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Tahir, Muhammad Nazir,Jeong, Daham,Kim, Hwanhee,Yu, Jae-Hyuk,Cho, Eunae,Jung, Seunho Korean Chemical Society 2014 Bulletin of the Korean Chemical Society Vol.35 No.1
Glass discs functionalized with alkynyl (GDA) terminated monolayers were prepared and incubated in $AgNO_3$ solution (GDA-Ag). The modified functional glass surfaces were characterized by X-ray photoelectron microscopy (XPS). The potential of GDA and GDA-Ag as antimicrobial surfaces was investigated. Anti-microbial efficacies of GDA against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, Bacillus cereus, and Candida albicans was relatively low ranging from 4.67 to 17.00%. However, the GDA-Ag was very effective and its antimicrobial efficacy ranged from 99.90 to 99.99% against the same set of microbial strains except for C. albicans where it was 95.50%. The durability of the Ag bonded to the terminal alkynyl groups was studied by placing the GDA-Ag in PBS buffer solution (pH 7.4) for two weeks. Initially, the silver release was relatively fast, with 40.05 ppb of silver released in first 24 h followed by a very slow and constant release. To study the potential of GDA-Ag for medical applications, in vitro cytotoxicity of GDA-Ag against Human Embryonic Kidney 293 (HEK293) cell lines was studied using WST-assay. The cytotoxicity of the GDA-Ag was very low (5%) and was almost comparable to the control (blank glass disc) indicating that GDA-Ag has a promising potential for medical applications.
Controlled Ondansetron Release Based on Hydroxyethyl Starch Hydroxyethyl Methacrylate
Tahir, Muhammad Nazir,Adnan, Ahmad,Cho, Eunae,Jung, Seunho Korean Chemical Society 2012 Bulletin of the Korean Chemical Society Vol.33 No.12
Presented study describes the synthesis of photo cross-linkable and water soluble hydroxyethyl starch hydroxyethyl methacrylate (HESHEMA) samples with different degree of substitution (DS) by functionalization of hydroxyethyl starch (HES) with hydroxyethyl methacrylate (HEMA) or hydroxyethyl methacrylate carbonylimidazole (HEMACI) in DMSO using two different routes. It was revealed that the reaction time for HESHEMA synthesis can be reduced from 5 days to 24 h by conducting the reaction at $80^{\circ}C$ instead of at room temperature. Solubility of HESHEMA was found to be dependent on DS which in turn was dependent on ratio between HES and HEMA or HEMACI. HESHEMA samples with DS > 0.24 depicted insoluble in water, whereas the samples with DS < 0.05 did not form appreciable gel. HESHEMA samples with appropriate DS were converted into hydrogels by cross-linking polymer chains under UV radiations and resulting HESHEMA hydrogels showed swelling up to 1200%. Application of HESHEMA in controlled drug delivery was investigated by diffusion based encapsulation of Ondansetron, a serotonin 5-$HT_3$ receptor antagonist drug, mainly used for nausea and vomiting treatment.
Muhammad Nazir Tahir,정다함,김환희,Jae-Hyuk Yu,조은애,정선호 대한화학회 2014 Bulletin of the Korean Chemical Society Vol.35 No.1
Glass discs functionalized with alkynyl (GDA) terminated monolayers were prepared and incubated in AgNO 3 solution (GDA-Ag). The modified functional glass surfaces were characterized by X-ray photoelectron microscopy (XPS). The potential of GDA and GDA-Ag as antimicrobial surfaces was investigated. Anti- microbial efficacies of GDA against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, Bacillus cereus, and Candida albicans was relatively low ranging from 4.67 to 17.00%. However, the GDA- Ag was very effective and its antimicrobial efficacy ranged from 99.90 to 99.99% against the same set of microbial strains except for C. albicans where it was 95.50%. The durability of the Ag bonded to the terminal alkynyl groups was studied by placing the GDA-Ag in PBS buffer solution (pH 7.4) for two weeks. Initially, the silver release was relatively fast, with 40.05 ppb of silver released in first 24 h followed by a very slow and constant release. To study the potential of GDA-Ag for medical applications, in vitro cytotoxicity of GDA-Ag against Human Embryonic Kidney 293 (HEK293) cell lines was studied using WST-assay. The cytotoxicity of the GDA-Ag was very low (5%) and was almost comparable to the control (blank glass disc) indicating that GDA-Ag has a promising potential for medical applications.
Teleparallel Energy-momentum Distribution of Locally Rotationally Symmetric Spacetimes
M. Jamil Amir,Tahir Nazir 한국물리학회 2014 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.65 No.9
In this paper, we explore the energy-momentum distribution of locally rotationally symmetric(LRS) spacetimes in the context of the teleparallel theory of gravity by considering the three metrics,I, II and III, representing the whole class of LRS sapcetimes. In this regard, we use the teleparallelversions of the Einstein, Landau-Lifshitz, Bergmann-Thomson, and M¨oller prescriptions. Theresults show that the momentum density components for the Einstein, Bergmann-Thomson, andM¨oller prescriptions turn out to be same in all cases of the metrics I, II and III, but are differentfrom those of the Landau- Lifshitz prescription, while the energy components remain the same forthese three prescriptions only in all possible cases of the metrics I and II. We mention here thatthe M¨oller energy-momentum distribution is independent of the coupling constant ; that is, theseresults are valid for any teleparallel models.