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Ping Yu,Qilong Sun,Jianfeng Li,Zhenjiang Tan,Jianming Pan,Yongsheng Yan 한국화학공학회 2015 Korean Journal of Chemical Engineering Vol.32 No.4
Magnetic molecularly imprinted microspheres (MMIS) were successfully prepared by suspension polymerization,and then as-prepared MMIS were used as adsorbents for selective recognition of 2,4,6-trichlorophenol (2,4,6-TCP) from aqueous solutions. The results composites were characterized by Fourier transform infrared (FT-IR), X-raydiffraction (XRD), thermo gravimetric analysis (TGA), scanning electron microscope (SEM) and vibrating samplemagnetometer (VSM). The results demonstrated that MMIS possesses porous spherical morphology, and exhibits goodthermal stability and magnetic property (Ms=10.14 emu g−1). Then batch mode of binding experiments was used todetermine the equilibrium, kinetics and selectivity recognition. The Langmuir isotherm model fitted the equilibriumdata better than did the Freundlich model, and the maximum adsorption capacity on MMIS was about 1.7 times higherthan that of MNIS. Kinetics behaviors of MMIS were well described by the pseudo-second-order model. MMIS possessedoutstanding selectivity recognition for 2,4,6-TCP in the presence of other competitive phenols (such as sesamol,3-CP, thymol, 2,4-DCP). Furthermore, the reusability performance of MMIS showed about 17.53% loss after five repeatedcycles. Finally, the MMIS were successfully applied to the selective extraction of 2,4,6-TCP from the vegetablesamples.
Effects of different diets on the growth and development of young silkworms
Wang Yuanfei,Shu Qilong,Gu Haoyi,Feng Piao,Dai Minli,Zhu Qingyu,Liu Wei,Dai Yan,Li Fanchi,Li Bing 한국응용곤충학회 2023 Journal of Asia-Pacific Entomology Vol.26 No.4
To investigate the impact of different diets on the growth and development of the silkworm Bombyx mori (L.; Lepidoptera: Bombycidae), we conducted an analysis of differentially expressed genes (DEGs) between larvae fed an artificial diet (referred to as the AD group) and those fed mulberry leaves (referred to as the ML group) during the first, second, and third instars using RNA sequencing (RNA-Seq) technology. Our results revealed that the DEGs primarily belonged to pathways associated with lipid metabolism, carbohydrate metabolism, amino acid metabolism, the endocrine system, the nervous system, the digestive system, the immune system, and oxida tion–reduction processes. Notably, in the AD group, there was a decrease in transcript levels of genes related to amino acid metabolism synthases, while the transcript levels of antimicrobial peptide genes were up-regulated. Furthermore, genes associated with cytochrome P450 (CYP) enzymes exhibited down-regulation in the AD group. These observed changes likely contributed to the delayed growth and compromised robustness observed in the AD group. Overall, these findings provided valuable insights into the mechanisms underlying the differ ences in growth, development, disease resistance, and adversity resistance between silkworms fed an artificial diet and those fed mulberry leaves.
Ping Yu,Yongsheng Yan,Qilong Sun,Jianfeng Li,Zhenjiang Tan,Chunxiang Li 한국공업화학회 2015 Journal of Industrial and Engineering Chemistry Vol.29 No.-
In the work, we reported an effective method for the preparation of surface molecularly imprintedpolymers based on bacillus as substrate material with superparamagnetic property throughminiemulsion polymerization. Then, the obtained magnetic surface molecularly imprinted polymers(MMIPs) were evaluated as adsorbents for selective recognition 2,4,6-trichlorophenol (2,4,6-TCP) fromaqueous medium. The resulting MMIPs were characterized by several techniques including FT-IR, SEM,TEM, Raman, XRD, VSM and TGA. The results demonstrated rod-shaped MMIPs was covered withimprinted layer, and exhibited chemical stability and good magnetic sensitivity. Batch mode of bindingstudies were carried out to determine the equilibrium isotherm, kinetics, selectivity adsorption andregeneration of MMIPs toward 2,4,6-TCP. The results indicated that the selective adsorption behaviors ofMMIPs were well described by the Langmuir isotherm model and the pseudo-second-order kineticsmodel. The specific adsorption capacity of MMIPs was 45.16 mg g 1 at 298 K, which was 2.15 timeshigher than that of magnetic non-imprinted polymers (MNIPs). The selective recognition studiesdemonstrated the outstanding affinity and selectivity toward 2,4,6-TCP in the presence of competitivephenols. The regeneration study showed excellent adsorption capacity even after five regenerationcycles. In addition, MMIPs were successfully applied to the extraction of 2,4,6-TCP from milk sample.
Xiaoju Liu,Haitao Feng,Yang Li,Xiaoyan Ma,Fang Chen,Qilong Yan 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.115 No.-
Three novel ferrocene-based hydrazone energetic transition-metal complexes denoted as M/E-FcDz-TMCs (M = Co (II), Fe (III), and Co(II)Fe(III)), were successfully prepared to improve the thermal decompositionof ammonium perchlorate (AP) and anti-migration performance of Fc-based catalysts. 1-hydrazinoethylene-ferrocene (E-FcDz) with unique electronic structure and energy bonds (C@N, NAN)as ligand reacted with transition metal Co, or Fe mono-metal nodes, and Co-Fe bimetal nodes, respectively. The chemical structure, crystalline texture, and morphology were confirmed, and the catalytic performancewas investigated. The thermal decomposition kinetics were estimated by applying Kissinger,FWO, and KAS methods. The results revealed that M/E-FcDz-TMCs had superior catalytic performancesfor AP decomposition compared to the traditional catalyst catocene due to their high electron transportcapacity. Especially, CoFe/E-FcDz-TMCs showed the best catalytic efficiency due to the hybridizationbetween Co (II) 3d and Fe (III) 3d orbitals in the structure led to electron redistribution, driving the optimalsynergistic catalytic effect of the bimetal Co-Fe nodes and E-FcDz, and further enhancing catalysis forAP. Moreover, AP/CoFe/E-FcDzTMCs showed the best combustion performance. In addition, the thermaldecomposition products of AP were explored by TG/FTIR, and the AP thermal decomposition processcould be explained by a possible mechanism following the principle of electron transfer theory.