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이경희,한현석,윤효근,부진효,이순보,곽현태 성균관대학교 기초과학연구소 1998 論文集 Vol.49 No.-
The coadsorption of CO and O₂ on W(110) surface was studied by LEED, TDS, and photoelectron spectroscopy. In the TDS for the coadsorption of CO at RT on O₂ precovered W(110) surface, two CO desorption states were observed at about 400 and 1150 K, called α and β , respectively. The β-CO spectra with second order desorption kinetics were shifted to lower desorption temperature as increasing the amount of preadsorbed atomic oxygen on the W(110). Moreover, the β-CO spectra were gradually increased with increasing the amount of preadsorbed oxygen to 0.5 ML. Even though a (2 x 1) LEED pattern appeared during oxygen adsorption at RT and 1-3 L oxygen exposures, we didn't observe any new pattern induced by CO in this study. Only the structure of c(11 x 5) was obtained at temperature in the range of 800-1100 K. These results indicated that there were interaction between CO and O and thereby the β-CO might riot be dissociated even at the higher temperature than 800 K. By using the XPS and UPS, it was also confirmed that the coadsorbed β-CO at 900 K doesn't dissociate as the experimental results of the adsorption of pure CO on W(110) surface at the same temperature. According to the valence band spectra, two CO peaks at near -10.7 eV (4σ) and -7.0 eV (5σ+1π) were observed, indicating molecular CO adsorption on the oxygen preadsorbed surface at RT. Even heating the coadsorbed surface to 900 K, we could also detect the CO 4σ peak which can be an important factor for identifying a contribution of the CO 4σ molecular orbital to the CO-metal bond. To our best knowledge, this is the first report and quite contradictory result to that reported previously.