풀러렌-물 클러스터의 상호작용에 대한 양자 역학적 이론 연구

김성현,신창호,김지선,강소영,김승준,Kim, Sung-Hyun,Shin, Chang-Ho,Kim, Ji-Sun,Kang, So-Yung,Kim, Seung-Joon 대한화학회 2015 대한화학회지 Vol.59 No.1

풀러렌(fullerene)의 내부에 캡슐화될 수 있는 물 분자의 수와 물 분자들이 증가함에 따라 풀러렌의 안정적인 구조에 미치는 영향을 조사하기 위해 밀도 범함수 이론(density functional theory, DFT)을 이용하여 풀러렌-물 클러스터$(H_2O)_n@C_{60}$, (n=1-10)의 구조 변화에 따른 열역학적 안정성 및 결합에너지를 계산하였다. 각각의 구조들에 대해서 여러 이론 수준에서 최적화하였으며 진동주파수를 계산하여 가장 안정한 구조를 조사하고 IR 스펙트럼을 예측하였다. 또한 풀러렌 내의 물 분자 수가 증가함에 따른 수소결합의 세기 변화를 순수한 물 클러스터$(H_2O)_n$, (n=1-6)의 수소결합과 비교 분석하였다. The density functional theory (DFT) calculations on $(H_2O)_n@C_{60}$, (n=1-10) complexes have been performed to elucidate hydrogen interaction between fullerene and water clusters. The optimized geometries, harmonic vibrational frequencies, and binding energies are predicted at various levels of theory. The harmonic vibrational frequencies for the molecules considered in this study show all real numbers implying true minima. We also compare the H-bond interaction between $(H_2O)_n$ and $(H_2O)_n@C_{60}$, (n=1-10) clusters.

순천만 갈대근권 토양으로부터 얻은 PAH 분해세균의 특성 분석

김성현,강성미,오계현,김승일,윤병준,강형일,Kim Sung-Hyun,Kang Sung-Mi,Oh Kye-Heon,Kim Seung-Il,Yoon Byoung-Jun,Kahng Hyung-Yeel 한국미생물학회 2005 미생물학회지 Vol.41 No.3

This study was accomplished in order to collect fundamental data on microbial roles in recycling process of reed rhizosphere. Sunchon bay, which is considered as one of the marsh and mud environments severely affected by human activities such agriculture and fisheries, was selected as a model place. In our initial efforts, two bacterial consortia were obtained by enrichment culture using PAH mixtures containing anthracene, naphthalene, phenanthrene and pyrene as the sources of carbon and energy, and four pure bacteria capable of rapid degradation of PAH were isolated from them. Four strains designated as SCB1, SCB2, SCB6, and SCB7 revealed by morphological, physiological and molecular analyses were identified as Burkholderia anthina, Alcaligenes sp., Achromobacter xylosoxidans., and Pseudomonas putida, respectively with over $99{\%}$ confidence. Notably, Burkholderia anthina SCB1 and Alcaligenes sp. SCB2 were found to utilize anthracene and pyrene more quickly than naphthalene and phenanthrene, whereas Achromobacter xylosoxidans SCB6 and Pseudomonas putida SCB7 exhibited similar growth and degradation patterns except for pyrene. These facts suggest that the rhizosphere microorganisms capable of PAH degradation might be used to clean up the contamination sites with polycyclic aromatic hydrocarbons. 본 연구는 농업과 어업, 그리고 생태체험과 같은 인간들의 활동으로 인하여 상당히 영향을 받는 갯벌환경 중의 하나인 순천만을 모델장소로 갈대의 환경정화 기능에 있어 근권에 분포하는 미생물의 역할에 대한 기초 자료를 얻고자 수행하였다. 우선, 순천만의 갈대근권 토양을 시료로하고 anthracene, naphthalene, phenanthrene, pyrene 등이 첨가된 다환성 방향족 화합물(polycyclic aromatic hydrocarbons; PAH)을 탄소원 및 에너지원으로 하는 농화 배양을 통하여 두 개의 consortium을 획득하였다. 두 consortium으로부터 순수 분리된 우수한 PAH분해능을 갖는 4개의 균주(SCB1, SCB2, SCB6,그리고 SCB7)를 형태 및 생리학적 특성과 16S rRNA유전자서열을 기초로 분석한 결과 각 균주는 $99{\%}$ 이상의 신뢰도로 Burkholderia sp., Aicaligenes sp., Achromobacter sp., and Pseudomonas sp.로 동정되었다. 주목할 만한 점은 Burkholderia sp. SCB1과 Alcaligenes sp. SCB2는 naphthalene이나 phenanthrene보다 훨씬 안정되어 있는 구조의 anthracene이나 pyrene에서 더 빠른 성장률과 기질 분해율을 나타내는 것으로 밝혀졌다. 반면,Achromobacter sp. SCB6와 Pseudomonas sp. SCB7은 pyrene을 제외한 다른 시험기질에 대하여 유사한 성장 및 분해패턴을 나타내었다. 이러한 결과는 주요한 염습지 식물중의 하나인 갈대의 근권에서 살아가는 이들 PAH 분해 균주들이 PAH와 같은 물질로 오염된 근권 환경의 정화작용에 중요한 역할을 할 수 있음을 제시해 주었다.

치주치료 후 구강 내 Volatile Sulfur Compounds(VSC)의 변화

김성현,채경준,정의원,김창성,최성호,조규성,채중규,김종관,방은경,Kim, Sung-Hyun,Chae, Gyeong-Jun,Jung, Ui-Won,Kim, Chang-Sung,Choi, Seong-Ho,Cho, Kyoo-Sung,Chai, Jung-Kyu,Kim, Chong-Kwan,Bang, Eun-Gyeong 대한치주과학회 2006 Journal of Periodontal & Implant Science Vol.36 No.3

Oral malodor may cause a significant social or psychological handicap to those suffering from it. Oral malodor has been correlated with the concentration of volatile sulfur compounds (VSC) produced in the oral cavity. Specific bacteria identified in the production of VSC have been reported and many of these bacteria are commonly suspected periodontal pathogens. The aim of this study was to estimate the change of the VSC concentration after periodontal treatment, Twenty subjects with probing depth $(PD)\;{\geq}5mm$ (experimental group) and 20 subjects with PD<5mm (control group) participated. VSC concentration measurement was made with gas chromatography. VSC concentration was measured at pre-treatment, 2 weeks after scaling and 1 month after periodontal treatment(root planning and flap operation). Maximum probing depth and bleeding on probing(BOP) were also examed at pretreatment and 1 month after periodontal treatment, The conclusions were as follow: 1. In the experimental group VSC concentration and CH3SH/H2S ratio were higher than control group. (p<0.05) 2. Both VSC concentration and CH3SH/H2S ratio showed decrease after periodontal treatment, But only CH3SH/H2S ratio after 1 month periodontal treatment was statistically significantly different from pre-treatment. (p<0.05) 3. CH3SH/H2S ratio tended to be on increase according to maximum probing depth and bleeding on probing. Periodontal disease could be a factor that caused oral malodor and oral malodor could be decreased after periodontal treatment.

N과 AlN 시트에 다양한 기체(CO_x, NO_x, SO_x)의 흡착에 관한 이론 연구

김성현,김백진,신창호,김승준,Kim, Sung-Hyun,Kim, Baek-Jin,Shin, Chang-Ho,Kim, Seung-Joon 대한화학회 2017 대한화학회지 Vol.61 No.1

본 연구는 그래핀과 유사한 2차원 붕소-질소(BN)와 알루미늄-질소(AlN) 시트에 여러 대기 유해 가스($CO_x$, $NO_x$, $SO_x$)가 흡착될 때의 구조적 특징과 결합에너지를 밀도 범함수 이론(DFT)과 MP2 방법을 사용하여 연구하였다. 분자 구조는 $B3LYP/6-31G^{**}$와 $CAM-B3LYP/6-31G^{**}$이론 수준에서 최적화하고, 진동 주파수를 계산하여 열역학적으로 가장 안정한 분자 구조를 확인하였다. 결합에너지는 $MP2/6-31G^{**}$ 이론 수준에서 한 점(single point) 에너지를 계산하고, 영점 진동에너지(ZPVE)와 바탕집합 중첩에러(BSSE)를 모두 보정하였다. BN 시트에 가스의 흡착은 모두 물리흡착으로 예측되었으며, AlN 시트에 대한 가스 흡착은 $CO_x$나 $NO_x$에 대해서는 물리흡착이 그리고 $SO_x$에 대해서는 화학 흡착이 일어날 것으로 예측되었다. The adsorption of various atmospheric harmful gases ($CO_x$, $NO_x$, $SO_x$) on graphene-like boron nitride(BN) and aluminum nitride(AlN) sheets was theoretically investigated using density functional theory (DFT) and MP2 methods. The structures were fully optimized at the $B3LYP/6-31G^{**}$ and $CAM-B3LYP/6-31G^{**}$ levels of theory and confirmed to be a local minimum by the calculation of the harmonic vibrational frequencies. The MP2 single-point binding energies were computed at the $CAM-B3LYP/6-31G^{**}$ optimized geometries. Also the zero-point vibrational energy (ZPVE) and 50%-basis set superposition error (BSSE) corrections were included. The adsorptions of gases on the BN sheet were predicted to be a physisorption process and the adsorptions of gases on the AlN sheet were predicted to be a physisorption process for $CO_x$ and $NO_x$ but to be a chemisorption process for $SO_x$.

증기화 증폭시트를 적용한 전자빔 가공 특성 연구

김성현,정성택,김현정,백승엽,Kim, Seong Hyun,Jung, Sung Taek,Kim, Hyun Jeong,Baek, Seung Yub 한국금형공학회 2018 한국금형공학회지 Vol.12 No.2

Recently, as machine components and products are getting smaller, it is demanded to develop superprecision production technologies multilaterally. Along with the advancement of production technology, people are paying keener attention to the development of eco-friendly technology and efficient processing technology. Particularly, in many industries related to automobiles, shipbuilding, or airplane components, it is demanded to obtain technology to process multiple micro-holes. On account of this trend, micro-hole processing employing high-power electron beams is rising nowadays, and more interest is being shown in it, too. In Korea, however, the process of manufacturing vaporized amplification sheets influencing high-power electron beam processing technology and the processability considerably has not been developed sufficiently yet. Therefore, this study has applied vaporized amplification sheets manufactured to analyze the processability of high-power electron beams and examine necessity for vaporized amplification sheets.

Thionin - Sodium Dodecyl Sulfate 계의 상호작용에 있어서 염 및 유기용매의 첨가효과에 관한 연구

김성현,송기동 ( Sung Hyun Kim,Ki Dong Song ) 한국공업화학회 1994 공업화학 Vol.5 No.5

양이온 색소인 thionin(Th)과 음이온 계면활성제인 sodium dodecyl sulfate(SDS) 사이의 상호작용을 흡수 spectra로 고찰하였다. 임계미셀농도(critical micelle concentration, CMC)보다 훨씬 낮은 premicellar 영역(S/D=10, 80및 160)에서 온도가 증가함에 따라 몰 흡광계수비가 증가하거나 감소함을 볼 수 있으며, S/D=160에서 Th-SDS계의 다분자 회합체가 생성하는 가장 안정한 온도 범위는 60℃ 이하임을 알 수 있었다. 한편 Th-SDS계에 첨가한 무기염 및 유기 용매의 농도가 증가함에 따라 γ-band와 J-band는 감소하나 α-band는 오히려 증가하는 경향이 나타났다. 이들의 α-band의 증가 순서는 무기염의 경우 Cl^- > ClO₄^- > SO₄^(2-) > NO₃^-로 나타나며, 유기용매인 경우는 2-propanol>ethanol>methanol>ethylene glycol로 나타남을 알 수 있다. The interaction between the cationic dye, thionin(Th) and the anionic surfactant, sodium dodecyl sulfate(SDS) has been investigated by absorption spectra. As the temperature of surfactant solution was increased in premicellar range(S/D=10, 80, and 160) which was much lower than the critical micelle concentration(CMC), the increment or decrement of the molar extinction coeffecient ratio appeared. It was found that the most stable temperature range of the oligomer aggregate in Th-SDS system at S/D=160 was below 60℃. With increasing the concentration of inorganic salt and organic solvents in Th-SDS system, α-band was increased, but γ-band or J-band was decreased. The orders of α-band increasing power were Cl^- > ClO₄^- > SO₄^(2-) > NO₃^- and 2-propanol>ethanol>methanol>ethylene glycol.

기천(氣喘)에 대(對)한 문헌적(文獻的) 고찰(考察)

김성현,Kim, Sung-Hyun 대한한방내과학회 1992 大韓韓方內科學會誌 Vol.13 No.2

This study has been carried out to investigate the cause, symptom and treatment of Gi-Chun (氣喘) by referring to 32 literatures. The results were obtained as follows; 1. The factor causing Gi-Chun (氣喘) is almost damage of feeling (七情損傷). 2. The symptom of Gi-Chun (氣喘) is as follows. agony, breathing urgent, cold hand and feet, body tired, low appetite 3. The treatment of Gi-Chun (氣喘) is as follows. Sunpaeganggi(宣肺降氣), Jihaepyungchun(止咳平喘), gudam(去痰) 4. The drugs(herb) of Gi-Chun (氣喘) is as follows. Samatang(四磨湯), Sachiltang(四七湯), Sojaganggitang(蘇子降氣湯), Gilgyungjigaktang(桔梗枳殼湯), Gamisachiltang(加味四七湯), Gamisoyosan(加味逍遙散).

화개산(華蓋散)이 GUINEA PIG의 기관지(氣管支) 평활근(平滑筋)에 미치는 영향(影響)

김성현,Kim, Sung-Hyun 대한한방내과학회 1990 大韓韓方內科學會誌 Vol.11 No.1

In order to study the effects of HWA GAE SAN known clinically for their effects of treatment for cough and asthma, the study was carried out to investigate the effect of HWA GAE SAN extract on the contractile force of isolated guinea pig trachea smooth muscle and elucidate its mechanism. The results were obtained as follows. 1. Preparation of isolated guinea pig trachea smooth muscle was suspended in the oxygeneted Kreb's Henseleit bicarbonate buffer solution at $37^{\circ}C$ and recorded the developed tension by the drug with the isometric transducer (Nacro F-60). The restin tension was approximately 0.5g. 2. The trachea smooth muscle in normal state showed a significant atony to the increase of density of HWA GAE SAN. 3. The atonic effect of the trachea smooth muscle was restricted after prescription of Pyrilamine& Cyproheptadine. Hireceptor broker, which were prearranged. 4. After 5, 15, 50& $150{\mu}l/ml$ of HWA GAE SAN were prescribed, the atony of trachea smooth muscle was caused by Histamine. 5. After 50& $150{\mu}l/ml$ of HWA GAE SAN were prescribed, the atony of trachea smooth muscle was remarkably dwindled which was caused by Acetylcholine. 6. After $150{\mu}l/ml$ of HWA GAE SAN were prescribed, the atony of trachea smooth muscle was remarkably dwindled which was caused by 5-Hydroxytryptamine.

현장 안전관리 감독자의 smartmaker 를 활용한 건설현장 근로자 정보 관리의 관한 연구

김성현,이지엽,손기영,Kim, Sung-hyun,Lee, Ji-yeob,Son, Kiyoung 한국건설안전학회 2020 한국건설안전학회 논문집 Vol.3 No.1

본 연구의 목적은 건설현장 근로자의 데이터 공유 시스템를 기반으로 건설재해 예방을 위한 근로자 정보 관리 모델을 구축하는 것이다. 이를 위해 첫째, 행연구 고찰을 통해 국내 건설현장의 외국인 근로자 현황을 파악하고, 정보 관리 애플리케이션에 대한 정보를 수집한다. 둘째, 스마트메이커 시스템을 활용하여 Brain storming을 실시하고, Aws를 통해 구축된 서버와 Family tree를 기반으로 개발된 애플리케이션의 기능을 분석한다. 셋째, 전문가 의견조사를 통해 개발된 정보 관리 모델의 경제성 및 효용성을 평가하고, 추가적인 기능 고찰 및 개선방안을 도출한다. 넷째, 개발된 정보 관리 모델의 국내 건설현장에서의 적용성에 대해 종합적으로 검토한다. 그 결과, 노무관리자와 현장 관리자 간의 보고체계가 단순화되어 노무자의 성실성 및 안전관리의 편리성이 있는 것으로 평가되었으며, 기능 추가 관련 사항으로는 자동 로그인 기능을 추가하여 편리성을 보완한다면 더욱 효과적일 것이라는 결론을 도출할 수 있었다. 본 연구의 결과는 향후 건설현장의 안전관리 시스템 구축연구의 기초자료로 활용될 것이다. In this study, an application was developed to reduce the work between labor and safety managers and to hire better workers when hiring workers. With the expected increase in foreign workers in the future, the number of illegal workers will also increase. As a result, accident and on-site management are becoming more difficult due to insufficient information collection of workers. Therefore, it was possible to secure on-site safety through an application that could collect accurate information and reduce the time of information exchange between safety managers and labor managers. In addition, the application was designed to help the safety manager identify the faithful workers more quickly when re-employment of the day laborers if many day laborers were assessed and filled out as they were. This anticipates the expected effect of shortening the construction period. The current application collected necessary information through an interview with the site manager. If the company collects more information needed in the field and has big data than it has collected necessary information so far, it will be highly competitive in the market as it can improve the completeness of applications by establishing opinions and reflecting information accordingly.

음식물(飮食物)에 의(依)하여 발생(發生)되는 해수(咳嗽)에 대(對)한 문헌적(文獻的) 고찰(考察)

김성현,이준무,한상환,Kim, Sung-Hyun,Lee, Jun-Mu,Han, Sang-Whan 대한한방내과학회 1991 大韓韓方內科學會誌 Vol.12 No.2

This study has been carried out to investigate the cause and symptom of coughing made of foods and wine by referring to 43 literatures. The results were obtained as follows; 1. The factor causing Sik Juk Su ( 食積嗽 ) is Dam Yeum ( 痰飮 ) made from mistaking meals. 2. Excepted Sik Juk Su ( 食積嗽 ), Coughing made of foods and wine are Bi Hae ( 脾咳 ), Uey Hae ( 胃咳 ), Dam Su ( 痰嗽 ). Ju Su ( 酒嗽 ). Han Su (寒嗽). 3. The symptom of Sik Juk Su ( 食積嗽 ) is as follows. pale-looking cough in early morning pain of right sub-ribs body tired low appetite body fever vomitting acid 4. Excepted Sik Juk Su ( 食積嗽 ), the symptom of Coughing made of foods and wine are simulanted of Sik Juk Su ( 食積嗽 ).