GC-ECD를 이용한 유기염소계 및 Pyrethroid계 농약 동시 분석법

김우성,이선화,김재이,정지윤,이명자,박영채,이영자,정성욱,이봉헌,박흥재 한국환경과학회 2003 한국환경과학회지 Vol.12 No.4

Pesticides were extracted from samples with 70% acetone and methylene chloride in order, and then cleaned up via open-column chromatography apparatus packed with florisil, and finally analyzed simultaneously the organochlorine and pyrethroid pesticides using GC(ECD). An ultra-2 fused silica capillary column was used to separate and identify the products. The resolution between the last isomeric peak of cypermethrin(59.987min) and the first isomeric peak of flucythrinate(60.043min) was not satisfactory. The last isomeric peak of fenvalerate(62.344min) and the first isomeric peak of fluvalinate(62.397min) were overlapped. Recoveries of soybean sample for the most pesticides were 73.3% to 102.4%. Detection limits were between 0.004 and 0.063 ㎍/㎎ when this method was used.

GC/NPD를 이용한 다성분 잔류농약의 동시분석

김우성,이선화,김상엽,정동윤,김재이,이영자,이홍재,정성욱,박흥재 한국환경과학회 2003 한국환경과학회지 Vol.12 No.10

Pesticides were extracted from samples with 70% acetone and methylene chloride in order, and then cleaned up via open-column chromatography apparatus packed with fiorisil, and finally analyzed simultaneously the organophosphorus pesticides using GC/NPD, Ultra-2 and Ultra-1 fused silica capillary columns were used to separate and identify the products. Recovery of most analytes from soybean sample, taken from pesticide residues well, was greater than(80%) for all except(6) analytes. This method can simultaneously determine multiple pesticides with a high degree of accuracy and precision.

Improvement of Thermoplastic Forming Ability of Ti–Zr–Ni–Cu Metallic Glass by Addition of Sn

Yeong‑Seong Kim,Woo‑Chul Kim,Won‑Tae Kim,Do‑Hyang Kim 대한금속·재료학회 2021 METALS AND MATERIALS International Vol.27 No.6

Ti–Zr–Ni–Cu metallic glass attracts an attention as a precursor of superelastic alloy that can be deformed into nm scalecomplex shapes. However, since the thermal stability of Ti–Zr–Ni–Cu metallic glass in the supercooled liquid region is quitelow, application of thermoplastic forming is limited. Therefore, in the present study, the effect of Sn addition on thermoplasticforming ability of Ti–Zr–Ni–Cu metallic glass has been investigated. Sn containing (Ti35Zr15Ni35Cu15)99Sn1 metallic glassexhibits longer incubation time before onset of crystallization than Ti35Zr15Ni35Cu15metallic glass, resulting in significantimprovement of thermoplastic forming ability. The crystallization behavior changes from three-dimensional growth of saturatednuclei to three-dimensional growth with constant nucleation rate with the addition of Sn. The overall activation energyfor crystallization of (Ti35Zr15Ni35Cu15)99Sn1 metallic glass is higher than that of Ti35Zr15Ni35Cu15metallic glass, indicatingthat the thermal stability of metallic glass is improved by addition of Sn. Because nuclei are continuously generated duringthe crystallization in (Ti35Zr15Ni35Cu15)99Sn1, the average grain size is much smaller than that in Ti35Zr15Ni35Cu15.

8년간(1992~1999) 산업안전보건연구원에 의뢰된 직업병 심의 사례 분석

강성규,김규상,김양호,최정근,안연순,진영우,최병순,양정선,김은아,채창호,최용휴,김대성,박정선,정호근 대한산업의학회 2000 대한직업환경의학회지 Vol.12 No.2

Objectives : Pneumoconisis and noise-induced hearing loss (NIHL) have been reported as main occupational diseases by the Special Health Examination. The Industrial Accident Compensation Insurance has reported various work-related diseases, however, these two diseases occupied almost a half of compensated cases. Therefore, it was not well known about the status of occupational diseases other than pneumoconiosis, NIHL, and cardio-cerebrovascular accident (CVA). This study was conducted to analyze claimed cases as an occupational disease, that was requested to the Korea Industrial Safety and Health Agency (KOSHA). Methods : The local office of the Korea Labor Welfare Corporation (KLWC) has asked the KOSHA for confirmation of claimed cases as an occupational disease. We analyzed 379 cases requested from KLWC, the Ministry of Labor, employers, unions and occupational health agencies from 1992 to 1999. Results : Male was 80.7 % of the requested cases. Their mean age was 42 years old and 75.5 % of them were more than 35 years old. The requested cases were increased rapidly from 25 cases in 1992 to 108 cases in 1999 and the accept rate was 50.7 %. The majority of requested cases were respiratory diseases(22.4%), cancers(18.5%), Neuropsychiatric problems(14.5%), and musculoskeletal problems(13.5%). The accept rate was high in reproductive, respiratory, musculoskeletal and digestive disorders and low in neuropsychiatric, renal and otologic problems and occupational cancers. 73.6% of them were caused by chemical agents, especially 28.5 % were by organic solvents. 67% of them were clinically confirmed at university hospitals. A half of the cases were from KyongIn area, even the request came from the whole country. Conclusions : A claim was common in workers whose age was over 35 years old and exposure history was over 10 years. The respiratory diseases and neuropsychiatric disorders were still main problems in occupational health and occupational cancers was increasing even though its accept rate was not high yet.

고정 흡착층에서 벤젠과 톨루엔의 단일 및 이성분 흡착특성

김한수,박영성 대전대학교 환경문제연구소 2001 환경문제연구소 논문집 Vol.5 No.-

The effects of various parameters, such as adsorption temperature, interstital velocity, concentration of adsorbates and sapect ratios(L/D) of the fixed bed, on the adsorption characteristics referring to single and binary component were studied in a fixed bed of an activated carbon. For the single component, the break point decreased with increasing the adsorption temperature, interstitial velocity and concentration of adsorbates. Interstitial velocity, concentration of adsorbates and adsorption temperature had considerable influence upon the MTZ and LUB that obtained through the breakthrough curves. An adsorption isotherm of benzene and toluene was determined with single component, Langmuir, Freundlich and Langmuir-Freundlich isotherm agreed with experimental data fairly well. For the binary component, the adsorption breakthrough curve of key component(toluene) was sigmoidal as in the case of the single component system. However, the breakthrough curve of non-key component(benzene) was entirely different from that of the single component adsorption process. The mageitude of roll up increased with increasing concentration of adsorbates and aspect ratio of the fixed bed, and decreased with increasing interstitial velocity.

行政哲學에 관한 硏究 : 理論과 實際的 觀點에서 On the Perspective of Theory and Practice

金永聲,鄭光朝 충남대학교 법률행정연구소 1986 논문집 Vol.14 No.-

주정폐수의 혐기성 소화처리시와 포기처리시 처리특성에 관한 연구

金煥起,李城白,黃譚勇 全北大學校 附設 都市및環境硏究所 1996 都市 및 環境硏究 Vol.11 No.1

The wastewater of alcohol manufactory plant has very high suspended soild and BOD concentration, acidity, and high temperture. Thus most of the plants drive on anaerobic digestion method of biological treatment because of using a lot of generated methane gas and possible to disinfect pathogenic bacteria in sluge and wastewater. But because of the problem in the concentration of anaerobic treatment water, second treatment is necessary 2-step activated treatment for increasing treatment efficiency. The purpose of this study was performed to know a difference between last 1-step digestion 1-step aeration treatment and 2-step digestion 2-step aeration treatment with retention time in digestion and aerator. The obtained results can be summarized as follows; 1. The concentration characteristic of alchohol production wastewater was analyzed COD 50,000∼80,000㎎/ℓ, BOD 22,000∼41,000㎎/ℓ, SS 20,000∼45,000㎎/ℓ, pH 4.1∼4.2, and 75∼80℃ according to the raw material of alchohol. 2. In case of the anaerobic digestion method of rice-barley wastewater, average COD removal rate of 2-step digestion appeared to 91.9% compared to average COD removal rate 59.3% on 1-step digestion. It is necessary to drive above 20 day of retention time in metane degestor because of increasing organic load causing the decrease of pH and the increase of VFA/COD within aerator. 3. Alcohol wastewater of tapioka is generally much treatment efficiency of 2-step digestion than that of 1-step digestion, but below 2.7㎏-COD/㎥·d of COD bulk load showed the possibility of treatment at 1-step and 2-step digestion method. 4. Amount of gas generation in anaerobic digestion was almost similar at 1-step and 2-step digestion. 5. In the result of aerobic treatment, treatment efficiency of 2-step consecutive aeration was highly about 3% compared to 1-step combined aeration and in the condition of COD 4,000㎎/ℓ, COD load 800㎏ -COD/d, COD volume-load 0.8㎏-COD/㎥·d were difficult two treatment methods both. 6. pH and VFA concentrations are considered as important factors to determine VFA restriction and the harmfulness of fatty acid was seemed to be related to pH. VFA in 1-step digestion appeared strong change with the increase of input wastewater quantity, but 2-step digestion was treated to stable change in output COD 1,230∼2,246㎎/ℓ.

韓國行政學의 發達過程과 土着化方案에 관한 硏究

金永聲,申基源 충남대학교 법률행정연구소 1989 논문집 Vol.17 No.-

유전체로 둘러싸인 속빈 직육면체 도파관을 사용한 레이저 공진기에서 횡특성모드의 왕복손실

金允溟,金永植,李鍾旿,徐七成,박재우 단국대학교 1989 論文集 Vol.23 No.-

The round-trip losses of CO_2 laser wavelength in a hollow rectangular dielectric waveguide with external spherical mirrors are calculated. The propagative attenuations of some higher order modes with different polarization are analyzed as well as EH_11 fundamental mode. Computations of the losses in coupling radiation of various modes from the guide into free space and back into the guide, as a function of mirror curvature and position, are also presented. The overall return losses of various modes are the sum of the two kinds of losses.

장기 이식 환자에서 Voriconazole 과 Cyclosporine 또는 Tacrolimus의 상호작용

한혜원,김재연,송영천,김승은,유성길 한국병원약사회 2009 병원약사회지 Vol.26 No.1

Abstract: In organ transplant patients, the opportunity of fungi infections such as invasive aspergillosis increase by use of immunosuppresant drugs and voriconazole is recommended as primary treatment drug. When voriconazole is administered with cyclosporine(CsA) or tacrolimus(FK506), caution about increment of blood CsA or FK506 concentrations that caused by the change of CYP3A4 activity is required but few domestic cases of interaction were reported yet, The purpose of this study was to assess the effect of voriconazole on the blood CsA or FK506 concentrations in transplant recipients and the factors of recipients that have an effect on the results. 25 transplant recipients who were administered voriconazole with CsA or FK506 from January 1 of 2006 to August 17 of 2008 in Asan Medical Center were objects (12 patients on CsA coadministration arm - 9 males, 3 females; 41~62years;2 liver, 2 kidney, 3 bone marrow, 5 heart transplant recipients, and 13 on FK506 coadministration arm - 7 males, 6 females;26~65years; 10 liver, 2 kidney, 1 heart transplant recipients). Blood CsA or FK506 concentrations before and after coadministration of voriconazole, and maximum concentration in one month from the first day of coadministration were monitored retrospectively. In most cases CsA or FK506 were administered as recommended doses regardless of coadministration of voriconazole, and blood concentration increased from 239.42±126. 77ng/ml to maximum 411.92±225. 76ng/ml in CsA coadministration arm(p=0.003), and from 7.72±2.79ng/ml to maximum 19.16±9.35ng/ml in FK506 coadministration arm(p=0.003). Gender, age, and the kind of transplant organ did not affect to the change of blood concentration in both two arms. In consequences, administration of voriconazole could affect on the blood CsA or FK506 concentration, and in cases of administra tion of voriconazole in transplant recipients treated with CsA or FK506, close monitoring and dose adjustment is needed.