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Zhongyu Zhang,Caifeng Bi,Yuhua Fan,Nan Zhang,Xingchen Yan,Jian Zuo,Xia Zhang 대한화학회 2014 Bulletin of the Korean Chemical Society Vol.35 No.6
A novel complex [Zn(phen)(o-AB)2] [phen: 1,10-phenanthroline o-AB: o-aminobenzoic acid] was synthesized and characterized by elemental analysis and X-ray diffraction single-crystal analysis. The crystal crystallizes in monoclinic, space group P2(1)/c with a = 7.6397(6) Å, b = 16.8761(18) Å, c = 17.7713(19) Å, α = 90°, β = 98.9570(10)°, γ = 90°, V = 2.2633(4) nm3, Z = 4, F(000) = 1064, S = 1.058, Dc = 1.520 g·cm−3, R1 = 0.0412, wR2 = 0.0948, μ = 1.128 mm−1. The Zn(II) is six coordinated by two nitrogen and four oxygen atoms from the 1,10-phenanthroline and o-aminobenzoic acid to furnish a distorted octahedron geometry. The complex exhibits intense fluorescence at room temperature. Theoretical studies of the title complex were carried out by density functional theory (DFT) B3LYP method. CCDC: 898291.
Zhang, Zhongyu,Bi, Caifeng,Fan, Yuhua,Zhang, Xia,Zhang, Nan,Yan, Xingchen,Zuo, Jian Korean Chemical Society 2014 Bulletin of the Korean Chemical Society Vol.35 No.6
A novel complex [$Zn(phen)(o-AB)_2$] [phen: 1,10-phenanthroline o-AB: o-aminobenzoic acid] was synthesized and characterized by elemental analysis and X-ray diffraction single-crystal analysis. The crystal crystallizes in monoclinic, space group P2(1)/c with $a=7.6397(6){\AA}$, $b=16.8761(18){\AA}$, $c=17.7713(19){\AA}$, ${\alpha}=90^{\circ}$, ${\beta}=98.9570(10)^{\circ}$, ${\gamma}=90^{\circ}$, $V=2.2633(4)nm^3$, Z = 4, F(000) = 1064, S = 1.058, $Dc=1.520g{\cdot}cm^{-3}$, $R_1=0.0412$, $wR_2=0.0948$, ${\mu}=1.128mm^{-1}$. The Zn(II) is six coordinated by two nitrogen and four oxygen atoms from the 1,10-phenanthroline and o-aminobenzoic acid to furnish a distorted octahedron geometry. The complex exhibits intense fluorescence at room temperature. Theoretical studies of the title complex were carried out by density functional theory (DFT) B3LYP method. CCDC: 898291.
Assessment and comparison of three different air quality indices in China
Youping Li,Ya Tang,Zhongyu Fan,Hong Zhou,Zhengzheng Yang 대한환경공학회 2018 Environmental Engineering Research Vol.23 No.1
Air pollution index (API) is used in Mainland China and includes only SO₂, NO₂ and PM10. In 2016, air quality index (AQI) replaced API. AQI contains three more air pollutants (CO, O₃ and PM2.5). Both the indices emphasize on the effect of a single pollutant, whereas the contributions of all other pollutants are ignored. Therefore, in the present work, a novel air quality index (NAQI), which emphasizes on all air pollutants, has been introduced for the first time. The results showed that there were 19 d (5.2%) in API, 28 d (7.7%) in AQI and 183 d (50.1%) in NAQI when the indices were more than 100. In API, PM10 and SO₂ were regarded as the primary pollutants, whereas all five air pollutants in AQI were regarded as primary. Furthermore, four air pollutants (other than the CO) in NAQI were regarded as primary pollutants. PM10, as being the primary pollutant, contributed greatly in these air quality indices, and accounted for 51.2% (API), 37.0% (AQI) and 52.6% (NAQI). The results also showed that particulate matter pollution was significantly high in Luzhou, where stricter pollution control measures should be implemented.
Huang, Guimei,Zhang, Xia,Fan, Yuhua,Bi, Caifeng,Yan, Xingchen,Zhang, Zhongyu,Zhang, Nan Korean Chemical Society 2013 Bulletin of the Korean Chemical Society Vol.34 No.10
A new complex [$Ni(phen)(C_9H_8Br_2NO_3)_2{\cdot}2CH_3OH{\cdot}2H_2O$] [phen: 1,10-phenanthroline $C_9H_8Br_2NO_3$: 3,5-dibromo-L-tyrosine] was synthesized and characterized by IR, elemental analysis and single crystal X-ray diffraction. X-ray crystallography shows that Ni(II) ion is six-coordinated. The Ni(II) ion coordinates with four nitrogen atoms and two oxygen atoms from three ligands, forming a mononuclear Ni(II) complex. The crystal crystallizes in the Orthorhombic system, space group $P2_12_12$ with a = 12.9546 ${\AA}$, b = 14.9822 ${\AA}$, c = 9.9705 ${\AA}$, V = 1935.2 ${\AA}$, Z = 1, F(000) = 1008, S = 0.969, ${\rho}_{calcd}=1.742g{\cdot}cm^{-3}$, ${\mu}=4.688mm^{-1}$, $R_1$ = 0.0529 and $wR_2$ = 0.0738 for 3424 observed reflections (I > $2{\sigma}(I)$). Theoretical study of the title complex was carried out by density functional theory (DFT) method and the B3LYP method employing the $6-3l+G^*$ basis set. The energy gap between HOMO and LUMO indicates that this complex is prone to interact with DNA. CCDC: 908041.
Guimei Huang,Xia Zhang,Yuhua Fan,Caifeng Bi,Xingchen Yan,Zhongyu Zhang,Nan Zhang 대한화학회 2013 Bulletin of the Korean Chemical Society Vol.34 No.10
A new complex [Ni(phen)(C9H8Br2NO3)2·2CH3OH·2H2O] [phen: 1,10-phenanthroline C9H8Br2NO3: 3,5- dibromo-L-tyrosine] was synthesized and characterized by IR, elemental analysis and single crystal X-ray diffraction. X-ray crystallography shows that Ni(II) ion is six-coordinated. The Ni(II) ion coordinates with four nitrogen atoms and two oxygen atoms from three ligands, forming a mononuclear Ni(II) complex. The crystal crystallizes in the Orthorhombic system, space group P21212 with a = 12.9546 Å, b = 14.9822 Å, c = 9.9705 Å, V = 1935.2 Å, Z = 1, F(000) = 1008, S = 0.969, ρcalcd = 1.742 g·cm−3, μ = 4.688 mm–1, R1 = 0.0529 and wR2 = 0.0738 for 3424 observed reflections (I > 2σ(I )). Theoretical study of the title complex was carried out by density functional theory (DFT) method and the B3LYP method employing the 6-3l+G* basis set. The energy gap between HOMO and LUMO indicates that this complex is prone to interact with DNA. CCDC: 908041.
Ye Guiwen,Li Jinteng,Yu Wenhui,Xie Zhongyu,Zheng Guan,Liu Wenjie,Wang Shan,Cao Qian,Lin Jiajie,Su Zepeng,Li Dateng,Che Yunshu,Fan Shuai,Wang Peng,Wu Yanfeng,Shen Huiyong 생화학분자생물학회 2023 Experimental and molecular medicine Vol.55 No.-
Improving health and delaying aging is the focus of medical research. Previous studies have shown that mesenchymal stem cell (MSC) senescence is closely related to organic aging and the development of aging-related diseases such as osteoarthritis (OA). m6A is a common RNA modification that plays an important role in regulating cell biological functions, and ALKBH5 is one of the key m6A demethylases. However, the role of m6A and ALKBH5 in MSC senescence is still unclear. Here, we found that the m6A level was enhanced and ALKBH5 expression was decreased in aging MSCs induced by multiple replications, H2O2 stimulation or UV irradiation. Downregulation of ALKBH5 expression facilitated MSC senescence by enhancing the stability of CYP1B1 mRNA and inducing mitochondrial dysfunction. In addition, IGF2BP1 was identified as the m6A reader restraining the degradation of m6A-modified CYP1B1 mRNA. Furthermore, Alkbh5 knockout in MSCs aggravated spontaneous OA in mice, and overexpression of Alkbh5 improved the efficacy of MSCs in OA. Overall, this study revealed a novel mechanism of m6A in MSC senescence and identified promising targets to protect against aging and OA.
Hong Zhou,Youping Li,Huifang Liu,Zhongyu Fan,Jie Xia,Shanli Chen,Yuxiang Zheng,Xiaocui Chen 대한환경공학회 2015 Environmental Engineering Research Vol.20 No.3
The PM10, SO₂ and NO₂ mass concentrations were obtained over five years from monitoring stations across Nanchong, a southwest city in China. Changes in urban air quality over time, as well as the factors influencing that change, were evaluated based on air pollutant concentrations, the Air Pollution Index (API), and the Comprehensive Pollution Index (P). The results showed that the total annual mean PM10, SO₂ and NO₂ concentrations over the five years studied were 61.1±1.1, 45.0±3.9 and 34.9±4.9 μg·m-3, respectively. The annual mean concentrations displayed a generally decreasing trend; lower than the annual mean second-level air quality limit. Meanwhile, the annual mean API values were in a small range of 52-53, the air quality levels were gradeⅡ, and P values were 1.06-1.21 less than the slight level (P ≤ 1.31). Total monthly mean PM10, SO₂, NO₂ concentrations, and API and P values were consistently higher in winter and spring than during autumn and summer. The results of a correlation analysis showed that temperature and pressure were the major meteorological factors influencing pollution levels. Pollution sources included industrial coal and straw burning, automobiles exhaust and road dust, fireworks, and dust storms.