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남혜원,현영희,변진원 동아시아식생활학회 2004 동아시아식생활학회지 Vol.14 No.6
This study was performed to develop a standardized recipe for yuza pyun made of citron juice that is by-product of citron tea, to increase the utilization of citron. The effects of mungbean starch(15%, 18%) and dilution ratio of yuza extract(100%, 75%, 50%) on the quality characteristics were evaluated. The quality characteristics of the samples were estimated in terms of sweetness, color difference, texture profile analysis and sensory evaluation. Sweetness of the 18% mungbean groups were higher than 15% groups(p<0.001). The values of Hunter color system indicated that higher content of yuza extract tended to increase yellowness significantly(p<0.001). Texture profiles of hardness, adhesiveness, springiness, cohesiveness, gumminess of yuzapyun showed no significant differences among samples. For sensory evaluation, color and sourness were decreased as yuza extract was diluted, whereas elasticity and sweetness were increased. Yuza pyun containing 18% of mungbean starch with 50% diluted extract was the most preferred in overall acceptability. According to multiple regression analysis, color, sweetness, elasticity and sourness(in order) were important control factors in overall acceptability.
Danielle Ooyoung Pyun,Miri K. Chung,Ho Jung Choi 고려대학교 언어정보연구소 2013 언어정보 Vol.17 No.-
Pyun, Danielle O., Chung, Miri K. & Choi, Ho Jung. 2013. KFL learners’ acquisition of Korean locative particles: A corpus-based contrastive interlanguage analysis. Language Information. Volume 17. 23-46. Adopting the contrastive interlanguage analysis methodology, this study investigates KFL (Korean as a Foreign Language) learners’ acquisition of Korean locative case particles. A learner corpus compiled from eighty-seven intermediate learners of Korean was compared with a native speaker corpus on the frequency distribution of the five semantic categories of the Korean locative case (i.e, static location, dynamic location, time, goal, and source). In addition, learner errors on the use of locative case particles were quantified and examined according to the five semantic categories. The results of this study showed that KFL learners’ use of locative case particles substantially deviated from native speakers’ usage in frequency. Learners’ inaccurate and limited use of locative case particles were attributed to such factors as L1 transfer, overgeneralization, prior input, and interlanguage development.
Pyun, Sang-Yong,Byun, Woong-Sub,Cho, Bong-Rae Korean Chemical Society 2011 Bulletin of the Korean Chemical Society Vol.32 No.6
Nitrile-forming eliminations from $(E)-2,4,6-(NO_2)_3C_6H_2CH=NOC_6H_4-2-X-4-NO_2$ (1) promoted by $R_3NH/R_3NH^+$ in 70 mol % MeCN(aq) have been studied kinetically. When X = $NO_2$, the reactions exhibited second-order kinetics as well as Br$\"{o}$nsted ${\beta}$ = 0.63 and ${\mid}{\beta}_{lg}{\mid}$ = 0.34-0.46, and an E2 mechanism is evident. As the leaving group was made poorer (X = H, Cl, and $CF_3$), Br$\"{o}$nsted ${\beta}$ value increased from 0.63 to 0.85-0.89 without much change in the ${\mid}{\beta}_{lg}{\mid}$ value E2, indicating that structure of the transition state changed to an E1cb-like with extensive $C_{\beta}-H$ bond cleavage, significant negative charge development at the ${\beta}$-carbon, and limited $C_{\alpha}$-OAr bond cleavage.
Pyun, Sang Yong,Cho, Bong Rae Korean Chemical Society 2013 Bulletin of the Korean Chemical Society Vol.34 No.7
Reactions of 4-nitrophenyl 2-thiophenecarboxylate (1a-e) with $R_2NH/R_2NH{_2}^+$ in 20 mol % DMSO (aq) have been studied kinetically. The $2^{nd}$ order kinetics, ${\beta}_{nuc}$ = 0.88-0.98, and linear Hammett and Yukawa-Tsuno plots observed for these reactions indicate an addition-elimination mechanism in which the $2^{nd}$ step is rate limiting. The ${\beta}_{nuc}$ value increased with a stronger electron-withdrawing 5-thienyl substituent, the Hammett plots are linear except for X = MeO, and Yukawa-Tsuno plots are linear with ${\rho}$ = 0.79-1.32 and r = 0.28-0.93, respectively. The ${\rho}$ value increased and r value decreased with a stronger nucleophile, indicating an increase in the electron density at the C=O bond and a decrease in the resonance demand. These results have been interpreted with enhanced N-C bond formation in the transition state with the reactivity increase.
崔相哲,朴恩珍,朴祐善,片宗根 명지대학교 공학기술연구소 1991 공학기술연구소 논문집 Vol.6 No.-
Pyun(1986) solved the Laplace equation in rectangular domain with Dirichlet type boundary conditions by several different methods, and compared the results. The methods used are the analytical method by separation of variables, the finite difference method, the finite element method with triangular and four-node rectangular elements, and the boundary element method. As a succession of the previous study, the finite element method with eight-node rectangular elements is used to solve the problem. Comparison with the results of previous study indicates that this solution approaches to analytical solution closely with relatively few numbers of element discretizations.
Pyun, Sang Yong,Kim, Ju Chang,Cho, Bong Rae Korean Chemical Society 2014 Bulletin of the Korean Chemical Society Vol.35 No.7
Ketene-forming elimination from 2-X-4-nitrophenyl furylacetates (1a-d) promoted by $R_2NH-R_2NH_2{^+}$ in 70 mol % MeCN(aq) has been studied kinetically. When X = Cl and $NO_2$, the reactions exhibited second-order kinetics as well as Br$\ddot{o}$nsted ${\beta}$ = 0.37-0.54 and $|{\beta}_{lg}|$ = 0.31-0.45. The Br$\ddot{o}$nsted ${\beta}$ decreased with a poorer leaving group and $|{\beta}_{lg}|$ increased with a weaker base. The results are consistent with an E2 mechanism. When the leaving group was changed to a poorer one [X= H (1a) and $OCH_3$ (1b)], the reaction mechanism changed to the competing E2 and E1cb mechanisms. A further change to the E1cb mechanism was realized for the reaction of 1a with $i-Pr_2NH/i-Pr_2NH_2{^+}$ in 70 mol % MeCN-30 mol % $D_2O$. By comparing the kinetic results in this study with the existing data for $ArCH_2C(O)OC_6H_3-2-X-4-NO_2$, the effect of the ${\beta}$-aryl group on the ketene-forming elimination was assessed.