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Estimating Interfacial Interaction Energy of Cu-Epoxy Resin from Molecular Dynamics Simulation
Dong rong Xin,Qiang Han 대한금속·재료학회 2014 ELECTRONIC MATERIALS LETTERS Vol.10 No.3
Interfacial delamination is one of the typical failure modes in electronic packages. To obtain good reliability of electronic packages, it is important to study the interface properties. In this study, molecular dynamics simulation is conducted to investigate the interfacial interaction energy of Cu-epoxy resin, which is widely used in electronic packages, and the effects of temperature, moisture, crosslink conversion and oxidation degree. The results show that the interaction energy of Cu-epoxy resin is almost independent of the cross-link conversion of the epoxy resin, whereas it is weakened by increasing temperature, moisture and oxidation. Meanwhile, the mechanism of interfacial energy variation is revealed on a molecular scale, which is useful for understanding the interfacial interaction and interfacial delamination.
Surrounding rock pressure of shallow-buried bilateral bias tunnels under earthquake
Liu, Xin-Rong,Li, Dong-Liang,Wang, Jun-Bao,Wang, Zhen Techno-Press 2015 Geomechanics & engineering Vol.9 No.4
By means of finite element numerical simulation and pseudo-static method, the shallow-buried bilateral bias twin-tube tunnel subject to horizontal and vertical seismic forces are researched. The research includes rupture angles, the failure mode of the tunnel and the distribution of surrounding rock relaxation pressure. And the analytical solution for surrounding rock relaxation pressure is derived. For such tunnels, their surrounding rock has sliding rupture planes that generally follow a "W" shape. The failure area is determined by the rupture angles. Research shows that for shallow-buried bilateral bias twin-tube tunnel under the action of seismic force, the load effect on the tunnel structure shall be studied based on the relaxation pressure induced by surrounding rock failure. The rupture angles between the left tube and the right tube are independent of the surface slope. For tunnels with surrounding rock of Grade IV, V and VI, which is of poor quality, the recommended reinforcement range for the rupture angles is provided when the seismic fortification intensity is VI, VII, VIII and IX respectively. This study is expected to provide theoretical support regarding the ground reinforcement range for the shallow-buried bilateral bias twin-tube tunnel under seismic force.
Association of Six Susceptibility Loci with Prostate Cancer in Northern Chinese Men
Zhang, Yu-Rong,Xu, Yong,Yang, Kuo,Liu, Ming,Wei, Dong,Zhang, Yao-Guang,Shi, Xiao-Hong,Wang, Jian-Ye,Yang, Fan,Wang, Xin,Liang, Si-Ying,Zhao, Cheng-Xiao,Wang, Fei,Chen, Xin,Sun, Liang,Zhu, Xiao-Quan,Zh Asian Pacific Journal of Cancer Prevention 2012 Asian Pacific journal of cancer prevention Vol.13 No.12
Background/Aim: Six prostate cancer (PCa) susceptibility loci were identified in a genome-wide association study (GWAS) in populations of European decent. However, the associations of these 6 single-nucleotide polymorphisms (SNPs) with PCa has remained tobe clarified in men in Northern China. This study aimed to explore the loci associated with PCa risk in a Northern Chinese population. Methods: Blood samples and clinical information of 289 PCa patients and 288 controls from Beijing and Tianjin were collected. All risk SNPs were genotyped using polymerase chain reaction (PCR)-high resolution melting curve technology and gene sequencing. Associations between PCa and clinical covariates (age at diagnosis, prostate-specific antigen [PSA], Gleason score, tumor stage, and level of aggressiveness) and frequencies of alleles and genotypes of these SNPs were analyzed using genetic statistics. Results: Among the candidate SNPs, 11p15 (rs7127900, A) was associated with PCa risk (P = 0.02, odds ratio [OR] = 1.64, 95% confidence interval [CI] = 1.09-2.46). Genotypes showed differences between cases and controls on 11p15 (rs7127900, A), 11q13 (rs7931342, T), and HNF1B (rs4430796, A) (P = 0.03, P = 0.01, and P = 0.04, respectively). The genotype TG on 11q13 (rs7931342, T) was positively associated with an increased Gleason score (P = 0.04, OR = 2.15, 95% CI = 1.02-4.55). Patients carrying TG on 17q24 (rs1859962, G) were negatively associated with an increased body mass index (BMI) (P = 0.03, OR = 0.44, 95% CI = 0.21-0.92) while those with AG on HNF1B (rs4430796, A) were more likely to have PSA increase (P = 0.002). Conclusion: Our study suggests that 11p15 (rs7127900, A) could be a susceptibility locus associated with PCa in Northern Chinese. Genotype TG on 11q13 (rs7931342, T) could be related to an increased Gleason score, AG on HNF1B (rs4430796, A) could be associated with PSA increase, and TG on 17q24 (rs1859962, G) could be negatively associated with an increased BMI in Chinese men with PCa.
Hydrothermal Synthesis of Indium Tin Oxide Nanoparticles without Chlorine Contamination
Hai Wen Wang,Guo Dong Xu,Jian Rong Zhang,Xin Yin 대한화학회 2014 Bulletin of the Korean Chemical Society Vol.35 No.7
Indium tin oxide (In2Sn1-xO5-y) nanoparticles were synthesized by hydrothermal method from stable indium tin acetylacetone complexes and postannealing at 600 oC. The absence of chlorine ions shortened the synthesis process, decreased the particle agglomeration and improved the particle purity. The introduced complexing ligand acetylacetone decreased the obtained nanoparticle size. The improved powder properties accelerated the sintering of the In2Sn1-xO5-y nanoparticles and reached a relative density of 96.4% when pressureless sintered at 1400 oC.
A displacement solution for circular openings in an elastic-brittle-plastic rock
Huang, Houxu,Li, Jie,Rong, Xiaoli,Hao, Yiqing,Dong, Xin Techno-Press 2017 Geomechanics & engineering Vol.13 No.3
The localized shear and the slip lines are easily observed in elastic-brittle-plastic rock. After yielding, the strength of the brittle rock suddenly drops from the peak value to the residual value, and there are slip lines which divide the macro rock into numbers of elements. There are slippages of elements along the slip lines and the displacement field in the plastic region is discontinuous. With some restraints, the discontinuities can be described by the combination of two smooth functions, one is for the meaning of averaging the original function, and the other is for characterizing the breaks of the original function. The slip lines around the circular opening in the plastic region of an isotropic H-B rock which subjected to a hydrostatic in situ stress can be described by the logarithmic spirals. After failure, the deformation mechanism of the plastic region is mainly attributed to the slippage, and a slippage parameter is introduced. A new analytical solution is presented for the plane strain analysis of displacements around circular openings. The displacements obtained by using the new solution are found to be well coincide with the exact solutions from the published sources.
Effect of Heat Treatment on the Lipophillic Pigments of Fresh Green Tea Liquor
Jian-Liang Lu,Zhan-Bo Dong,Shun-Shun Pan,Chen Lin,Xin-Qiang Zheng,Borthakur Devajit,Yue-Rong Liang 한국식품과학회 2009 Food Science and Biotechnology Vol.18 No.3
Changes in lipophillic pigments concentration and its relation to color of fresh green tea liquor during heat treatment were studied. The results showed liquor greenness decreased markedly with extension of incubation time at 55℃, while the brightness and yellowness changed a little. Significant increase in ‘a’ and ‘b’ values of tea liquor was observed at 95℃. Color change of liquor at 55℃ was accompanied by a decrease in the level of chlorophylls, lutein and neoxanthin, and an increase in the pheophytins and β-carotene levels. However, all pigments except β-carotene decreased with time extension at 95℃. Significant correlation was found between pigments and color difference index. The browning of fresh green tea liquor was attributed to vicissitudes of lipophillic pigments during heat treatment, especially to the change of chlorophylls/pheophytins ratio. Result also showed addition of Zn²? at 1.6 μ㏖/ℓ could partially alleviate the decrease in greenness during heat treatment.
Non-Doped Organic Light-Emitting Diodes with Saturated Red Emission
Fei Xiao,Bing-xian Shao,Huan-rong Wu,Hui-ying Fu,Xiao-yuan Hou,Xin-dong Gao,Yi-qiang Zhan 한국물리학회 2007 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.50 No.2
Non-doped organic light-emitting diodes with saturated red emission were fabricated using 4-(2-(3,3-dicyanomethylene-5,5-dimethyl-1-cyclohexylidene)vinyl)phenyldi(1-naphthyl)amine (DNP-2CN) or 4-(2-(3,3-dicyanomethylene-5,5-dimethyl-1-cyclohexylidene)vinyl)phenyl(1-naphthyl)phe- nylamine (DPN-2CN) as the emitting layer. Different electron-transporting materials, tris(8-hydroxylquinoline) aluminum (Alq$_3$), 2,2',2''-(1,3,5-phenylene)tris[1-phenyl-1$H$-benzimidazole] (TPBI) and 2-(4-biphenyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole (PBD), were introduced into the devices for examining their energy level compatibility of DNP-2CN or DPN-2CN. The device with a structure of ITO/ NPB/ DNP-2CN/ BCP/ Alq$_3$/ LiF/ Al showed red emission with $\lambda_{max}$ at 670 nm (CIE coordinates: $x$ = 0.66, $y$ = 0.33) and a high luminance of 438 cd m$^{-2}$ at a driving voltage of 12 V. The device with a structure of ITO/ NPB/ DPN-2CN/ BCP/ Alq$_3$/ LiF/ Al showed a high brightness of 225 cd m$^{-2}$ at a driving voltage of 12 V with $\lambda_{max}$ at 674 nm (CIE coordinates: $x$ = 0.65, $y$ = 0.33).
Hydrothermal Synthesis of Indium Tin Oxide Nanoparticles without Chlorine Contamination
Wang, Hai Wen,Xu, Guo Dong,Zhang, Jian Rong,Yin, Xin Korean Chemical Society 2014 Bulletin of the Korean Chemical Society Vol.35 No.7
Indium tin oxide ($In_2Sn_{1-x}O_{5-y}$) nanoparticles were synthesized by hydrothermal method from stable indium tin acetylacetone complexes and postannealing at $600^{\circ}C$. The absence of chlorine ions shortened the synthesis process, decreased the particle agglomeration and improved the particle purity. The introduced complexing ligand acetylacetone decreased the obtained nanoparticle size. The improved powder properties accelerated the sintering of the $In_2Sn_{1-x}O_{5-y}$ nanoparticles and reached a relative density of 96.4% when pressureless sintered at $1400^{\circ}C$.