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Controlled Cationic Polymerization of Sulfide-Containing Vinyl Ethers
Takeshi Namikoshi,Yuhei Watanabe,Ayaka Kaneda,Kazuma Ishikawa,Shinji Watanabe,Miki Murata 한국고분자학회 2022 Macromolecular Research Vol.30 No.1
The living cationic polymerizations of sulfide-containing vinyl ethers, namely, alkyl-sulfide-containing 2-(ethylthio)ethyl vinyl ether (ESEVE) and arylsulfide- containing 2-(phenylthio)ethyl and 2-[4-(methylthio)phenoxy]ethyl vinyl ethers (PSEVE and MSPEVE, respectively), were examined using HCl/ZnCl2, 1-(isobutoxy)ethyl acetate (IBEA)/Et1.5AlCl1.5, and IBEA /Et1.5AlCl1.5/SnCl4 as initiators. The polymerization of ESEVE terminated at a 35% monomer conversion, and a high-molecular-weight polymer was not obtained; instead, the nucleophilicity of the sulfur moiety in ESEVE led to cyclization, forming five-membered ring sulfonium species. In contrast, the side reactions were suppressed when PSEVE was used, which has a less-nucleophilic sulfur moiety on its benzene ring, and polymerization proceeded to an 88% conversion, affording a high-molecular-weight polymer with a narrow molecular weight distribution (Mw= 12,500, Mw/Mn = 1.18). Furthermore, cyclic sulfonium was not produced during the polymerization of MSPEVE, in which the sulfur atom was farther from the generated carbocation; the polymerization proceeded quantitatively producing a high-molecular-weight polymer with a narrow molecular weight distribution, despite the short lifetime of the growing species. In particular, a high-molecular-weight polymer with the narrowest distribution (Mw= 13,500, Mw/Mn = 1.08) was obtained when SnCl4 was used as the Lewis acid.
Koinuma, Shoichi,Fujimoto, Yu,Hayashi, Yasuhiro,Shinji, Takao,Watanabe, Yosuke,Tadokoro, Masayuki The Korean Institute of Electrical Engineers 2014 The Journal of International Council on Electrical Vol.4 No.2
The installation of residential fuel cell systems (FCs) with photovoltaic generation systems (PVs) in residences has begun in Japan. Because of the reverse power flow from PVs, the line voltage may exceed the proper range during daytime operation. In addition, because residential PVs are connected to a single-phase distribution system, the voltage imbalance rate may increase. Here, we focus on an FC with a large available capacity during the daytime, so as to adjust the voltage by reactive power control with the available capacity of the FC. We propose a method of reactive power control that uses the available capacity of FCs to improve the voltage magnitude and voltage imbalance rate in a distribution network.
Sanuki, Takuro,Mishima, Gaku,Kurata, Shinji,Watanabe, Toshihiro,Kiriishi, Kensuke,Tachi, Mizuki,Ozaki, Yu,Okayasu, Ichiro,Kawai, Mari,Matsushita, Yuki,Miura, Keiichiro,Ayuse, Takao The Korean Dental Society of Anesthsiology 2015 Journal of Dental Anesthesia and Pain Medicine Vol.15 No.3
Background: We hypothesized that ketamine, when administered as the anesthetic induction agent, may prevent cardiovascular depression during high-dose remifentanil administration, unlike propofol. To test our hypothesis, we retrospectively compared the hemodynamic effects of ketamine, during high-dose remifentanil administration, with those of propofol. Methods: Thirty-eight patients who underwent oral surgery at the Nagasaki University Hospital between April 2014 and June 2015 were included in this study. Anesthesia was induced by the following procedure: First, high-dose remifentanil ($0.3-0.5{\mu}g/kg/min$) was administered 2-3 min before anesthesia induction;next, the anesthetic induction agent, either propofol (Group P) or ketamine (Group K), was administered. Mean arterial pressure (MAP) and the heart rate were recorded by the automated anesthesia recording system at four time points: immediately before the administration of high-dose remifentanil (T1);immediately before the administration of propofol or ketamine (T2);2.5 min (T3), and 5 min (T4) after the administration of the anesthetic induction agent. Results: In Group P, the MAP at T3 ($75.7{\pm}15.5mmHg$, P = 0.0015) and T4 ($68.3{\pm}12.5mmHg$, P < 0.001) were significantly lower than those at T1 ($94.0{\pm}12.4mmHg$). However, the MAP values in the K group were very similar (P = 0.133) at all time points. The heart rates in both Groups P (P = 0.254) and K (P = 0.859) remained unchanged over time. Conclusions: We showed that ketamine, when administered as the anesthetic induction agent during high-dose remifentanil administration, prevents cardiovascular depression.
Experimental and numerical flow analysis in hydraulic vane pump
Junichi SUEMATSU,Tetsuhiro TSUKIJI,Mariko WATANABE,Shinji YAKABE,Hirohito WATANABE,Yoshinari NAKAMURA,Kazunari SUZUKI 유공압건설기계학회 2015 유공압건설기계학회 학술대회논문집 Vol.2015 No.10
The purpose of this study is to conduct a three dimensional flow analysis of a hydraulic vane pump by using computational fluid dynamics (CFD), to evaluate an accuracy of volumetric flow rate in CFD compared to experimental value and to examine a influence of the evaporation coefficient and condensation coefficient in Zwart–Gerber–Belamri cavitation model to pressure in a vane chamber. In this study, standard k-ε turbulent model with the Zwart–Gerber–Belamri cavitation model is used to estimate the cavitating flow in vane pump. In CFD, two notch models are used. From results of experiments and CFD analysis of volumetric flow rate, there is little difference between the experiments and CFD results in the low speed range. However, for high speed range, in a case with no cavitation model, the CFD results of volumetric flow rate are different from the experimental ones. On the other hand, in the case with cavitation model, those agree with the experimental values. In this case, the error of volumetric flow rate is less than 1% in the low speed range and less than 2.5% in the high speed range. From CFD results of pressure fluctuation in a vane chamber when the evaporation coefficient and condensation coefficient in the cavitation model are varied, the surge pressure can be seen in a vane chamber. In conclusion, it could be considered that the CFD calculation with cavitation model is sufficiently accurate in volumetric flow rate. In addition, as the evaporation coefficient becomes large, amplitude of the pressure fluctuation in a vane chamber after a surge pressure becomes large, as the condensation coefficient becomes large, the surge pressure in a vane chamber becomes low.