Study of Molecular Reorientation in Liquid with Raman Spectroscopy(III). Temperature Dependence of Molecular Rotation of $C_6F_6$ in Neat Liquid

김명수,Myung Soo Kim Korean Chemical Society 1984 대한화학회지 Vol.28 No.1

라만 분광법을 사용하여 순수한 액체 상태의 $C_6F_6$의 재배치 운동을 연구하였다. 라만 스펙트럼 중 ${\nu}_2$와 ${\nu}_16$ 밴드를 선정하여 그 모습을 293~333K온도 범위에서 측정하였다. 분자의 주대칭축($C_{6-}$축)의 회전 및 스핀운동에 관한 회전 확산 상수 ($D_{\bo}$, $D_{\parallel}$)가 온도의 함수로써 결정되었으며 이로부터 $C-6F_6$의 재배치운동은 명백히 비등방적임을 알게 되었다. 실험 결과를 유체역학적 모델로 분석하여 본 결과 주대칭축의 회전운동은 확산적이며 스핀운동은 관성적이라는 것이 밝혀졌다. The reorientational motion of $C_6F_6$ in neat liquid is investigated in the temperature range 293∼333K by analyzing ${\nu}_2$ and ${\nu}_16$ bands of its Raman spectrum. Diffusion constants for the tumbling ($D_{\bo}$) and spinning ($D_{\parallel}$) motions are determined. The reorientation of the molecule seems to be distinctly anisotropic. Based on the hydrodynamic model, the tumbling motion of the figure axis of $C_6F_6$ is largely diffusional. On the other hand, the spinning motion of the same axis looks mostly inertial.

마이크로 시뮬레이션을 이용한 고속도로 화물차 전용차로 도입에 관한 연구

김명수,Kim, Myung-Soo 대한토목학회 2013 대한토목학회논문집 Vol.33 No.4

화물차 운송의 시간과 비용이 증가하여 물류비가 증가하게 되고 높은 물류비는 결과적으로 산업경쟁력의 저하로 이어지게 되므로 이 연구에서는 물류비 절감을 위해 고속도로에 화물차 전용차로 도입에 관한 연구를 실시하고자 한다. 연구의 대상지는 화물차의 통행이 많은 경부고속도로로 금호 JCT~남구미 IC 구간이고 이 구간에 기본차로, 버스전용차로 설치, 화물차 전용차로 설치, 두 전용차로를 설치시 그에 따른 운행속도, 밀도에 대해 도출하였다. 분석결과 화물차 전용차로 설치시 평균운행속도가 83.4km/h로 가장 높고 밀도는 22.47km/대로 가장 낮은 것으로 나타나 화물차 전용차로 도입시 긍정적인 영향을 미친다고 할 수 있다. The high distribution costs causes the increasing of truck delivery time and cost, which results in reducing industrial competitiveness incre. Therefore, This study conducted research into the introduction of truck only lane for reducting distribution costs. The site of study is Keumho JCT ~ Namgumi IC of Kyeongbu Expressway which has much truck traffic because of industrial complex. Thus, this study deduced travel speed and density in each scenaria(base, bus only lane, truck only lane, two only lane). According to analysis result, if a truck only lane install, the average driving speed is 83.4km/h as a highest and density 22.47veh/km as lowest. it means that if the truck only lane is install, it will be positive influence on the expressway

Micelle 형성에 관한 현상학적 고찰

김명수,Myung Soo Kim 대한화학회 1989 대한화학회지 Vol.33 No.5

계면활성제가 수용액 중에 용해되면 용액내에서 micelle이라는 응집체를 형성하며, micelle은 그 내부에 oil를 용해시켜 swollen micelle을 형성하게 된다. 실제로 물-oil-계면활성계의 상평형도상에서 micelle과 swollen micelle은 동일영역에 존재하게 되나 일반적으로 micelle과 swollen micelle의 형성에 관해서는 서로 다른 관점으로 취급되어 왔다. 본 연구에서는 이러한 계면활성제 응집체의 형성에 관한 일관된 열역학적 모델을 제시하고자 한다. 모든 경우에 저농도 영역에서 이상용액 이론을 적용하였으며, micelle 형성에너지는 소수성 작용에너지와 계면에서의 표면에너지의 합으로 표시하였다. 이론식으로부터 임계마이셀농도, 평균응집분자수, 용해비 등을 예측하였으며 실험관측치와 비교하였다. When the sufactants are dissolved in water, they associate to form micelles and solubilize oil inside the micelle to form swollen micelles. Although spherical aggregates like micelles and swollen micelles occupy the same regions in the phase diagram of water-oil-surfactant systems, they are treated in different viewpoint for the formation of such aggregates. Hence a unified thermodynamic formalism for the formation of such structure is presented in this study. In all cases, the to ideal solution theory is applied for dilute system and the energy of formation is expressed as the sum of hydrophobic interaction energy and surface energy due to surfactant film. From the model, critical micelle concentration (CMC), average aggregation number, and solubilization ratio are predicted and compared with the known experimental observation.

"K"국민학교(國民學校) 아동(兒童)의 치아우식증(齒牙齲蝕症) 이환추이(罹患推移)에 관(關)한 연구(硏究)

김명수,Kim, Myung-Soo 대한소아치과학회 1974 大韓小兒齒科學會誌 Vol.1 No.1

The dental caries survey of "K" primary school children was performed twice for one year interval and evaluated the transitional trend of dental caries prevalences. The number of children surveyed at the first year, 1973, was 819 boys and 653 girls; and the second year, 1974, was 815 boys and 661 girls aged 6 to 12. Under this survey, the following results were detected: 1. The average df person rate in deciduous teeth was increased by 7.52% in boy, 5.59% in girl and 6.65% of both. 2. The average df Index in deciduous teeth was increased by 0.13 in boy, 0.04 in girl and 0.1 of both. The average dt Index was decreased by 0.59 in boy, 0.64 in girl and 0.61 of both. The average ft Index was increased by 0.73 in boy, 0.68 in girl and 0.71 of both. 3. There showed no significant differences in DMF person rate between 1973 and 1974. 4. The DMFT Index of the permanent teeth was decreased by 0.19 in boy, and increased by 0.22 in girl. There showed no significant differences in both sexes between 1973 and 1974. The average DT Index was decreased by 0.43 in boy, 0.03 in girl and 0.31 of both. The average FT Index was increased by 0.23 in boy; 0.35 in girl and 0.29 of both. The average MT Index showed no significant differences in both sexes between 1973 and 1974.

동북아시아의 세력균형과 군사력 수준 변화 연구: 세력균형이론에 기초한 2030년경의 동북아시아 안보환경 전망

김명수,Kim, Myung-soo 한국해양전략연구소 2021 해양안보 Vol.3 No.1

This study examines the distribution of power in Northeast Asia based on the balance of power theory, a representative theory of realism, assuming military capabilities as the core power of states. The results of previous studies on the balance of power and military forces are reviewed and used to analyze changes in the strength of the US, China, Russia, Japan, South Korea, and North Korea through 2020 to predict the security environment in 2030. In the balance of power theory, if the balance of power between a nation or a group of powers collapses, the possibility of war is high, and to survive in the international community with high uncertainty and distrust, the theory predicts that states must increase their powers in a self-help world and strengthen cooperation and alliance. Countries in Northeast Asia are also continuing to strengthen their military capabilities, and countries neighboring China are paying keen attention and remaining vigilant due to the rapid changes in the international security environment after the rapid rise of China. To mark the future 100th anniversary of the Chinese armed forces in the 2030s, China aims to realize 'defense and military modernization' and build a 'world-class military force' by the nation's 100th anniversary in the 2050s. The US is busy checking China's rise by strengthening international cooperation and alliances. The security environment and power dynamics in Northeast Asia are slowly changing as the US and China continue to compete for global hegemony. The changes and implications of the distribution of power in Northeast Asia after 2030 are examined based on the balance of power theory. 본 연구는 현실주의의 대표적 이론인 세력균형이론을 기초로 군사력을 국가의 핵심 힘으로 전제하여 동북아시아의 힘의 분포를 살펴본다. 이전 세력균형과 군사력 수준에 관한 연구결과를 고찰하고, 그 연구한 결과를 활용하여 2020년까지 미국, 중국, 러시아, 일본, 한국과 북한의 힘의 변화를 분석하여 2030년경 안보환경을 전망하여 본다. 세력균형이론에서 국가(nation)나 국가군(a group of power) 간에 힘의 균형이 무너지면 전쟁 가능성이 높고, 그 불확실성과 불신이 높은 국제사회에서 생존과 안전을 확보하기 위하여 국가는 힘의 증강(자조, self-help)과 더불어 협력(cooperation)과 동맹(alliance)을 더욱 강화하는 행동을 한다고 본다. 동북아시아의 국가들도 자국의 군사력을 지속 증강하고 있으며, 특히 중국의 급속한 부상으로 국제 안보환경의 급격한 변화에 주변 국가들은 촉각을 세우고 경계심을 늦추지 않고 있다. 중국은 2030년대 중국 창군 100주년과 더불어 '국방 및 군현대화'를 실현하고, 2050년대 건국 100주년에 '세계일류군대건설'을 목표로 하고 있다. 그리고 미국은 국제사회의 협력과 동맹 강화 등 중국 견제에 분주하다. 미국과 중국이 패권경쟁이 진행되고 있는 상황에서 동북아시아의 안보환경과 힘의 역학관계도 서서히 변하고 있다. 세력균형이론에 기초하여 2030년 이후 동북아시아의 힘의 분포 변화와 함의를 살펴보고자 한다.

수산화칼륨을 이용한 왕겨로부터 활성탄의 제조

김명수,홍종철 ( Myung Soo Kim,Jong Chul Hong ) 한국화학공학회 1998 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.36 No.6

Activated carbon was prepared from rice hulls using potassium hydroxide as an activation agent. The effect of process variables such as carbonization, activation temperature, and chemical ratio of KOH to char on the pore structure and activation yield of the carbons was studied. High-quality activated carbons with high surface area, high pore volume, and well-developed pore structure could be prepared, when the char produced by the carbonization of rice hulls in a stream of nitrogen at 700℃ was well mixed with a concentrated solution of potassium hydroxide at a KOH : char ratio of 4 : 1 and then the mixture was activated for 3 hours at 850℃ in a stream of nitrogen.

Study of Molecular Reorientation in Liquid with Raman Spectroscopy (I). Anisotropic Rotation of CDC$l_3$ in Neat Liquid

김명수,신국조,Myung Soo Kim,Kook Joe Shin Korean Chemical Society 1982 대한화학회지 Vol.26 No.4

순수 액체상태의 $CDCl_3$의 비등방성 회전운동을 라만 스펙트럼의 ${\nu}_1$- band를 분석하여 조사하였다. 이로부터 분자의 $C_3$-대칭축에 수직한 축 주위로의 회전운동에 관계되는 확산상수($D_{II}$)는 위에서 얻은 $D_{\perp}$와$^35C$l의 NQR이완시간으로 부터 구하였다. 이렇게 구한 확산상수들은 $^2H$와 $^35C$l의 NQR 이완시간으로 부터 구한 값들과 실험오차 범위내에서 잘 일치하였다. 또한 두 확산상수들의 값들로부터 순수한 CDC$l_3$의 재배치 운동이 상당히 비등방적인 것을 알게 되었다. Anisotropic rotation of $CDCl_3$ in neat liquid is investigated by the analysis of ${\nu}_1$ band of Raman spectrum and the diffusion constant($D_{\perp}$) for the tumbling motion is obtained. The diffusion constant ($D_{II}$) for the spinning motion is obtained from the above $D_{\perp}$ value and the chlorine-35 nuclear quadrupole relaxation time. The diffusion constants thus obtained seem to agree very well with the ones obtained from $^2H$ and $^35C$l in NQR results within experimental errors. The data suggest fairly anisotropic character of reorientational motions in neat $CDCl_3$.

미국 대학교의 성공모델 - 듀크대학교

김명수,Kim, Myung-Soo 한국정보통신학회 2007 한국정보통신학회지 Vol.8 No.1

해외에서 유입된 뎅기열 1 예

김명수(Myung Soo Kim),김자경(Ja Kyung Kim),김영근(Young Keun Kim),이꽃실(Kkot Sil Lee),염준섭(Joon Sup Yeom),허애정(Ae Jung Huh),장경희(Kyung Hee Chang),송영구(Young Goo Song),김준명(June Myung Kim) 대한내과학회 2002 대한내과학회지 Vol.62 No.5

Dengue fever (DF) is an acute febrile viral disease frequently presenting with headache, bone or joint and muscular pain, rash and leukopenia. Dengue hemorrhagic fever (DHF) is characterized by four major clinical manifestations: high fever, hemorrhagic phenomena, often with hepatomegaly and in severe cases, signs of circulatory failure. Such patients may develop hypovolemic shock resulting from plasma leakage. This is called dengue shock syndrome (DSS) and can be fatal. The disease is one of the leading causes of hospitalization and death in children in several Asian, central and south American and African countries. Dengue fever and Dengue hemorrhagic fever have steadily increased in both incidence and distribution over the past 40 years. With an increased air travel, more travelers to the tropics and subtropics are returning within the incubation period of acute febrile infection. We experienced a Korean engineer with complaints of fever, chill, headache, nausea and myalgia after return from Malaysia and confirmed as dengue fever.(Korean J Med 62:548-551, 2002)

청정에너지 회수용 유증기/매연 포집모듈에 관한 연구

김명수(Kim Myung-Soo),오꾸라 시게노부(Shigenobu Ohkura),함경춘(Ham Kyoung-Chun) 한국태양에너지학회 2009 한국태양에너지학회 학술대회논문집 Vol.2009 No.11월

Traditionally, so-called "industrial waste gases", such ad exhaust from boilers at industrial installations and a large quantity of soot discharged from power station, before their release into the atmosphere, have been on occasion subjected to an air cleaning process to remove fine particles that may pollute the atmosphere (such as mist and dust containing various powdery or oily substances and moisture from industrial waste gases). The release of industrial waste gases containing these particles directly into the atmosphere poses a serious threat to the earth environment; and recovery of these noxious substances is required by law in some countries and local governments. in urban areas, air pollution from automobile exhaust and others creates a serious condition. Some homes are equipped with and use indoor air purifiers. In many of the kitchens of restaurants, smoke generated during cooking and otherwise contaminated air are cleansed by air purifiers before being released outside or recycled inside. For the dust collecting devices to recover the fine particles contained in contaminated air, the cause for air pollution and how to purify air, many types based on various principles are known. Specifically, classified based on theories of particle collection, filtration, gravity, inertia, centrifugation, electricity, and cleaning types are cited as available processes. Among them, an appropriate type is selected according to the size or type of fine particles to be collected and conditions for installation. For the efficiency of dust collection, a filtration system (by using bag filters and others) and electric system are particularly outstanding and are therefore used widely in various areas of industry. In this research, rotary type high performance oil mist and smoke collecting system with self auto cleaning device equipped with the cleaning fluid spraying section is investigated.