/2-TNATA/NPB/TCTA/CBP:$7%Ir(ppy)_3$/BCP/SFC-137/LiF/Al로 설계 제작하고 그 전계발광 특성을 평가하였다. 소자 제작에서 발광 호스트의 두께를 $150{\AA}{\sim}350{\AA}$ 범위로 변화시켜, 전계발광 특성을 비교해 본 결과, CBP두께가 약 $300{\AA}$ 부근일 때 가장 우수한 휘도 특성이 얻어졌다 전류 효율은 CBP두께가 $300{\AA}{\sim}350{\AA}$범위일 때 거의 포화되어 최대로 나타났다. $CBP(300{\AA}):7%Ir(ppy)_3-EML$ 층을 갖는 PhOLED(phosphorescent organic light emitting diode)의 전류 밀도, 휘도, 그리고 전류 효율은 10V의 인가전압에서 각각 $40mA/cm^2,\;10000cd/m^2$, 25cd/A로 나타났다. 또한 이 소자의 최대 전류효율은 $160cd/m^2$의 휘도 상태에서 40.5cd/A로 나타났다. 발광 스펙트럼은 512nm의 중심 파장과 약 60nm의 FWHM(Full Width Half Maximum)을 나타내었으며, CIE (Commission Internationale de I'Eclairage)도표 상에서 색 좌표는 (0.28,0.63)으로 나타났다. New devices with the structure of ITO/2-TNATA/NPB/TCTA/CBP:$7%Ir(ppy)_3$/BCP/SFC-137/LiF/Al were designed and fabricated to develop high efficiency green phosphorescent organic light emitting diodes and their electroluminescence properties were evaluated. Among the devices with different thicknesses of CBP in a range of $150{\AA}{\sim}350{\AA}$, the best luminance was obtained in the device with $300{\AA}$-thick CBP host. Nearly saturated current efficiencies indicates that the maximum efficiency value can be obtained with CBP thicknesses of $300{\AA}{\sim}350{\AA}$. The current density, luminance, and current efficiency of the PhOLED(phosphorescent organic light emitting diode) with $CBP(300{\AA}):7%Ir(ppy)_3-emissive$ layer at an applied voltage of 10V were $40mA/cm^2,\;10000cd/m^2$, and 25 cd/A, respectively. The maximum current efficiency was 40.5cd/A under the luminance of $160cd/m^2$. The peak wavelength and FWHM(full width at half maximum) in the electroluminescence spectral were 512nm and 60nm, respectively. The color coordinate was (0.28, 0.63) on the CIE (Commission Internationale de I'Eclairage) chart.
장지근,정진철,신세진,김희원,강의정,안종명,서동균,임용규,김민영,Jang Ji-Geun,Jeong Jin-Cheol,Shin Se-Jin,Kim Hee-Won,Kang Eui-Jung,Ahn Jong-Myong,Seo Dong-Gyun,Lim Yong-Gyu,Kim Min-Young 한국반도체디스플레이기술학회 2006 반도체디스플레이기술학회지 Vol.5 No.1
The polyvinyl series organic films as gate insulators of thin film transistor(TFT) have been processed and characterized on the polyether sulphone (PES) substrates . The poly-4-vinyl phenol(PVP) and polyvinyl toluene (PVT) were used as solutes and propylene glycol monomethyl ether acetate(PGMEA) as a solvent in the formation of organic insulators. The cross-linking of organic insulators was also attempted by adding the thermosetting material, poly (melamine-co-formaldehyde) as a hardener in the compound. The electrical characteristics measured in the metal-insulator-metal (MIM) structures showed that insulating properties of PVP layers were generally superior to those of PVT layers. Among the layers of PVP series; copolymer PVP(10 wt%), 5wt% cross-linked PVP(10 wt%), copolymer PVP(20 wt%), 5 wt% cross-linked PVP(20 wt%) and 10 wt% cross-linked PVP(20 wt%), the 10 wt% cross-linked PVP(20 wt%) layer showed the lowest leakage current of 1.2 pA at ${\pm}10V$. The ms value of surface roughness and the capcitance per unit area are 2.41 and $1.76nF/cm^2$ in the case of 10 wt% cross-linked PVP(20 wt%) layer, respectively.