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류승훈 ( Sung Hun Ryu ),최원석 ( Won Seok Choi ),김건완 ( Gun Wan Kim ),도제성 ( Je Sung Do ),유명우 ( Myung Ho Yoo ) 한국고무학회 2011 엘라스토머 및 콤포지트 Vol.46 No.2
In the present investigation, thermal aging behavior of H-NBR/NBR blend with various H-NBR content was investigated. Mixture of dicumyl peroxide and sulfur were used as a curing agent. The influence of the thermal aging of the H-NBR/NBR blends on the solid state properties such as tensile strength, elongation at break, hardness and abrasion resistance was investigated. Tensile strength was increased with increasing H-NBR content, while abrasion resistance was decreased. Both elongation at break and hardness were not affected by the addition of H-NBR. The properties such as hardness, tensile strength and elongation at break of the aged samples were lower than unaged samples. However, the rate of deterioration of those properties was decreased by increasing the H-NBR content, which indicated that improved thermal aging behavior was obtained by the addition of H-NBR. Abrasion loss was increased with increasing aging time, but it became less by the addition of H-NBR addition. 본 연구는 H-NBR 함량 변화에 따른 H-NBR/NBR 블렌드의 열노화 거동에 대하여 살펴보았다. 이 때 가교제로는 dicumyl peroxide와 황 혼합물을 사용하였으며, 열노화에 따른 H-NBR/NBR 블렌드의 인장강도, 파괴신율, 경도 그리고 내마모성의 변화를 살펴보았다. H-NBR을 첨가함에 따라 인장강도는 증가하였으나 내마모성은 감소하는 현상을 나타내었다. 파괴신율과 경도는 H-NBR의 영향을 받지 않았다. 노화가 진행된 모든 시편은 초기 시편보다 낮은 인장강도, 파괴신율, 경도를 나타내었다. 그러나 H-NBR의 함량이 증가함에 따라 이러한 물성저하 속도가 감소함을 알 수 있었다. 즉 H-NBR 첨가에의해 열노화 특성이 향상됨을 알 수 있었다. 모든 NBR/H-NBR 블렌드는 노화시간이 증가함에 따라 내마모성이 감소하였으며, H-NBR을 첨가한 경우 내마모성의 저하가 상대적으로 낮음을 알 수 있었다.
SWCNT/에폭시 복합체의 기계적 전기적 성질에 미치는 Clay의 상승효과
최원석 ( Won Seok Choi ),류승훈 ( Sung Hun Ryu ) 한국고무학회 2014 엘라스토머 및 콤포지트 Vol.49 No.3
단일벽 카본나노튜브 (SWCNT)/에폭시 복합체에 sodium-montmorillonite (Na+-MMT)을 첨가하여 MMT크기와 MMT/SWCNT 비율이 복합체의 기계적 전기적 성질에 미치는 영향에 대하여 살펴보았다. 다른 크기를 갖는 3종류의 MMT를 사용하였으며, 모두 SWCNT의 분산에 효과적임을 알 수 있었다. MMT함량이 증가함에 따라 SWCNT/에폭시 복합체의 기계적인 성질은 증가하였으며, 임계함량에 도달한 후에는 감소하기 시작하였다. 그러나 표면전기저항은 MMT 함량이 증가함에 따라 감소하였으며, 임계함량에 도달한 후 증가하기 시작하였다. 최대 기계적 성질과 최소전기특성은 임계 MMT/SWCNT 비율은 MMT 크기에 크게 의존하였으며, 이는 MMT크기가 증가함에 따라 감소하였다. Sodium-montmorillonite (Na+-MMT) was introduced into single wall carbon nanotube (SWCNT)/epoxy composite to investigate the effect of MMT size and MMT/SWCNT ratio on the mechanical and electrical properties of composite. Three different sizes of MMTs were used and all were found to function as effective dispersion aids for SWCNTs. Mechanical properties of SWCNT/epoxy composite increased with MMT content; tending to decrease once the MMT content reached a critical level. However, the surface electrical resistance decreased with increasing MMT content and tended to increase after the critical content was reached. Critical MMT/SWCNT ratio for maximum mechanical properties and minimum electrical resistivity was strongly dependent on the MMT size. Critical MMT/SWCNT ratio was decreased with MMT size.
이동현 ( Dong Hyun Lee ),류승훈 ( Seung Hun Ryu ),조정흠 ( Jung Heum Jo ),서성철 ( Sung Chul Seo ) 한국산업보건학회 2014 한국산업보건학회지 Vol.24 No.4
Objectives: The adverse health effects attributed to exposure to radon have been well known over the world. However, the efforts for prevention and mitigation of radon have not been taken in Korea so far. The purpose of this study was to evaluate the effectiveness of mitigation methods applied for various types of houses and public buildings with high level of radon. Methods: Based on the results of National Radon Surveyperformed by the National Institute of Environmental Research(NIER) in 2010-2012, we selected 30 candidate buildings consisting of 20 houses and 10 public buildings with greater than 148 Bq/㎥ of radon level. We measured the concentration of radon in 30 buildings, using E-PERMs and RAD-7 during January to March of 2013. More than five E-PERMs and one RAD-7 per house were installed for seven days. Ten houses and five public buildings were finally chosen to be mitigated after mainly considering the level of radon and the location of buildings nationwide. Three mitigation methods such as Sealing, two types of Active Ventilation(window-shaped and wall-typed ventilations), and Active Soil Depressurization(ASD) were applied, and the concentrations of radon were measured before and after mitigation, respectively. To evaluate the effectiveness of mitigation methods, reduction rates of radon were calculated and Wilcoxon``s signed-rank test was performed. Results: The mean concentration of 15 buildings just before radon mitigation was 297.8 Bq/㎥, and most of the buildings were located in Gangwon, Chungbuk, Chungnam, and Daegu areas(73.3%), and built in 1959-1998. The level of radon decreased from 48% to 90% and kept the below recommendation limit of 148 Bq/㎥ after installation of radon mitigation. Among mitigation methods applied, the reduction rate(58.7-90.4%) of radon attributed to ASD was the greatest than that of other methods, followed by Active Ventilation(48.4-78.4%) and Sealing(<22%). The effectiveness of radon reduction by window-shaped Active Ventilation(63.2-75.2%) was relatively better than that of wall-typed Active Ventilation(48.4-54.3%). Conclusions: The results of this study indicate that ASD could be more effective for radon mitigation. Moreover, our findings would be background information in future for making the strategy for radon mitigation nationwide, as well as for developing Korean-version of mitigation techniques according to types of dwellings in Korea.