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Longbao Yu,Zhefei Ye,Jinze Li,Chunhong Ma,CHANGCHANG MA,XINLIN LIU,Huiqin Wang,Lili Tang,Pengwei Huo,Yongsheng Yan 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.6
A series of hamburger-like Ag@ZnO/C core–shell plasmonic photocatalysts have been synthesized via a simple solvothermal method for degradation of tetracycline (TC) under visible light irradiation, possessing high photocatalytic activity and good stability. The presence of localized surface plasmon resonance (LSPR) in the Ag core has increased the photocatalytic activity over an extended wavelength range. The plasmon-induced resonant energy transfer (PIRET) and direct electron transfer (DET) have facilitated the excitation and separation of photogenerated e-/h+pairs, which has been further confirmed by electrochemical investigations. The presences of hydroxyl radicals ( ·OH), superoxide radicals ( · O-2) and singlet oxygen (1O2) in the photocatalytic reaction system of Ag@ZnO/C photocatalyst have been demonstrated by electron spin resonance (ESR) measurements. All of the experiment results indicate that the ternary structure of Ag@ZnO/C can effectively enhance the photocatalytic activity. Furthermore, the effects of introduced Ag contents and carbon source dosage were researched by comparative photocatalytic experiments, and the potential structures of photodegradation products were studied by HPLC-MS.
Fusheng Zhang,Enxiu Liu,Xudong Zheng,Longbao Yu,Yongsheng Yan 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.58 No.-
An optical sulfonamides sensor is fabricated based on a molecular imprinted resin templated bynanocrystalline cellulose. A chiral nematic imprinted compositefilm is synthesized which issubsequently treated with removal of templates to generate a red reflecting photonicfilm. Thefilmshows a naked-eye color response to sulfanilamide, which is related to reassemble imprinted sites in thechiral nematic structure, resulting in a yellow reflectingfilm. Upon exposure to various antibiotics, it canbe simultaneously in selectively response to three sulfonamides. This strategy facilitates enormouslypotential application of the resin as battery-free and portative optical monitoring sensors.
Fabrication of free-standing fluorescent mesoporous silica films for detection of nitrobenzene
Fusheng Zhang,Xudong Zheng,Enli Liu,Longbao Yu,Yongsheng Yan 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.46 No.-
We report a facile two-step strategy for grafting lanthanide complexes onto the surface of nanocrystallinecellulose-templated mesoporous silicafilms to prepare luminescence mesoporous silicafilms, whichretain both chiral nematic order of the cellulose nanocrystals andfluorescence of the lanthanidecomplexes are successfully co-assembled after removal of the cellulose and grafting lanthanidecomplexes. Thefilms exhibit well-definedfluorescence combining the assembly lanthanide complexes. The mesoporous channels offluorescent mesoporous silicafilms are more accessible to the analytescompared with traditionalfluorescent materials. So, ourfluorescent mesoporous silicafilms were used asfluorescent sensor for the detection of nitrobenzene.
Pengwei Huo,Yanfeng Tang,Mingjun Zhou,Jinze Li,Zhefei Ye,CHANGCHANG MA,Longbao Yu,Yongsheng Yan 한국공업화학회 2016 Journal of Industrial and Engineering Chemistry Vol.37 No.-
ZnWO4-CdS heterostructure photocatalysts have been successfully synthesized by hydrothermalmethod with assembling CdS on the surface of ZnWO4. The obtained composite photocatalysts werecharacterized by X-ray diffraction, transmission electron microscopy, Raman, thermo-gravimetricanalysis, UV–vis diffuse reflectance spectroscopy, photoluminescence and photocurrent measurement. The results show that the interface between ZnWO4 and CdS is well formed, and the CdS nanoparticlesare uniformly distributed onto ZnWO4 nanorods which could facilitate charge transfer and reducerecombination of photo-generated electrons and holes. Compared with pure ZnWO4 and CdS, the aspreparedheterostructure photocatalysts exhibit excellent photostability and photodegradation abilityof ciprofloxacin (CIP) under visible light irradiation.
Gas phase dehydration of glycerol catalyzed by rutile TiO_2-supported heteropolyacids
Lingqin Shen,Aili Wang,Hengbo Yin,Yonghai Feng,Longbao Yu,Tingshun Jiang,Yutang Shen,Zhanao Wu,박은덕 한국공업화학회 2011 Journal of Industrial and Engineering Chemistry Vol.17 No.3
Gas phase dehydration of glycerol catalyzed by the rutile TiO2-supported heteropolyacids was investigated. The TiO_2-supported heteropolyacid catalysts were prepared by the incipient wetness impregnation method using silicotungstic, phosphotungstic, and phosphomolybdic acids as active compounds. The as-prepared catalysts were characterized by X-ray diffraction, infrared spectroscopy,temperature programmed desorption of ammonia, and surface area measurement. The heteropolyacids supported by rutile TiO_2 were crystallites. The catalytic activity of the catalysts in the gas phase dehydration of glycerol was significantly affected by the type and loading of heteropolyacids. TiO_2-supported silicotungstic acid (20 wt.%) catalyst showed the highest catalytic activity with an acrolein selectivity of 80 mol% at a conversion of glycerol of 99% and a reaction temperature of 280 8C under ambient pressure. The possible reaction route in the gas phase dehydration of glycerol catalyzed by the TiO_2-supported heteropolyacid catalysts was also discussed briefly.
Acylation of salicylamide to 5-acetylsalicylamide using ionic liquids as dual catalyst and solvent
Weiguang Chen,Yunsheng Zhang,Zhangzhun Lu,Aili Wang,Yutang Shen,Tingshun Jiang,Longbao Yu,Hengbo Yin 한국공업화학회 2010 Journal of Industrial and Engineering Chemistry Vol.16 No.5
The Lewis acidic ionic liquids, 1-butyl-3-methylimidazolium chloroaluminate ([BMIM]Cl-nAlCl3) and Nbutylpyridinium chloroaluminate ([BPy]Cl-nAlCl3), were used as both catalyst and solvent in Friedel–Crafts acylation of salicylamide with acetyl chloride to 5-acetylsalicylamide. The Lewis acidic ionic liquids, substituting for the conventional carcinogenic nitrobenzene solvent and anhydrous AlCl3catalyst, showed excellent catalytic activity in the acylation of salicylamide to 5-acetylsalicylamide. When [BMIM]Cl-2AlCl3 was used as the catalyst, the yield of 5-acetylsalicylamide reached 81.3%. When [BPy]-2AlCl3 was used as the catalyst, the maximum yield of 5-acetylsalicylamide was 89.2%. The content of AlCl3 and the structure of the cations in the ionic liquids had synergistic effect on the acylation reaction. 2010 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
Oxidation of cyclopentene catalyzed by phosphotungstic quaternary ammonium salt catalysts
Jinjuan Xue,Aili Wang,Jingbo Wang,Dongzhi Zhang,Weiguang Chen,Longbao Yu,Tingshun Jiang,Hengbo Yin 한국공업화학회 2010 Journal of Industrial and Engineering Chemistry Vol.16 No.2
A series of phosphotungstic quaternary ammonium salts, Q3 (PW12O40) and Q3(PW4O16) [Q = (C5H5)N+(C16H33), (C16H33)N+(CH3)3, (C4H9)4N+, and (CH3)4N+], were used as the catalysts in oxidation of cyclopentene. The catalysts [(C5H5)N(C16H33)]3(PW4O16) and [(C16H33)N(CH3)3]3(PW4O16) showed high catalytic activity in the selective oxidation of cyclopentene while using H2O2 (50%) as an oxidant and 2-propanol as a solvent. The oxidation products mainly consisted of glutaraldehyde, cis-1,2-cyclopentanediol and trans-1,2-cyclopentanediol. The above-mentioned two catalysts were dissolved completely in the reaction medium during the catalysis process and precipitated themselves from the reaction system after reaction, showing the characteristics of reaction-controlled phase-transfer catalysis. The types of quaternary ammonium cations and the phosphotungstic anions in phosphotungstic quaternary ammonium salts affected catalytic activity.
Dongzhi Zhang,Chen Ge,Jinjuan Xue,Tingshun Jiang,Longbao Yu,Yutang Shen,Hengbo Yin 한국공업화학회 2009 Journal of Industrial and Engineering Chemistry Vol.15 No.4
A series of Cu–Zn–Zr catalysts were prepared by a coprecipitation method and characterized by X-ray diffraction, X-ray photoelectron spectroscopy, temperature programmed reduction, and N2 adsorption. The catalytic activity of the Cu–Zn–Zr catalyst in the hydrogenation of maleic anhydride using ethanol as a solvent was studied at 220–280℃ and 1 MPa. Maleic anhydride was mainly hydrogenated to gbutyrolactone and tetrahydrofuran while ethanol dehydrogenated to ethyl acetate. After reduction, CuO species present in the calcined Cu–Zn–Zr catalysts were converted to metallic copper (Cu0). The presence of ZrO2 favored the deep hydrogenation of g-butyrolactone to tetrahydrofuranwhile the presence of ZnO was beneficial to the formation of the intermediate product g-butyrolactone. The molar ratios of the hydrogen produced in ethanol dehydrogenation to the hydrogen consumed in maleic anhydride hydrogenation increased with the increase of the reaction temperature.
Oxidation of cyclopentene catalyzed by tungsten-substituted molybdophosphoric acids
Jinjuan Xue,Haixia Li,Dongzhi Zhang,Tingshun Jiang,Longbao Yu,Yutang Shen,Hengbo Yin 한국화학공학회 2009 Korean Journal of Chemical Engineering Vol.26 No.3
A series of Keggin type tungsten-substituted molybdophosphoric acids (H3PMo12−nWnO40·XH2O) were synthesized and characterized by ICP-AES, FT-IR, TG-DSC, and XRD. The tungsten substitution extent significantly affected their catalytic activity in the oxidation of cyclopentene and the selectivity of the resultant products. The tungsten-substituted molybdophosphoric acids with tungsten substitution numbers in a range of 3-6.8 exhibited high catalytic activity in the oxidation of cyclopentene. After reaction for 8 h, the conversion of cyclopentene was up to 97%; the oxidation products mainly consisted of glutaraldehyde, cis-1,2-cyclopentanediol and trans-1,2-cyclopentanediol with the yields of ca. 23%, 27%, and 45%, respectively.
Chun Liu,Hengbo Yin,Chen Ge,Aili Wang,Min Ren,Yunsheng Zhang,Longbao Yu,Tingshun Jiang 한국화학공학회 2011 Korean Journal of Chemical Engineering Vol.28 No.6
Uniform sized and integrated hollow silica spheres with porous shells were prepared by using sulfuric and carboxylic acid-functionalized polystyrene latex spheres as templates, sodium silicate as a precursor, and cetyltrimethylammonium bromide as a shell structure-directing agent. When polystyrene-methyl acrylic acid latex spheres were used as the templates, the pores in the shells of the resultant hollow silica spheres were composed of both micropores and mesopores. The pores in the shells of the hollow silica spheres were mainly composed of mesopores when sulfonated polystyrene-methyl acrylic acid latex spheres were used as the templates. The shell thickness and the specific surface area of the hollow silica spheres increased with the increase in the surface acidity of the latex spheres.