규질이암으로부터 트리스실리트라닐옥시에틸아민의 합성

김병규(Byoung Gyu Kim),장희동(Hee Dong Jang) 한국암석학회 2009 한국암석학회 학술발표회 논문집 Vol.2009 No.5

차영상의 가산 투영과 배경 추출을 이용한 동영상에서의 목표물 추출 기법

김병규(Byoung-Gyu Kim),박동조(Dong-Jo Park) 한국통신학회 1998 한국통신학회 학술대회논문집 Vol.1998 No.11

규질이암으로부터 실리콘 유기화합물 합성

김병규 ( Byoung Gyu Kim ),장희동 ( Hee Dong Jang ),김종석 ( Jong Seok Kim ) 한국광물학회 2007 광물과 암석 (J.Miner.Soc.Korea) Vol.20 No.3

WO₃ 피복 석탄회의 광촉매 특성에 미치는 TiO₂의 첨가 효과

유연태,김병규,Yu, Yeon-tae,Kim, Byoung-gyu 한국재료학회 2003 한국재료학회지 Vol.13 No.10

To improve the photocatalyticactivity of $TiO_2$-coated coal fly ash, tungsten hydroxide was doped by impregnation method and was oxidized by heat treatment in temperature ranges of $WO^{\circ}C$ for 2 hrs. The changes of crystal structure and crystal size of $TiO_2$and $WO_3$on coal fly ash were investigated by X-ray diffraction analysis. The crystal structure of titanium dioxide showed only anatase type and $TiO_2$-$WO_3$ compounds appeared in the heat treatment temperature ranges of $500∼600^{\circ}C$. By adding $V_3$in $TiO_2$coated on fly ash, the growth of crystal size of anatase was restrained and the anatase phase was stabilized in temperature ranges of $500∼<800^{\circ}C$. And $WO_3$acted as a trap site of electrons excited from anatase by irradiating UV. The maximum removal efficiency of NO gas for $TiO_2$/$WO_3$-coated coal fly ash was 84% and appeared when the ammonium tungstate of $1.3${\times}$10^{-3}$ M was doped and then heated at $600^{\circ}C$ for 2 hrs.

Au/TiO₂ core-shell 나노입자의 합성에 있어서 Au 나노입자의 분산특성에 미치는 Mercaptoundecanoic acid (MUA)의 피복 효과

유연태,김병규,Yu, Yeon-Tae,Kim, Byoung-Gyu 한국재료학회 2006 한국재료학회지 Vol.16 No.12

Mercaptoundecanoic acid (MUA) has been used to enhance the dispersity of Au nanoparticles in organic solvent and the affinity between the Au nanoparticles surface and titanium dioxide shell in the synthesis of $Au/TiO_2$ core-shell composite nanoparticles. The dispersity of the MUA-coated Au nanoparticles in ethanol aqueous solution with different concentration of $H_2O$ was investigated by UV-Vis. absorption spectrum and the coating amount of MUA was varied from 0.02 mM to 1.0 mM. The MUA-coated Au nanoparticles were highly dispersed in pure $H_2O$ in the wide range of the coating amount of MUA. On the contrary, the MUAcoated Au nanoparticles showed an enhanced stability in the ethanol/$H_2O$=8/2 mixed solution only when the coating amount of MUA was 0.05 mM, and in the ethanol/$H_2O$=7/3 mixed solution when the coating amount of MUA was in the range from 0.02 mM to 0.17 mM. From this systematic study, it can be inferred that the stability and the dispersibility of Au nanoparticles in organic solvents are highly sensitive towards the amount of MUA coating.

Synthesis of Li<SUB>1.6</SUB>[MnM]<SUB>1.6</SUB>O<SUB>4</SUB> (M=Cu, Ni, Co, Fe) and Their Physicochemical Properties as a New Precursor for Lithium Adsorbent

김양수(Kim, Yang-Su),문원진(Moon, Won-Jin),정순기(Jeong, Soon-Ki),원대희(Won, Dae-Hee),이상로(Lee, Sang-Ro),김병규(Kim, Byoung-Gyu),정강섭(Chung, Kang-Sup) 한국산학기술학회 2011 한국산학기술학회논문지 Vol.12 No.10

New precursors as a Li adsorbent, Li1.6(MnM)1.6O4 (M=Cu, Ni, Co, Fe), were synthesized by hydrothermal method and their physicochemical properties were discussed. XRD and HRTEM results revealed that the original spinel structure was stabilized by cobalt-doping while Cu-, Ni- and Fe-doping led to structural changes. Such a structural stabilization by Cobalt-doping was maintained after lithium leaching by acid treatment. Li absorption efficiency from seawater was significantly enhanced by using the Cobalt-doped spinel manganese oxide, Li1.6[MnCo]1.6O4, compared to the commercially available Li1.33Mn1.67O4; the adsorbed amount of Li from 1g-adsorbent was 35 and 16 mg by Li1.6[MnCo]1.6O4, and Li1.33Mn1.67O4, respectively.

소성블릭 제조를 위한 무연탄 석탄회의 특성 연구

유연태,김병규,최영윤,남철우,이용석,김천순,Yu Yeon-Tae,Kim Byoung-Gyu,Choi Young-Yoon,Nam Chul-Woo,Lee Yeng-Seok,Kim Cheon-Sun 한국자원리싸이클링학회 2004 資源 리싸이클링 Vol.13 No.2

To increase the recycling rate of anthracite fly ash, the properties of anthracite fly ash were compared to that of bituminous fly ash. Especially, the high temperature properties of the fly ash are investigated by using thermal analysis, high temperature microscope and X-ray diffraction analysis for utilizing anthracite fly ash to prepare the calcinated bricks. The average ratio of $A1_2$$O_3$/$SiO_2$ for anthracite is 0.62 and the ratio for bituminous is 0.34. The content of $SiO_2$ in anthracite fly ash was higher than that of bituminous fly ash. The $A1_2$$O_3$ of anthracite fly ash reacted with the $A1_2$$O_3$ in the fly ash and formed new mullite crystal at over $1000^{\circ}C$, so anthracite fly ash showed high fire resistance. And, the fly ash mixtures having kaolin were prepared, and then extruded in vacuum to evaluate the extruding property of anthracite fly ash mixture. The extruding velocity was decrease with increasing the addition amount of fly ash in the mixture, and the maximum addition amount of fly ash that could be extruded was 60 wt%. 무연탄 석탄회의 재활용 향상을 위하여, 무연탄 석탄회의 특성을 유연탄 석탄회의 특성과 비교하였다. 특히, 무연탄 석탄회를 소성블릭의 원료로 활용하기 위하여, 무연탄 석탄회의 고온 특성이 열분석, 고온현미경 및 X선 회절 분석에 의해 조사되었다. 무연탄석탄회의 $A1_2$$O_3$/SiO$_2$ 비는 평균 0.62이고 유연탄 석탄회는 $A1_2$$O_3$/$SiO_2$ 비가 0.34로 무연탄 석탄회 중 A1$_2$$O_3$ 성분의 조성이 높았다. 무연탄 석탄회 중 $SiO_2$는 석탄회 중의 $A1_2$$O_3$와 반응하여 $1000^{\circ}C$의 고온에서 새로운 뮬라이트 결정을 형성하였고, 그 결과 우수한 내화도를 나타내었다. 또한, 무연탄 석탄회의 첨가량 변화에 따른 혼합시료의 압출 성형 특성을 평가하기 위하여 고령토와의 혼합시료가 제조되었고, 무연탄 석탄회 첨가 성형 벽돌의 압출속도는 혼합시료 중 석탄회의 첨가량이 증가할수록 감소하였으며, 압출 성형가능한 무연탄 석탄회의 최대 첨가량은 60wt%이었다.

고정, 임의시간 강우량 선택에 따른 농경지 배수 영향 분석

황동주,김병규,심좌근,Hwang, Dong Joo,Kim, Byoung Gyu,Shim, Jwa Keun 한국관개배수위원회 2012 한국관개배수논문집 Vol.19 No.1

Recently, it has been increased disaster of crops and agricultural facilities with climate change such as regional storm, typhoon. However agricultural facilities have unsafe design criteria of improving drainage corresponding to this change. This study has analyzed the impact that inundation area and magnitude of drainage-facility is decided based on fixed- and unfixed-duration precipitation by applying revised design criteria of drainage for climate change. The result was shown that 1-day and 2-days rainfall for 20-years return period has increased about 11.4%, 4.4% respectively by changing fixed- to unfixed duration. And the increase rate of design flood was 15.0%. The result was also shown that Inundation area was enlarged by 6.6% as well as increased inundation duration under same basic condition in designed rainfall between fixed- and unfixed-duration. According to the analysis, it is necessary for pump capacity in unfixed-duration to be increased by 70% for same effect with fixed-duration. Therefore, when computing method of probability precipitation is changed from fixed one to unfixed-duration by applying revised design criteria, there seems to be improving effect in drainage design. Because 1440-minutes rainfall for 20-years return period with unfixed-duration is more effective than 1-day rainfall for 30-years return period with fixed-duration. By applying unfixed-duration rainfall, capacity of drainage facilities need to be expanded to achieve the same effects (Inundation depth & duration) with fixed-duration rainfall. Further study is required for considering each condition of climate, topography and drainage by applying revised design criteria.

유가금속(有價金屬) 회수(回收)를 위한 중유회(重油灰)의 연소거동(燃燒擧動)에 관한 연구(硏究)

최영윤,남철우,김병규,Choi, Young-Yeon,Nam, Chul-Woo,Kim, Byoung-Gyu 한국자원리싸이클링학회 2009 資源 리싸이클링 Vol.18 No.1

중유회를 효율적으로 소각 처리할 수 있는 이동상식 스토카로를 설계, 제작하기 위해 중유회가 노상을 이동하면서 겪는 조건들을 회분식 노에서 모사(模寫)하여 열중량분석법으로 중유회의 소각실험을 수행하였다. 이 결과로부터 이동상식 스토카로의 운전조건 및 노상면적 등을 구하였다. 중유회의 연소과정은 연소속도 차이에 의해 3단계로 구별되며, 각 단계별로 효과적인 연소가 이루어질 수 있도록 해야 한다. 비산방지 및 체적감소를 위하여 소각 전 첨가되는 수분 함량은 20 wt.%가 적절하였다. 중유회의 연소속도는 산소농도에 크게 의존하므로, 소각로는 연소공기의 조절 기능이 필요하다. 저융점 금속화합물의 용착 및 증발을 방지하고, 소각잔사의 불용화 및 유가금속 회수를 위해 소각온도는 $750^{\circ}C{\sim}800^{\circ}C$가 적절하고, 중유회의 균일한 연소반응과 연소속도의 향상을 위해 소각 중 중유회의 교반이 요구된다. 최적 조건에서 단위면적당 소각속도는 $12.53kg/m^{2}hr$이며 1일 18 ton의 중유회를 소각처리하기 위해서는 $60m^2$의 노상면적이 필요하다. To design and construct a moving bed stoker incinerator for incineration treatment of the domestic oil fly ash, operating condition and moving bed area of incinerator were determined by performing incinerate experiment of the oil fly ash in the muffle furnace which simulates moving bed stoker incinerator in all conditions. Incineration process of the oil fly ash could be divided into 3 stages, every stage needs the appropriate operating condition for effective incineration. The optimum content of water in the heavy oil fly ash was found to be 20 wt% to prevent the ash from flying and reduce the volume. Science combustion rate of oil fly ash depends on the oxygen content, the incinerator must have a equipment to control the oxygen content in the combustion air. The optimum temperature was $750{\sim}800^{\circ}C$ in order to prevent adhesion to the stocker and evaporation of metal compounds of low melting point. Uniform combustion reaction and acceleration of combustion rate required agitation during the combustion of oil fly ash. The incineration rate was $12.53kg/m^2hr$ and the working area of moving bed incinerator was found to be $60m^2$ to incinerate 18 tons of oil fly ash per day.

$TiO_2$ 피복 석탄회의 제조와 광촉매 특성에 관한 연구

유연태,최영윤,김병규,이희정,이병택,Yu, Yeon-Tae,Choi, Young-Yoon,Kim, Byoung-Gyu,Lee, Hee-Jung,Lee, Byong-Taek 한국재료학회 2001 한국재료학회지 Vol.11 No.8

$TiO_2$ coated coal fly ash has been prepared in order to develop the low price $TiO_2$ photocatalyst and spread out its utilizing field. $TiO_2$ particles is coated on the surface of coal fly ash by precipitation method. In this method, $TiCl_4$ aqueous solution was used as a titanium stock solution and $NH_4HCO_3$ was used as a precipitant. The titanium hydroxide precipitated on the surface of coal fly ash in these neutralizing reaction process was oxidized by heat treatment in temperature ranges of $300~700^{\circ}C$. The crystal structure of the generated titanium dioxide showed anatase type. The crystal size of titanium dioxide increased with raising the temperature of heat treatment, but the removal ability of NO gas decreased. When the titanium dioxide was heated at temperature ranges of $300~ 400^{\circ}C$ for 2 hours, the crystal size of titanium dioxide appeared about 9nm, and the removal rate of NO gas showed 85~ 92%. The whiteness of $TiO_2$ coated coal fly ash increased with raising the coating rate of titanium dioxide and the temperature of heat treatment. 저가형 $TiO_2$ 광촉매의 개발과 광촉매의 활용범위를 확대하고자, 석탄회를 지지체로 이용하여 $TiO_2$ 광촉매를 제조하였다. 석탄회 표면에 $TiO_2$ 입자의 피복은 침전법에 의해서 수행되었다. $TiO_2$의 공급원으로는$ TiCl_4$수용액과 침전제로는 $NH_4$$HCO_3$가 사용되었다. 이들의 중화반응에 의해 석탄회 표면에 생성되는 Ti(OH)4$_4$는 $300~700^{\circ}C$의 열처리 과정에서 산화되었다. 여기서 생성된 $TiO_2$의 결정구조는 anatase형을 나타내었다. 피복 $TiO_2$의 결정립 크기는 열처리 온도의 상승에 따라 증가하였으나, NO가스의 제거능은 감소하는 경향을 보였다. $TiO_2$피복 석탄회를 $300~400^{\circ}C$의 온도 범위에서 2시간 동안 열처리할 경우, $TiO_2$의 결정립 크기는 약 9nm이었고, 질소산화물 제거율은 85~92%이었다. 또한, $TiO_2$피복 석탄회의 백색도는 $TiO_2$의 피복량이 증가할수록 열처리 온도가 증가할수록 상승하는 경향을 나타내었다.