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      • KCI등재

        Enhanced ionic conductivity of composite solid electrolyte by directionally ordered structures of linear Li1.3Al0.3Ti1.7(PO4)3

        You Li,Mulan Tang,Shuxin Xu,Shuchao Zhang,Yuxin Zhai,Jiarong Yin,Zhengguang Zou 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.114 No.-

        The NASICON-type solid electrolyte structure of Li1.3Al0.3Ti1.7(PO4)3 (LATP) exhibits good electrochemicalperformance and thermal stability, and has been promising as a solid electrolyte. Here, a stable goodstabilityLATP precursor spinning solution was prepared using the sol–gel method for the first time. A linearLATP solid electrolyte with an oriented ordered structure was obtained using improved electrostaticspinning equipment. The sintering process regime of the LATP-ordered construction was determined. Theionic conductivity of the prepared LATP-PEO/LiClO4-PEG composite solid-state electrolyte with anordered structure was as high as 2.05 10-4 Scm1 at room temperature (25 C), one order of magnitudehigher than the ionic conductivity of the LATP composite solid-state electrolyte reported so far. Organicsolid-state electrolytes to protect LATP-ordered structured solid-state electrolytes yield excellent electrochemicalstability in lithium-metal batteries.

      • KCI등재

        Intratumoral Heterogeneity of Breast Cancer Xenograft Models: Texture Analysis of Diffusion-Weighted MR Imaging

        윤보라,조나리야,Mulan Li,장민혜,박소연,강호철,김보형,송인찬,문우경 대한영상의학회 2014 Korean Journal of Radiology Vol.15 No.5

        Objective: To investigate whether there is a relationship between texture analysis parameters of apparent diffusion coefficient (ADC) maps and histopathologic features of MCF-7 and MDA-MB-231 xenograft models. Materials and Methods: MCF-7 estradiol (+), MCF-7 estradiol (-), and MDA-MB-231 xenograft models were made with approval of the animal care committee. Twelve tumors of MCF-7 estradiol (+), 9 tumors of MCF-7 estradiol (-), and 6 tumors in MDA-MB-231 were included. Diffusion-weighted MR images were obtained on a 9.4-T system. An analysis of the first and second order texture analysis of ADC maps was performed. The texture analysis parameters and histopathologic features were compared among these groups by the analysis of variance test. Correlations between texture parameters and histopathologic features were analyzed. We also evaluated the intraobserver agreement in assessing the texture parameters. Results: MCF-7 estradiol (+) showed a higher standard deviation, maximum, skewness, and kurtosis of ADC values than MCF-7 estradiol (-) and MDA-MB-231 (p < 0.01 for all). The contrast of the MCF-7 groups was higher than that of the MDA-MB-231 (p = 0.004). The correlation (COR) of the texture analysis of MCF-7 groups was lower than that of MDA-MB-231 (p < 0.001). The histopathologic analysis showed that Ki-67mean and Ki-67diff of MCF-7 estradiol (+) were higher than that of MCF-7 estradiol (-) or MDA-MB-231 (p < 0.05). The microvessel density (MVD)mean and MVDdiff of MDA-MB-231 were higher than those of MCF-7 groups (p < 0.001). A diffuse-multifocal necrosis was more frequently found in MDA-MB-231 (p < 0.001). The proportion of necrosis moderately correlated with the contrast (r = -0.438, p = 0.022) and strongly with COR (r = 0.540, p = 0.004). Standard deviation (r = 0.622, r = 0.437), skewness (r = 0.404, r = 0.484), and kurtosis (r = 0.408, r = 0.452) correlated with Ki-67mean and Ki-67diff (p < 0.05 for all). COR moderately correlated with Ki-67diff (r = -0.388, p = 0.045). Skewness (r = -0.643, r = -0.464), kurtosis (r = -0.581, r = -0.389), contrast (r = -0.473, r = -0.549) and COR (r = 0.588, r = 0.580) correlated with MVDmean and MVDdiff (p < 0.05 for all). Conclusion: The texture analysis of ADC maps may help to determine the intratumoral spatial heterogeneity of necrosis patterns, amount of cellular proliferation and the vascularity in MCF-7 and MDA-MB-231 xenograft breast cancer models.

      • KCI등재

        Facile Synthesis of Nanosheet-Structured V2O5 with Enhanced Electrochemical Performance for High Energy Lithium-Ion Batteries

        Shuquan Liang,Mulan Qin,Yan Tang,Qing Zhang,Xilin Li,Anqiang Pan 대한금속·재료학회 2014 METALS AND MATERIALS International Vol.20 No.5

        Nanosheet-structured vanadium pentoxide (V2O5) has been fabricated by a sol-gel method. As revealed bythe TEM, the as-synthesized V2O5 crystallites are composed of layer-by-layer stacked nanosheets. As acathode material for lithium batteries, it exhibits much better electrochemical performance than the startingcommercial V2O5 powders. A high specific discharge capacity of 264 mA h g-1 can be obtained for thenanosheet-structured electrodes, which retains the capacity of 90% after 50 cycles. However, the commercialV2O5 only delivers a specific discharge capacity of 206 mA h g-1 with a capacity retention of 64%after 50 cycles. Moreover, the nanosheet-structured V2O5 electrodes show much-improved C-rate capability. The superior cycling performance demonstrates that the nanosheet-structured V2O5 is a promising cathodematerial in lithium-ion battery applications.

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