http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
박성수(Seong Soo Park),박송자(Song-Ja Park),표희수(Heesoo Pyo),조정희(Jung Hee Cho),김혜수(Hye Soo Kim),박택규(Taek Kyu Park) 한국농약과학회 2000 농약과학회지 Vol.4 No.1
The purpose of this study is to establish the assessment techniques of hazardous chemicals by the development of analytical method of biological samples. In this study, we have developed an extraction method of nine pesticides used for rice paddy that resulted in high recovery from the spiked human urine by the liquid-liquid extraction with diethyl ether at pH 7.0. Calibration curve obtained from each pesticide standard using by gas chromatography/mass spectrometry/selected ion monitoring has shown good linearity and detection limits were the range of 0.4~2.0 ng/mL, in urine. As a biological monitoring, urine samples of local farmers exposed directly to nine pesticides in the field were collected and analyzed by GC/MS. Of the tested pesticides, metabolites of phenthoate assumed were identified by GC/MS analysis. No parent compound was detected.
RPLC/DAD를 이용한 Polycyclic Aromatic Hydrocarbon류의 분석에 관한 연구(I)
이원,홍지은,박송자,표희수,Lee, Won,Hong, Jee-Eun,Park, Song-Ja,Pyo, Hee Soo 한국분석과학회 1997 분석과학 Vol.10 No.5
Benzo(a)pyrene을 비롯한 16종의 polycyclic aromatic hydrocarbon(PAHs)과 4종의 nitro-PAHs를 reversed-phase liquid chromatography/diode array detection (RPLC/DAD)를 이용하여 기울기용리법으로 분리하고, PAH류의 머무름거동에 영향을 미치는 인자들, 즉 탄소수, F인자, L/B ratio, 물에 대한 용해도 및 방해수소원자쌍의 수와 시료의 머무름과의 상관관계를 고찰하였다. 대부분의 PAH류는 탄소원자수와 F값이 커질수록 logk'이 증가하는 사실을 확인하였다. 그리고 몇 가지 이성체들과 nitro-PAH류들은 용해도가 크고, L/B값이 작으며, 방해수소원자쌍의 수가 많을수록 먼저 용리됨을 확인하였다. 각 PAH류의 검출한계는 100~500ng/mL 범위로 나타났으며, 실제 물시료에 대한 검출한계(method detection limit, MDL)는 0.1~0.5ng/mL 범위였다. The retention behaviors of 16 PAHs and 4 nitro-PAHs were studied with several parameters involved numbers of carbon atoms, F factor, aqueous solubility, L/B ratio, and numbers of interfering hydrogen atom pairs on the chemical structures of PAHs by using reversed-phase liquid chromatography/diode array detection method (RPLC/DAD) and gradient elution method. It was obtain that the log k' for most of PAHs with increasing the number of carbon and the F factor in their molecules. Chromatographic retention of PAH isomers and nitro-PAHs were examined with aqueous solubility, L/B ratio and number of interfering hydrogen atom pairs. As a result of comparison with these factors and retention times, it was found that those solutes having larger aqueous solubilities and greater L/B ratios were retained longer on stationary phase. This tendency was also occured in the molecules having the more number of interfering hydrogen atom pairs. Detection limits of PAHs which were obtained with three times measurements by RPLC/DAD were in the range of 100~500ng/mL and method detection limit(MDL) for water sample were in the range of 0.1~0.5ng/mL.