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Wang, Jie,Luo, Xiliang,Young, Christine,Kim, Jeonghun,Kaneti, Yusuf Valentino,You, Jungmok,Kang, Yong-Mook,Yamauchi, Yusuke,Wu, Kevin C.-W. American Chemical Society 2018 Chemistry of materials Vol.30 No.13
<P>Hollow micro-/nanostructures with controllable shape, size, and composition are an intriguing class of porous materials with a promising potential for various applications. Metal-organic frameworks (MOFs) have been attractive as promising precursors for preparing carbon materials with various kinds of nanoartchitectures owing to the rich variety in their composition, morphology, and structure. Herein, we report a glucose-assisted hydrothermal method for directly transforming MOFs into hollow carbonaceous materials. During the hydrothermal reaction, the MOF particles (zeolitic imidazolate frameworks-8, ZIF-8) are decomposed, which is induced by the acid generated from the hydrolysis of glucose. At the same time, the species released from the decomposed MOF continuously diffuse out and react with the glucose-derived polymers, resulting in the formation of hollow Zn-containing carbonaceous composites. Following calcination at 900 °C and 500 °C under a nitrogen atmosphere, hollow carbon and zinc oxide/carbon (ZnO/C) materials can be obtained, respectively. The obtained ZnO/C materials with hollow interiors exhibit more active sites, which are supported by their superior electrochemical performance for supercapacitor applications. The proposed method in this work provides a pathway for synthesizing a variety of multicompositional inorganic hollow structures from MOFs, which would facilitate their potential use in practical applications.</P> [FIG OMISSION]</BR>
Dynamic analysis of three adjacent bodies in twin-barge floatover installation
Wang, Shuqing,Li, Xiliang Techno-Press 2014 Ocean systems engineering Vol.4 No.1
Floatover technology has been widely used in offshore installation, which has many substantial advantages compared with the traditional derrick barge. During the topside offloading of a twin-barge floatover installation, the transport barge is side by side moored between two floatover barges. In this paper, the twin-barge model with the connecting hawsers and pneumatic fenders is established. Coupled dynamic analysis is carried out to investigate the motions of the barges under wind, wave and current environments. Particular attention is paid to the effects on system responses with different frictional performance of fender, axial stiffness of the hawsers and environmental conditions. The research results can be used for optimizing the parameters of the system and reducing the risk of topside offloading.
Xiliang Liu,Song Liu,Youkun Fan,Jin Qi,Xin Wang,Wei Bai,Dongliang Chen,Chengdong Xiong,Lifang Zhang 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.104 No.-
The poly(L-lactide-co-e-caprolactone) (PLCL) ureteral stent creeps and loses shape stability, increasingthe risk of stent tube dislocation. The rubbery biodegradable cross-linked PLCL networks were preparedthrough gamma irradiation under vacuum in the presence of trimethylolpropane triacrylate (TMPTA),pentaerythritol tetraacrylate (PET4A), and pentaerythritol triacrylate (PETA). At a standard sterilizationdose of 25 kGy, the gel content and network density of PLCL networks increased with increasingcrosslinking agent content (1, 3, 5, 7 wt%), and crosslinking efficiency decreased in the order ofPETA > PET4A > TMPTA. The average molecular weight (Mc ) between two crosslinks ranged from 2000to 105 g/mol. To perform the beneficial semi-interpenetrated polymer network and characterized bythe principle, the networks were processed in several doses (25, 50, 75, 100, and 125 kGy). In place ofthe Charlesby-Pinner equation, the irradiation cross-linking followed the Chen-Liu-Tang equation. ThePLCL network with 7 wt% PETA had a gel fraction of 83%, tensile strength of 34.7 MPa, and tensile setvalue as low as 5%. Furthermore, degradation in vitro was slowed down. Thus, PLCL networks with appropriateelasticity and flexibility, inherent biodegradability, and excellent biocompatibility can provide apromising alternative method for soft tissue repair engineering, such as ureteral stents.
Jin Yong,Wang Zhilin,Zhang Zhenxin,Lin Bo,Ge Zhengjun,You Qidong,Chen Hao,Liu Xiliang,Xu Chenghao,Gao Shuaiqiang,Wu Yi,Abro Zafar 한국자원공학회 2023 Geosystem engineering Vol.26 No.4
CO2 flooding is a significant technology for oil recovery, to reveal the microcosmic mechanism of CO2 flooding, CO2 slim tube experiments, long core CO2 flooding experiments, gas chromatography analysis experiments, and numerical simulations were carried out. The results show that the miscibility increase can improve the effect of dissolution and diffusion in the CO2-crude oil system, easing the CO2 finger entry phenomena, and delaying gas breakthrough time. Besides, the CO2 -crude oil interaction is enhanced by increasing the pressure difference between the injection well and the production well, which improves the oil recovery of CO2 flooding. Besides, CO2 carries the light and medium components (C4 ~ 25) forward to cross the first miscible zone, which makes the CO2-crude oil system form double miscible zones. This study reveals the rule of CO2 front and light components front under different miscibility degrees of CO2 flooding from the microscopic perspective and deepens the theory of CO2 flooding in low-permeability sandstone reservoirs.
Zhongyuan Tian,Lu Yang,Penghui Li,Yuncai Xiao,Jian Peng,Xiliang Wang,Zili Li,Mei Liu,Dingren Bi,Deshi Shi 한국통합생물학회 2016 Animal cells and systems Vol.20 No.2
Enterococcus faecium HDRsEf1 strain used as a probiotic to inhibit intestine inflammation and improve animal growth performance has been proved by our research team; however, it remains unclear how HDRsEf1 was recognized by intestine cells and how it activates the downstream pathway which benefit intestine health. In this study, HDRsEf1 was used to stimulate HT-29 cell line to partially uncover the intestine benefit mechanism of HDRsEf1. The results of cell viability assays showed that HDRsEf1 had no toxicity on HT-29 at concentrations up to 1 × 108 CFU/mL, HDRsEf1 could upregulate the TLR1, TLR2, and TLR6 mRNA level, especially TLR2, and significantly downregulate the mRNA level of TLR4, TLR5, TLR7, TLR8, but did not significantly affect the mRNA or protein level of MyD88, which suggests that HDRsEf1 activates the TLR2 pathway in an MyD88-independent pattern. HDRsEf1 could significantly downregulate the mRNA level of pro-inflammatory factors IL-1β, IL-6, IL-8, IL-12p35, IL-17, and TNF-α and did not affect the anti-inflammatory factors IL-10, PPAR-γ, and TSLP; besides HDRsEf1 did not upregulate the degradation of IκB in HT-29 cells. By contrast, enterohemorrhagic E. coli (EHEC) O157:H7 strongly up-regulated the mRNA level of pro-inflammatory factors IL-1β, IL-6, IL-8, IL-23, and TNF-α, downregulated obviously anti-inflammatory factor PPAR-ɣ, and obviously upregulated the degradation of IκB, which suggested that HDRsEf1 may act as an antagonist to regulate intestine inflammation response to intestine pathogen. These findings shed a light on the intestine benefit mechanism of HDRsEf1.
Trichoderma biodiversity in major ecological systems of China
Kai Dou,Jinxin Gao,Chulong Zhang,Hetong Yang,Xiliang Jiang,Jishun Li,Yaqian Li,Wei Wang,Hongquan Xian,Shigui Li,Yan Liu,Jindong Hu,Jie Chen 한국미생물학회 2019 The journal of microbiology Vol.57 No.8
An investigation of Trichoderma biodiversity involving a large-scale environmental gradient was conducted to understand the Trichoderma distribution in China. A total of 3,999 isolates were isolated from forestry, grassland, wetland and agriculture ecosystems, and 50 species were identified based on morphological characteristics and sequence analysis of genetic markers. Trichoderma harzianum showed the largest proportion of isolates and the most extensive distribution. Hypocrea semiorbis, T. epimyces, T. konilangbra, T. piluliferum, T. pleurotum, T. pubescens, T. strictipilis, T. hunua, T. oblongisporum and an unidentified species, Trichoderma sp. MA 3642, were first reported in China. Most Trichoderma species were distributed in Jilin and Heilongjiang Provinces in northeast China and the fewest were distributed in Qinghai Province. Based on the division of ecological and geographic factors, forestry ecosystems and low-altitude regions have the greatest species biodiversity of Trichoderma.