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Conversion of methanol into light olefins over ZSM-11 catalyst in a circulating fluidized-bed unit
Xiaojing Meng,Huiwen Huang,Qiang Zhang,Minxiu Zhang,Chunyi Li,Qiukai Cui 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.3
Methanol conversion and the reaction pathway were investigated in a pilot-scale circulating fluidized-bed (CFB) unit over hierarchical ZSM-11 catalyst. Experimental results indicated that ZSM-11 catalyst was highly resistant to external coke due to the formation of mesopores. Elevated temperatures favored the production of propylene and butylene and decreased the yield of ethylene. Additionally, no direct relations were shown between the formation of ethylene and other products under different pressures, suggesting that ethylene was a primary product produced at the initial of the reaction. Methylation-cracking and oligomerization were verified as the main reaction pathway for the formation of C3 + alkenes., Methylation and oligomerization of olefins were dominated under high methanol partial pressure and consequently responsible for the production of higher olefins, while the b-scission of C7 = for propene and butylene, and C8 = for butylene were enhanced at low methanol partial pressure.
Xiaojing Zhang,Nan Zhang,Yue Zhou,Robert Delatolla,Yali Song,Yongpeng Ma,Hongzhong Zhang 대한환경공학회 2020 Environmental Engineering Research Vol.25 No.6
In this study, the effect of CuO nanoparticles (NPs) on partial nitrification (PN) process was investigated at various pH values. The short- and long-term experiments were carried out in six identical reactors, with or without CuO NPs, at pH values of 6.5, 8.0 and 10.0. The ammonia oxidation, reaction rates, copper content, and the microbial community were investigated. The results of this work suggested that CuO NPs inhibited the ammonia oxidation by aerobic ammonia-oxidizing bacteria (AOB), under both the acid and alkali conditions. AOB could resist the acid condition but was significantly suppressed when CuO NPs was fed, and the low pH did not aggravate the inhibition level. Almost all the bacteria lost bioactivity under the pH as 10.0, while anaerobic ammonia-oxidizing bacteria survived. The acid condition increased the Nitrosomonas relative abundance while the alkali condition lowered it. More than 60% of the supplied CuO NPs was discharged via effluent.
Design and behavior of 160 m-tall post-tensioned precast concrete-steel hybrid wind turbine tower
Xiangguo Wu,Xuesen Zhang,Qingtan Zhang,Dong Zhang,Xiaojing Yang,Faqiang Qiu,Suhyun Park,Thomas H.-K. Kang 국제구조공학회 2022 Steel and Composite Structures, An International J Vol.44 No.3
Prefabricated hybrid wind turbine towers (WTTs) are promising due to height increase. This study proposes the use of ultra-high performance concrete (UHPC) to develop a new type of WTT without the need to use reinforcement. It is demonstrated that the UHPC WTT structure without reinforcing bars could achieve performance similar to that of reinforced concrete WTTs. To simplify the design of WTT, a design approach for the calculation of stresses at the horizontal joints of a WTT is proposed. The stress distribution near the region of the horizontal joint of the WTT structure under normal operating conditions and different load actions is studied using the proposed approach, which is validated by the finite element method. A further parametric study shows that the degree of prestressing and the bending moment both significantly affect the principal stress. The shear-to-torsion ratio also shows a significant influence on the principal tensile stress.
Sport and exercise impact on the therapy with nanomedicine in drug delivery
Zhang, Bo,Jin, Hao,Duan, Xiaojing Techno-Press 2022 Advances in nano research Vol.13 No.3
Nanomachines can be pretty helpful in curing diseases. Nanomototors, thanks to their self-propelled feature, are one of the best structures to be utilized as drug delivery devices. These devices have been employed in biomedical application as they can improve the efficiency of drug delivery. In this study stability of a designed nanomotor in the bloodstream is investigated when the physical activities have been done considering the physical activities. Sports training, as well as exercise enhance the bloodstream, and this factor can significantly impact the drug-delivery quality. The mathematical simulation of nanomotor movement in the condition of the sports is done based on the mechanical sciences, and the impact of various essential parameters is discussed in detail.
Distinct growth phenomenon observed on L-Arg․ CF3COOH crystals
Xiaojing Liu,Zeyan Wang,Guanghui Zhang,Guangwei Yu,Aidong Duan,Xinqiang Wang,Dong Xu 한국물리학회 2009 Current Applied Physics Vol.9 No.1
Atomic force microscopy has been employed to study the growth behaviour on the {101} facets of L-Arg ․ CF3COOH crystals grown at 25℃ at a supersaturation of σ = 0.2. Nucleation on the wider step terraces and a large nucleus composed of two separate 2D nuclei were observed for the first time. For the region where blocking occurs convex pattern are found in the macrosteps, which correspond to the sites of the impurities that act as pinning points hindering step propagation. Finally, liquid inclusions will be generated because of disparate formation mechanisms. Atomic force microscopy has been employed to study the growth behaviour on the {101} facets of L-Arg ․ CF3COOH crystals grown at 25℃ at a supersaturation of σ = 0.2. Nucleation on the wider step terraces and a large nucleus composed of two separate 2D nuclei were observed for the first time. For the region where blocking occurs convex pattern are found in the macrosteps, which correspond to the sites of the impurities that act as pinning points hindering step propagation. Finally, liquid inclusions will be generated because of disparate formation mechanisms.
( Xiaojing Li ),( Zhifeng Li ),( Zhao Han ),( Ling Zhang ),( Zhao Liu ),( Baoguo Liu ) 대한피부과학회 2018 Annals of Dermatology Vol.30 No.5
Background: Actinic keratosis (AK) was an intraepidermal tumor which caused by ultraviolet irradiation-induced skin damage. Objective: The aim was to screen biomarkers for development of skin disease by comparing the gene expression profiles between cutaneous squamous cell carcinoma (CSCC) and AK. Methods: GSE45216 with 30 cutaneous squamous cell carcinoma patients and 10 actinic keratosis patients were downloaded and significance analysis of microarrays was processed to screen differently expressed genes (DEGs). Fisher’s exact test was processed for DEGs enrichment. Pathway relationship network systematically reflected the signal conduction and synergism between enriched pathways based on Kyoto Encyclopedia of Genes and Genomes database. Gene co-expression network was constructed according to gene expression data. Quantitative real- time-PCR was used to verify screened biomarkers. Results: Total 410 DEGs were screened and enriched into various functions, such as signal transduction and negative regu-lation of apoptotic process. They also participated into cytokine- cytokine receptor interaction and focal adhesion. The pathway relationship network was constructed with 27 nodes. Hub nodes with higher degree of this network were mitogen-activated protein kinase signaling pathway and apoptosis. The gene co-expression network was constructed with 39 nodes. Thereinto, hub node was ELOVL fatty acid elongase. The expression levels of ELOVL4 and HPGD were significantly higher in CSCC samples than that in AK samples, while the expression levels of INHBA and LAMC2 in CSCC samples were significantly lower than that in AK samples. Conclusion: These screened genes, including ELOVL4, HPGD, INHBA and LAMC2, played important roles in transformation from AK to CSCC. (Ann Dermatol 30(5) 536∼543, 2018)
Parametric study of an undulating plate in a power-extraction regim
Xiaojing Sun,Jihua Zhang,Huizhen Li,Diangui Huang 대한기계학회 2019 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.33 No.1
Our previous studies suggest that instead of propulsion, a body undergoing lateral traveling-wave-like motions can also work like a kinetic energy harvester which extracts energy from moving fluids including wind and water currents. Parameters including wavelength, dimensionless wave velocity and amplitude have critical effects on the energy extraction efficiencies of this type of undulating foil energy harvester. In this paper, a two-dimensional, numerical simulation of a flexible plate undergoing a traveling wave motion was then conducted. At a given dimensionless wave speed, it is found that there exits an optimum wavelength at which this type of energy harvester can extract the maximum amount of kinematic energy from the flow. Moreover, the optimum value of the wavelength increases as amplitude increases. A high efficiency area appears under the optimal combination of wavelength and amplitude. At a given amplitude, the optimal dimensionless wave speed for maximum power extraction decreases with increasing wavelength. The high efficiency area of the undulating plate resulting from the optimal combination of wavelength and wave speed is identified. At a given wave length, there is an optimal value of amplitude at which the maximum energy extraction can be achieved. In this case, a high efficiency area representing the optimal combination of amplitude and wave speed has also been discovered.
Efficient production of propylene and gasoline from methanol in multi-regime riser
Xiaojing Meng,Huiwen Huang,Qiang Zhang,Chunyi Li,Qiukai Cui 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.4
High gas-solid contact efficiency and low solid back-mixing are necessary to both promote methanol conversion and inhibit side reactions. Thus, a novel multi-regime reactor with dense-phase reaction section and dilutephase conveying region was designed. The reactor promoted stable reaction activity during a 300 h pilot-scale evaluation with high yields of propylene and gasoline. A process for maximum propylene and gasoline production from methanol (PGFM) characterized by moderate operating severity, application of ZSM-11 catalyst and novel reactor, and stratified reprocessing or etherification of light gasoline and C4 olefins was proposed. The PGFM process can be implemented in the existing FCC process and is considered to be more economic and flexible.