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Effect of reducing agents on the synthesis of anisotropic gold nanoparticles
Yoo Sunghoon,남동환,Singh Thangjam Ibomcha,Leem Gyu,이승현 나노기술연구협의회 2022 Nano Convergence Vol.9 No.5
The seed-mediated method is a general procedure for the synthesis of gold nanorods (Au NRs), and reducing agents such as ascorbic acid (AA) and hydroquinone (HQ) are widely used for the growth process. Further, they are mild reducing agents; however, when AA is used, controlling the size of Au NRs with a higher aspect ratio (localized surface plasmon resonance (LSPR) peak, λ Lmax > 900 nm) is challenging because it results in a faster growth rate of Au NRs. In contrast, when HQ is used, Au NRs with a higher aspect ratio can be synthesized as it slows down the growth rate of the Au NRs and greatly enhanced the λ Lmax . However, the increase in λ Lmax is still needs not satisfactory due to the limited enhancement in the aspect ratio of Au NRs due to utilization of single reducing agent. The growth kinetics of the Au NRs can be modulated by controlling the reducing power of the reducing agents. In such scenario, judicious use of two reducing agents such as AA and HQ simultaneously can help us to design Au NRs of higher aspect ratio in a controlled manner due to the optimum growth rate resulting from the combined effect of both the reducing agents. In this study, we investigated the effect of the two reducing agents by controlling the volume ratios. When the growth solution contains both the reducing agents, the growth of Au NRs is first initiated by the fast reduction of Au 3+ to Au + due to stronger reducing power of the AA and when the AA in the growth solution is completely utilized, further growth of the Au NRs continues as a result of the HQ thereby resulting to high aspect ratio Au NRs. Consequently, the LSPR peak (λ Lmax > 1275 nm) can be tuned by controlling the volume ratios of the reducing agents.
김대원,김모곤,남동환,정순기,임순재 한국센서학회 2000 센서학회지 Vol.9 No.1
Every object emits some energy from its surface. The emission energy forms surface heat distribution which we can capture by using an infrared thermal imager. The infrared thermal image may include valuable information regarding to the subsurface anomaly of the object. Since a thermal image reflects surface clutter and subsurface anomaly, we have difficulty in extracting the information on the subsurface anomaly only with thermal images taken under a wavelength. Thus, we use visible wavelength images of the object surface to remove exterior clutter. We, therefore in this paper, visualize the infrared image for overlaying it with a visible wavelength image. First, we make an interpolated image from two ordinary images taken from both sides of an infrared sensor. Next, we overlay the intermediate image with an infrared image taken from the infrared camera. The technique suggested in this paper can be utilized for analyzing the infrared images on non-destructive inspection against disaster and for safety.
실사 가상환경 항해를 위해 Spheroid 를 이용한 어안렌즈의 왜곡보정
신주홍 ( Ju-hong Shin ),남동환 ( Dong-hwan Nam ),권기준 ( Gi-jun Kwon ),정순기 ( Soon Ki Jung ) 한국정보처리학회 2004 한국정보처리학회 학술대회논문집 Vol.11 No.2
실제영상으로 가상환경을 구축해서 사용자가 가상환경을 돌아다님으로써 보다 큰 몰입감과 현실감을 제공하는 영상기반 가상현실 기술은 최근 들어 웹 기반 가상현실시스템을 구축하기 위해서 많이 사용된다. 이 기술은 가상환경 구축에 있어 항해를 쉽게 하기 위한 한 방법으로 넓은 시각 영역(field of view)을 얻을 수 있는 wide-angle 렌즈를 흔히 사용한다. 어안렌즈(fish-eye lens)는 전형적인 넓은 시각 영역을 가진 렌즈로서, 매우 큰 radial distortion 을 가진다. 왜곡을 없앤 영상을 얻기 위해 본 논문에서는 구면기하(spherical geometry) 및 사영기하(projective geometry)를 사용하여 어안영상을 보정하는 non-metric 기법을 제안한다. 제안한 이 방법은, 기존의 방법들 보다는 쉽고 빠른 속도로 왜 곡을 보정할 수 있으므로 어안영상의 왜곡을 보정하는 하드웨어를 효율적으로 구현할 수 있다. 그리고 spheroid 를 이용해 좀 더 왜곡을 정확히 보정방법과 별도의 서보 모터 없이 pan/title 를 가능케 하는 시점이동에 따른 왜곡 보정 방법을 제시한다.