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Zhu Yucan,Peng Long,Chen Song,Feng Yuchao,Xia Jianxing,Wang Wei,Chen Liang,Yin Hong,Zhou Minjie,Hou Zhaohui 한국탄소학회 2023 Carbon Letters Vol.33 No.3
With the rapid development of flexible wearable electronic products, flexible all graphene-based supercapacitors (FGSCs) with reduced graphene oxide rGO//graphene oxide (GO)//rGO structure have attracted substantial attention due to their unique structures and energy storage mechanism. However, restricted by design idea and preparation technology, improvement of capacitance performance for the FGSCs is not obvious recently. Herein, we demonstrate that an interface integration strategy of constructing the high-performance FGSCs with compact structure. Hydroquinone (HQ)-modified rGO (HQ-rGO) films (electrode materials) and sulfuric acid-intercalated GO films (electrolyte/separator) are assembled into the FGSCs utilizing hydrogen bonding and capillary contractility. The HQ further improves the electrochemical capacitance of electrode materials. The synergistic effect of the hydrogen bonding and capillary contractility guarantees compact and stable structure of the device. The resulting FGSCs exhibit an excellent areal capacitance of 804.6 mF cm−2 (@2 mA cm−2) and 441 mF cm−2 (@30 mA cm−2), and their highest energy and power densities can achieve 109.5 μWh cm−2 and 21,060 μW cm−2, respectively. These performances are superior to other all-in-one graphene-based SCs reported. Therefore, the construction technology of the FGSCs is a promising for developing all graphene-based SCs with high-performance.
Qiang Liu,Zhaohui Meng,Ronghui Wu,Liyun Ma,Wu Qiu,Honghao Zhang,Shuihong Zhu,Lingqing Kong,Zijjie Xu,Aniruddha Patil,Xiangyang Liu 한국섬유공학회 2019 Fibers and polymers Vol.20 No.10
In this work, regenerated silk fibroin (RSF) and silicon dioxide (SiO2) composite fiber was successfully extrudedby wet spinning method. The effect of SiO2 addition on structure of the composite fiber at microscopic level is studied, whichsubsequently correlated to the mechanical performance. The best concentration ratio for composite fiber is identified byscreening SiO2 concentration from 0.025 w/w% to 0.5 w/w%. The experimental results revealed that the SiO2 at a lowconcentration of 0.1 w/w% was well distributed. The breaking stress, breaking strain and Young’s modulus at 0.1 w/w% SiO2addition of the RSF fibers increased considerably compared to the neat RSF fibers from 243±3 to 458±21 MPa, 51±4 % to54±7 % and 6.34±0.55 to 11.69±1.12 GPa, respectively. To the best of our knowledge, this is the first report for RSF/SiO2composite fiber. We believed the insight provided in this report which looks into the structural evolution should be beneficialto the future design and building of other advanced functional fibers.
A study of factors influencing disruptive innovation in Chinese SMEs
Jin Cheng,Zhaohui Zhu,Yunting Zhang 기술경영경제학회 2017 ASIAN JOURNAL OF TECHNOLOGY INNOVATION Vol.25 No.1
Although around 99% of companies in China today are small- and medium-sized enterprises(SMEs), their innovative status is not optimistic, being constrained by lack of funding, size,and experience. Nevertheless, disruptive innovation provides an opportunity for SMEs tosurpass the large companies. This paper analyses external and internal factors influencingdisruptive innovation in SMEs, and compares those factors between low-end disruption andhigh-end disruption. The results of this empirical study suggest that factors influencing highenddisruptive innovation include government support, external knowledge sources, strategicsupport, and dominant position of R&D; while the factors influencing low-end disruptiveinnovation are cooperation with venture capitalists, external knowledge sources, dominantposition of R&D, and entrepreneurs’ innovation willingness. Two case studies are describedto illustrate our results.
Component-based model for posttensioned steel connections against progressive collapse
Yan Fei Zhu,Chang Hong Chen,Ying Huang,Zhaohui Huang,Yao Yao,Leon M. Keer 국제구조공학회 2021 Steel and Composite Structures, An International J Vol.40 No.4
A component-based method for the estimation of the posttensioned (PT) steel frame against progressive collapse is proposed and presented in the current paper. A mechanical model of PT steel connections is developed and benchmarked with experimental data of a PT beam-column substructure from literature. The developd mechanical models of four PT connections are able to capture the initial elastic stiffness, decompression load, and residual stiffness under lateral loading. Then, analysis of a reduced-scale three-storey two-bay PT steel frame is carried out with sufficient accuracy by incorporating the proposed joint model into the frame analysis. The proposed method is then applied to assessing progressive collapse of a one-storey two-bay PT frame under middle column removal scenario, and is verified against existing experimental and ANSYS finite element results. Three resistance mechanism for progressive collapse of the PT frame are evaluated, which consists of angle flexural mechanism, beam compression arching action and strand tensile catenary action. Finally, parameter analyses of the PT frames are conducted to investigate the effects of the connection details on the behavior and resistance of progressive collapse. The proposed model can be used to predict the quasi-static behavior of PT frames under monotonic vertical loading conditions with satisfactory accuracy.
Enlai Zheng,Yuanzhao Yang,Zhaohui Peng,Yue Zhu,Xiao Zhao,Xiangze Lin,Min Kang 대한기계학회 2019 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.33 No.6
Thermal models are important in the process of predicting the thermal characteristics and corresponding thermal error of multi-link high-speed precision presses (MLHSPPs) with an oil-lubrication system. Previous models only involved the effects of bearing stiffness, temperature change of bearings, flexibility of crank shaft on the heat generation power, while the influences of revolute clearance joint and flexibility of linkage are seldom considered, which inevitably reduces the accuracy of thermal analysis. To overcome this problem, dynamic models of flexible multi-link mechanisms (MLM) with clearance, lubrication, crankshaft-bearing system are constructed, the interaction forces between pin and bushing are obtained to calculate its heat generation power. Then, an improved model of MLHSPP with lubrication is proposed to analyze the temperature evolution and the thermal error between slider and work table at the position of LDP, by considering bearing stiffness, temperature change of bearings, flexibility of crank shaft, linkage, clearance, lubrication and thermal contact resistance all together. Compared with results from traditional models, the simulation data from this improved thermal model agree well with experiment, which proves the validity of the proposed model. Furthermore, the temperature rise and the thermal error of MLHSPP between slider and work table at the position of LDP under different input speeds, lubricating oil flux and contact angles of ball bearing were also studied.
Screening nephroprotective compounds from cortex Moutan by mesangial cell extraction and UPLC
Min Sun,Limei Huang,Jianliang Zhu,Wenjie Bu,Jing Sun,Zhaohui Fang 대한약학회 2015 Archives of Pharmacal Research Vol.38 No.6
A method for screening nephroprotective compoundsin cortex Moutan, a common traditional Chinesemedicine (TCM) in treating diabetic nephropathy with renalmesangial cell extraction and ultra performance liquidchromatography technique was described in this paper. Wehypothesize that the compounds which bind to cell membranesunder pathological conditions may be the bioactivecompounds in TCMs. Mesangial cells were cultured inmedium containing 5 mM (physiological, NG) or 30 mM(pathological, HG) glucose for 48 h and then incubated withcortex Moutan extract. After the unbound substances werewashed off, the cell membrane-bound compounds weredissociated and concentrated by an SPE column. By comparingthe chromatograms of NG and HG cultured-cellextractions and cortex Moutan extract, three compoundsbound to both NG and HG-cultured mesangial cells wereidentified as paeoniflorin, pentagalloylglucose (PGG) andpaeonol. In vitro studies showed that paeoniflorin, PGG andpaeonol reduced the activity of nicotinamide-adenine dinucleotidephosphate oxidase (NADPH) activity, anddecreased the level of reactive oxygen species (ROS),transforming growth factor-b1 (TGF-b1) and fibronectin inhigh glucose cultured mesangial cells. The results indicatethat paeonol, paeoniflorin and PGG may be the nephroprotectivecompounds from cortex Moutan. This study isexpected to provide a more reliable and effective method forscreening bioactive compounds from the complex TCM systems.
Qinghua Wang,Wei Wang,Junlin Huang,Hong Yin,Yucan Zhu,Haitao Wang,Minjie Zhou,Binhong He,Zhaohui Hou,Wenyuan Xu 한국탄소학회 2023 Carbon Letters Vol.33 No.1
Transition-metal phosphides (TMPs), a promising anode material for lithium-ion batteries (LIBs), are limited in application because of its serious volume effect in the cycle. In this work, a simple electrospinning strategy was proposed to restrict the grain size of CoP nanocrystals by nano-confined effect of carbon nanofibers with ligands. The addition of ligands not only could realize the uniform dispersion of CoP nanocrystals, but also strengthen the bond between the metals and carbon nanofibers. As a result, the CoP/CNF composite exhibits excellent lithium storage performance, and its reversible specific capacity could reach 1016.4 mAh g? 1 after 200 cycles at a current density of 200 mA g? 1. The research is anticipated to provide a new idea for the preparation of anode materials for lithium ion batteries.