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Guodong Feng,Puyou Jia,Liqiang Zhang,Lihong Hu,Meng Zhang,Yonghong Zhou 한국화학공학회 2015 Korean Journal of Chemical Engineering Vol.32 No.6
A novel flame-retardant plasticizer based on castor oil (FRC) was synthesized, and its potential application for polyvinyl chloride (PVC) was evaluated through the study of torque during melt processing, thermogravimetric analysis (TGA), limiting oxygen index instrument, scanning electron microscope (SEM) and mechanical tests. The results suggested that the FRC has a plasticizing effect in blends with PVC. The addition of FRC resulted in reduction of processing torque, good compatibility, improvement in thermal stability and efficient flame retardant. Torque reduction was observed (33.6%), indicating the reduction of viscosity and the improvement of process. The increase (31.9%) of LOI value indicated that incorporation of FRC system had obviously improved the flame retardant property of PVC blends. The excellent flame retardant properties were obtained by forming an isolation layer on the surface of PVC blends in the process of FRC burning. FRC could improve the thermal ability of PVC blends by enhancing the decomposition temperature of PVC. The performance in all properties of PVC products could be obtained by controlling the formula blends. Therefore, castor oil-based flame retardant plasticizers would appear suitable for a wide range of application.
Li Guodong,Li Dan,Wu Chun,Li Shengnan,Chen Feng,Li Peng,Ko Chung-Nga,Wang Wanhe,Lee Simon Ming-Yuen,Lin Ligen,Ma Dik-Lung,Leung Chung-Hang 생화학분자생물학회 2022 Experimental and molecular medicine Vol.54 No.-
In hypoxia and hyperglycemia, SET7/9 plays an important role in controlling HIF-1α methylation and regulating the transcription of HIF-1α target genes, which are responsible for angiogenesis and wound healing. Here, we report the Ir(III) complex Set7_1a bearing acetonitrile (ACN) ligands as a SET7/9 methyltransferase inhibitor and HIF-1α stabilizer. Interestingly, Set7_1a could engage SET7/9 and strongly inhibit SET7/9 activity, especially after preincubation with homocysteine (Hcy), which is elevated in diabetes. We hypothesize that Set7_1a exchanges ACN subunits for Hcy to disrupt the interaction between SET7/9 and SAM/SAH, which are structurally related to Hcy. Inhibition of SET7/9 methyltransferase activity by Set7_1a led to reduced HIF-1α methylation at the lysine 32 residue, causing increased HIF-1α level and recruitment of HIF-1α target genes that promote angiogenesis, such as VEGF, GLUT1, and EPO, in hypoxia and hyperglycemia. Significantly, Set7_1a improved wound healing in a type 2 diabetic mouse model by activating HIF-1α signaling and downstream proangiogenic factors. To our knowledge, this is the first Hcy-targeting iridium compound shown to be a SET7/9 antagonist that can accelerate diabetic wound healing. More importantly, this study opens a therapeutic avenue for the treatment of diabetic wounds by the inhibition of SET7/9 lysine methyltransferase activity.
Puyou Jia,Guodong Feng,Caiying Bo,Lihong Hu,Xiaohui Yang,Liqiang Zhang,Meng Zhang,Yonghong Zhou 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.60 No.-
A composition of phosphaphenanthrene groups-containing castor-oil-based phosphate plasticizer (PGPP) was synthesized and characterized. Flame retardant PVC blends cooperated with different mass of PGPP were prepared. Flame retardancy of PVC blends were investigated with LOI, TGA, TGA-FTIR, TGA-MS and cone calorimeter. Flame retardant mechanism was also studied. The flame retardant performance of PGPP provides novel route for efficient use of vegetable oil and preparing advanced flame retardant PVC materials.
Wang, Shiquan,Li, Guohua,Du, Guodong,Li, Li,Jiang, Xueya,Feng, Chuanqi,Guo, Zaiping,Kim, Seungjoo Springer 2010 NANOSCALE RESEARCH LETTERS Vol.5 No.8
<P>Cobalt-doped tungsten disulfide nanorods were synthesized by an approach involving exfoliation, intercalation, and the hydrothermal process, using commercial WS<SUB>2</SUB> powder as the precursor and <I>n</I>-butyllithium as the exfoliating reagent. XRD results indicate that the crystal phase of the sample is 2H-WS<SUB>2</SUB>. TEM images show that the sample consists of bamboo-like nanorods with a diameter of around 20 nm and a length of about 200 nm. The Co-doped WS<SUB>2</SUB> nanorods exhibit the reversible capacity of 568 mAh g<SUP>−1</SUP> in a voltage range of 0.01–3.0 V versus Li/Li<SUP>+</SUP>. As an electrode material for the lithium battery, the Co-doped WS<SUB>2</SUB> nanorods show enhanced charge capacity and cycling stability compared with the raw WS<SUB>2</SUB> powder.</P>
Application of the French Codes to the Pressurized Thermal Shocks Assessment
Mingya Chen,Guian Qian,Jinhua Shi,Rongshan Wang,Weiwei Yu,Feng Lu,Guodong Zhang,Fei Xue,Zhilin Chen 한국원자력학회 2016 Nuclear Engineering and Technology Vol.48 No.6
The integrity of a reactor pressure vessel (RPV) related to pressurized thermal shocks (PTSs)has been extensively studied. This paper introduces an integrity assessment of an RPVsubjected to a PTS transient based on the French codes. In the USA, the “screening criterion”for maximum allowable embrittlement of RPV material is developed based on theprobabilistic fracture mechanics. However, in the French RCC-M and RSE-M codes, whichare developed based on the deterministic fracture mechanics, there is no “screening criterion”. In this paper, the methodology in the RCC-M and RSE-M codes, which are used forPTS analysis, are firstly discussed. The bases of the French codes are compared with ASMEand FAVOR codes. A case study is also presented. The results show that the method in theRCC-M code that accounts for the influence of cladding on the stress intensity factor (SIF)may be nonconservative. The SIF almost doubles if the weld residual stress is considered. The approaches included in the codes differ in many aspects, which may result in significantdifferences in the assessment results. Therefore, homogenization of the codes inthe long time operation of nuclear power plants is needed.
Shaoheng Li,Ziji Bai,Feiyang Rong,Jiayin Huang,Lipan Zhou,Guodong Feng,Zhiguang Song 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.124 No.-
Palladium-catalyzed coupling reactions have become effective tools for forming new carbon–carbonbonds. In this work, a novel fluorescence active benzotriazole-coumarin derivative, (E)-N’-((1H-benzo[d][1,2,3]triazol-6-yl)methylene)-7-(diethylamino)-2-ox o-2H-chromene-3-carbohydrazide (BTANC),was synthesized as ligand in Pd(II) cation coordination. It is shown that BTANC has a strong fluorescentemission at 483 nm and Pd(II) can effectively quench the fluorescence of BTANC and BTANC shows excellentsensitivity and selectivity towards Pd (II) ions. Otherwise, the BTANC-Pd(II) complex was also testedin the Sonogashira coupling reaction of phenylacetylene and aryl halides. The desired product wasobtained with high yield (up to 99%) under the optimized reaction conditions. More to that, Low fluorescenceemission was observed during the Pd-catalyzed reaction process and the fluorescent emission ofBTANC was recovered at the end of the Pd-catalyzed reaction because the oxidative addition of the arylhalide towards Pd (0) was shut down at the end of the Pd-catalyzed reaction. This fluorescence propertiesof BTANC indicates the feasibility of using fluorescence signal as a potential tool to monitor the completionof the Sonogashira coupling reaction.
In situ growth of hollow Cu2O spheres using anionic vesicles as soft templates
Xiaolin Luo,Zhe Pan,Fei Pei,Zhipeng Jin,Kangkang Miao,Pengfei Yang,Huaming Qian,Qiang Chen,Guodong Feng 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.59 No.-
Geometrically optimizing anionic vesicles were fabricated using two types of anionic surfactants with antipodal molecular configuration. The influence of counterions on the anionic vesicles was systematically investigated to maintain electrostatic interaction between the anionic vesicles and the precursors, as well as to ensure the structural integrity of the vesicle templates. The transcription from vesicles to hollow Cu2O spheres was achieved through an in situ reduction approach. The obtained hollow Cu2O spheres were assembled by abundant nanoparticles around the vesicle interface and showed preferable adsorption capacity for methyl orange in the dark compared with the solid Cu2O spheres synthesized without any surfactants.
Ai-min Ren,Yu Zhang,Weiwei Yu,Kai Zhao,Zhiru Hu,Zhiquan Zhang,Guodong Feng,Zhi-Guang Song 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.99 No.-
In this article, a series of coumarin derivativefluorescent probes have been synthesized, which can realizesimple, rapid and sensitive detection of Pd2+. We tested thefluorescence properties of threefluorescentprobes, (E)-N0-(((4-chloropyridin-2-yl) methylene)-7-(diethylamino)-2-oxo-2H-chromene-3-carbohy(CMDCC) has the betterfluorescence properties and anti-interference ability. Then, CMDCC as thefluorescence probe for detection of Pd2+ was systematic studied. Under optimized conditions, this probehas a wide pH range, a lower detection limit (4.4510 8 mol L-1), and a faster response speed (3 min). Inthe Pd2+ concentration range of 0.1 5 mmol L-1, thefluorescence intensity of this probe and concentrationof Pd2+ show a good linear response. In this work, Pd2+ content in organic waste liquid was successfullydetected and a standard addition test was also performed. The satisfactory recovery rate was obtained. Moreover, it can be observed with naked eyes that the palladium ion changes the solution color of CMDCCfrom green to red. This color change can easily be compared with other metal salts. It indicates thatCMDCC can also detect Pd2+ by colorimetric method. Therefore, CMDCC should be used to rapidly,conveniently detect Pd2+ in environmental samples.