Addition of V2O5-MnO2/USY-zeolite catalyst in PTFE fiber for bag filter and its catalytic activity tests for NH3-SCR at low-temperature

Jin Ho Boo,Eunseok Kim,Byung Chan Kwon,Myung Jo Seo,Ji Man Kim,Ji Bong Joo,Dohyung Kang,No-Kuk Park 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.123 No.-

This study investigated the catalytic activity of vanadium-manganese supported on USY-zeolite as a catalystfor low-temperature NO removal, and embedded the powder catalyst in PTFE filter of bag filter. TheV2O5-MnO2/USY-zeolite catalyst was prepared using the co-impregnation method, and the V2O5/MnO2ratio was 0/10, 2.5/7.5, 5/5, 7.5/2.5, or 10/0. The catalytic activity test for NH3-SCR(selective catalyticreduction) of NO was performed at 150–230 C. An enhanced NO conversion above 60% was exhibitedin the low-temperature region below 230 C, and the NO removal efficiency increased as the MnO2 contentincreased. The NH3-TPD and NO-TPD(Temperature Programmed Desorption) analysis confirmed thatthe NH3 adsorption of the catalyst more significantly influences the NO removal performance than the NOadsorption. As the MnO2 content on the catalysts increased, the strength and amount of adsorbed NH3increased, resulting in enhanced NO conversion. The catalyst-embedded PTFE (polytetrafluoroethylene)fiber was prepared by extruding physically mixed PTFE and catalyst powder. Scanning electron microscopy/energy dispersive X-ray spectroscopy confirmed that the catalyst was well dispersed on the surfaceand inside the PTFE fiber. The NO removal performance of the catalyst included PTFE fiber increased asthe amount of the catalysts added was increased.

Hatta No.(MH)와 Enhancement Factor(E)가 고려된 수용 BPA의 오존 산화 모델 적용성 연구

박노석(No Suk Park),김성은(Sung Eun Kim),김정현(Jeong Hyun Kim),배철호(Chul Ho Bea),민진희(Jin Hui Min),안효원(Hyo Won Ahn) 大韓環境工學會 2004 대한환경공학회지 Vol.26 No.12

119구급차로 이송된 환자의 병원 전 전문응급처치에 관한 조사

박진옥,이경희,노상균,최청숙 한국응급구조학회 2003 한국응급구조학회지 Vol.7 No.1

An analysis was performed to evaluate the prehospital advanced emergency care in Emergency Medical Service system(EMS) through the review of the 119 transport records of 190 patients who visited to Jecheon Seoul hospital emergency center at Chungpuk Jecheon via 119 system during the period from October 2002 to September 2003. The results were obtained as follows: 1. Among 190 patients, male were 127(66.8%) and female were 63(33.2%) and non-traumatic patients were 81(42.6%) and traumatic patients were 109(57.4%). 2. The analysis of prehospital care by Emergency Medical Technician(EMT) revealed that Airway maintenance and keeping oral airway(37.7%), oxygen supply(75.9%), Tourniquett or MAST(18.9%), Immobilization of neck or spine(94.7%), Immobilization of extremities(51.4%), wound bandage and dressing(25.0%), BCLS(12.1%) and Application of AED(2 patients). 3. The analysis of prehospital care by EMT revealed prehospital care was limited to keep of intubation or LMA, medication and IV insertion, insertion of gastric tube and ACLS. 4. There was no case of the notification to medical institute or consultation to doctor.

천연제올라이트를 지지체로 사용한 고온건식 아연계 탈황제의 반응특성 연구

박노국,정용길,이종대,이태진,김재창 한국화학공학회 2003 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.41 No.5

고온건식 탈황제의 지지체로 알루미나와 천연제올라이트를 사용하여 아연계 탈황제를 제조하였으며 성능을 조사하였다. 두 가지 탈황제의 반응특성실험은 480℃/580℃(황화/재생온도)에서 칸 밸런스와 고정층 반응장치로 반응속도와 황수용능력을 비교하였으며 내마모 실험장치를 이용하여 탈황제의 내마모도를 조사하였다. 두 탈황제의 성능 실험결과 천연제올라이트를 지지체로 사용한 탈황제의 초기 황화반응속도가 알루미나를 지지체로 사용한 탈황제보다 빨라졌으며, 10 cycle에서 황수용능력이 20 gS/100 g sorbent 이상 유지되었다. 내마모성은 AI(마모지표)값이 14.7%정도였다. 본 연구에서는 천연제올라이트의 고온건식 탈황제의 지지체로 적용 가능성을 확인하였다. Two types of zinc-based sorbents using alumina and natural zeolite as the supports for hot-gas desulfurization were prepared, and investigated their desulfurization capability. Their reaction rate and sulfur capacity were compared by Cahn balance and over the fixed bed reactor system at 480℃/580℃ (sulfidation/regeneration). The attrition resistance was measured by ASTM methd. Thc initial sulfidation rate of ZnO/natural zeolite sorbent was higher than that of ZnO/alumina, and the sulfur capacity of ZnO/natural zeolite sorbent was maintained above 20 gS/l00 g sorbent for 10 cycles. A attrition index was 14.7%. The use of natural zeolite as a support of sorbents may be possible for hot gas desulfurization.

CO/CO_2혼합 gas를 이용한 산화텅스텐(WO_3) 환원-탄화 반응에 관한 연구

박영효,이종대,박노국,이태진 嶺南大學校 工業技術硏究所 2003 工業技術硏究所論文集 Vol.31 No.1

The reduction-carburization of tungsten oxide(WO_3) with CO/CO_2 mixtures was studied. The reduction rate was increased with the concentration of CO. The final products at 1100℃ were WC(CO concentration: 90∼100 vol%), W (CO concentration: 85 vol%) and WO_2 (C0 concentration: 70 vol%). For the CO concentration of 100 vol%, the general reaction routes were WO_3 → W_20O_58 → W_18O_49 → WC (reaction temperature: ­600℃), WO_3 → W_20O_58 → W_18O_49 → WO_2 → WC (reaction temperature: 600∼800℃) and WO_3 → W_20O_58 → W_18O_49 → WO_2 → W → WC (reaction temperature: +900℃).

고온에서 황화수소 제거를 위한 Fe₂O₃탈황제의 반응성

박노국,김장희,이태진 嶺南大學校 環境問題硏究所 1994 環境硏究 Vol.14 No.1

석탄가스화의 고온건식탈황제 개발을 목적으로 철계 탈황제를 선정하여 Fe₂O₃의 함량을 61.8%, 30.0% 그리고 10.0%로 변화시킨 3종류의 탈황제에 대하여 탈황 및 재생반응을 조사하였다. 먼저 H₂S의 제거효율이 가장 최적인 반응온도를 찾기 위하여 출구에서의 농도변화를 GC-TCD로 분석하였으며, SEM 사진 분석결과 최적의 H₂S 제거효율을 나타내는 온도는 500℃로 나타났다. 탈황-재생반응을 반복적으로 수행하였으며, 황화반응은 H₂S와 (H₂+ CO + CO₂+ N₂)의 혼합가스를 사용하여 500℃에서, 재생반응은 O₂-N₂의 혼합가스로 800℃에서 각각 수행하였다. Fresh한 탈황제, 황화반응 및 재생반응 후의 탈황제 SEM사진과 XRD 특성도 비교 조사하였다. 그리고 반응기 출구에서 H₂S 농도의 파과곡선으로부터 탈황제의 성능을 비교하였다. Several Fe₂O₃sorbents were investigated as regenerable sorbents for the removal of H₂S at high temperature. To find optimal temperature of the reaction between H₂S gas and Fe₂O₃sorbent, the effluent gas from a fixed-bed reactor was analysed by GC-TCD. The experimental results showed that H₂S removal efficiency of sorbent was optimum at 500℃ and SEM data were in accordance with this feature. The sorbents were subjected to successive sulfidation-regeneration cycles. Sulfidation was carried out at 500℃ with H₂S-(H₂+CO+CO+N₂)mixtures, regeneration with O₂-N₂mixtures. Fresh, sulfided, and regenerated sorbents were characterized by SEM and XRD. Breakthrough exit concentration of H₂S is discussed in term of physical structure of the sorbents.

두경부에 발생한 모기질종 2예

박진복,김민정,강신노,김종애 침례병원 2003 浸禮病院學術誌 Vol.19 No.-

DEM의 정확도 분석에 의한 도시 소유역의 유출해석

박진형,이관수,이삼노 한국지리정보학회 2004 한국지리정보학회지 Vol.7 No.1

본 연구는 수치지형자료의 해상도와 보간법의 변화에 따른 정확도 분석을 실시하여 도시소유역의 유출현상을 해석하고자 하였다. 수치자료는 격자크기별로 TIN 보간법을 이용하여 DEM 자료를 생성하고, 정확도 분석은 수치지도의 등고선을 이용하여 결정계수(R2)와 회귀식을 도출하였다. 검증된 DEM 자료를 사용하여 소유역구분, 면적, 유역폭, 지면경사도 등의 지형인자를 추출하여 도시유출모형에 적용시켜 여서-문수지구의 도시 소유역에 가장 적합한 유출모형을 알아보고자 한다. 모형의 적용 결과 SWMM의 유출수문곡선이 ILLUDAS의 유출수문곡선보다 실측값에 더 근사하게 나타났고, SWMM의 경우 실측값과 최대 19%, 최소 5%, 평균 13%의 오차를 나타냈다. 본 연구대상지역과 같은 도시소유역은 강우지속시간이 첨두도달시간에 미치는 영향은 미미하게 나타났다. 본 연구의 결과로 SWMM 모형이 여서-문수지역의 도시유출모형으로 적합하며 적용면에서도 더 다양한 기능과 정확성을 나타낸다고 판단된다. The purpose of this study is to analyze the urban hydrologic state by the use of GIS, resolution and interpolation. The determination coefficient(R2) and Regression Formula were derived from the contour of digital map for the accuracy, and DEM data was made by using TIN interpolation by the size of the grid. By using the observed DEM data, topographical factors were extracted from the small basin, size, the width of a basin and the slope, and were applied in the urban runoff model. Through the model, we tried to find out the most suitable runoff model in a small basin of Yosu-Munsu area. As a result of applying models to the drainage considered, the runoff hydrograph estimated by SWMM model was closer to the observed one than that estimated by ILLUDAS model. The difference between the runoff hydrograph by SWMM and the observed one is maximum error of 19%, minimum error of 5% and average error of 13%. The influence of duration in contrast to pick time is insignificant in a urban small basin. As a conclusion of this study, SWMM model was more suitable and applicable for the urban runoff model than ILLUDAS model due to its accuracy and various abilities.

탄산칼슘의 고온건식 탈황반응성 연구

박노국,유성구,서길수,이태진 영남대학교 공업기술연구소 2000 工業技術硏究所論文集 Vol.28 No.2

The sulfidation reaction of calcium carbonate to remove H2S were investigated. Expecially, the effect of polymorphs of calcium carbonate and reaction temperature on the sulfur capture were determined. It was found that calcination reaction of calcium carbonate were influenced by polymorphs of calcium carbonate. The calcination temperatures of aragonite were lower than those of other calcium carbonates. For the sulfidation of calcite with H2S, the effect of reaction temperature on the sulfur capture were not found. But in caes of vaterite and aragonite, the reaction temperature were found to have a significant effect on the sulfidation reaction. From in these results, optimum temperatures of sulfidation reaction using vaterite and aragonite were determined at 800∼850℃ and 750℃, respectively.

다운 증후군과 동반된 그레이브스병 1예

노혜정,신진호,김하영,김용성,백승훈,박병현,조정구 圓光大學校 醫科學硏究所 2005 圓光醫科學 Vol.20 No.1