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The hierarchical microstructure of helical polyacetylene nanofiber
Zhao Xia Jin,Zhi Yong Wang,Zu Jin Shi,Hyun Jung Lee,Yung Woo Park,Kazuo Akagi 한국물리학회 2007 Current Applied Physics Vol.7 No.4
The microstructure of helical polyacetylene nanofiber was studied by HRTEM. A hierarchical self-organized microstructure in nanometer scales was observed firstly.
Two new tirucallane triterpenoids from the leaves of Aquilaria sinensis
Jin Tang Cheng,Ya Qiong Han,Juan He,Xing De Wu,Liao Bin Dong,Li Yan Peng,Yan Li,Qin Shi Zhao 대한약학회 2013 Archives of Pharmacal Research Vol.36 No.9
Two new tirucallane triterpenoids, aquilacallanesA–B (1–2), together with 15 known compounds(3–17) were isolated from the leaves of Aquilaria sinensis. The structures of these new compounds were elucidated onthe basis of extensive spectroscopic analyses. All compoundswere evaluated for their cytotoxic activity againstfive human cancer cell lines. The known compounds,ursolic acid (7) and 5,7,40-trimethoxyflavone (14), exhibitedweak cytotoxic activity against some cells.
( Jin Xu ),( Xuejia Shi ),( Xiaomeng Zhang ),( Zhenzhong Wang ),( Wei Xiao ),( Linguo Zhao ) 한국미생물생명공학회(구 한국산업미생물학회) 2021 Journal of microbiology and biotechnology Vol.31 No.3
To efficiently recycle GH78 thermostable rhamnosidase (TpeRha) and easily separate it from the reaction mixture and furtherly improve the enzyme properties, the magnetic particle Fe<sub>3</sub>O<sub>4</sub>-SiO<sub>2</sub>-NH<sub>2</sub>-Cellu-ZIF8 (FSNcZ8) was prepared by modifying Fe<sub>3</sub>O<sub>4</sub>-NH<sub>2</sub> with tetraethyl silicate (TEOS), microcrystalline cellulose and zinc nitrate hexahydrate. FSNcZ8 displayed better magnetic stability and higher-temperature stability than unmodified Fe<sub>3</sub>O<sub>4</sub>-NH<sub>2</sub> (FN), and it was used to adsorb and immobilize TpeRha from Thermotoga petrophilea 13995. As for properties, FSNcZ8-TpeRha showed optimal reaction temperature and pH of 90℃ and 5.0, while its highest activity approached 714 U/g. In addition, FSNcZ8-TpeRha had better higher-temperature stability than FN. After incubation at 80℃ for 3 h, the residual enzyme activities of FSNcZ8-TpeRha, FN-TpeRha and free enzyme were 93.5%, 63.32%, and 62.77%, respectively. The organic solvent tolerance and the monosaccharides tolerance of FSNcZ8-TpeRha, compared with free TpeRha, were greatly improved. Using naringin (1 mmol/l) as the substrate, the optimal conversion conditions were as follows: FSNcZ8-TpeRha concentration was 6 U/ml; induction temperature was 80℃; the pH was 5.5; induction time was 30 min, and the yield of products was the same as free enzyme. After repeating the reaction 10 times, the conversion of naringin remained above 80%, showing great improvement of the catalytic efficiency and repeated utilization of the immobilized α-L-rhamnosidase.
Jin, Xiao-Liang,Liu, Sheng-Fu,Shi, Wen,Yang, Huan,Zhao, Rong-Xiang The Korean Institute of Power Electronics 2021 JOURNAL OF POWER ELECTRONICS Vol.21 No.2
Existing PWM methods suffer from a trade off between zero-sequence circulating current (ZSCC) and line-current ripple, which are two major concerns of two parallel interleaved two-level (2L) voltage-source converters (VSCs). Thus, this paper introduces a novel space vector-based PWM strategy to reduce both line-current ripple and ZSCC. Given the redundancy of the vector combination of two parallel interleaved converters, this paper proposes eight optimal vector sequences, which simultaneously optimizes the ZSCC and the line-current ripple. Then, a carrier-based scheme is applied to yield optimal vector sequences, which simplifies the implementation procedure. Furthermore, this paper quantitatively compares both the ZSCC and the line-current ripple of the proposed method to those of existing PWM schemes. This comparison confirms that the proposed method is superior to existing PWM schemes in terms of current ripple and ZSCC. Finally, experimental results further verify the theoretical analysis and the effectiveness of the proposed strategy.
Jin-Wei Yang,Cui Li,Xiao-Peng He,Hong Zhao,Li-Xin Gao,Wei Zhang,Xiao-Xin Shi,Yun Tang,Jia Li,Guo-Rong Chen 대한화학회 2010 Bulletin of the Korean Chemical Society Vol.31 No.11
The incorporation of microwave irradiation with the prevalent “click chemistry” is currently of considerable synthetic interest. We describe here the introduction of such laboratorial shortcut into carbohydrate-based drug discovery,resulting in the rapid formation of a series of triazole-linked salicylic β-D-O-glycosides with biological activities. All “clicked” products were achieved in excellent yields (≈ 90%) within only a quarter. In addition, based on the structural characteristics of the afforded glycomimetics, their inhibitory activities were evaluated toward protein tyrosine phosphatases 1B (PTP1B) and a panel of homologous protein tyrosine phosphatases (PTPs). Docking simulation was also conducted to plausibly propose binding modes of this glycosyl salicylate series with the enzymatic target.
Shi Yihan,Zhang Ming,Zhao Junshan,Zhang Liu,Cui Xumei,Zhu Xinhua,Jin Dandan,Gong Jiali,Yang Dingyu,Li Jitao 대한금속·재료학회 2022 ELECTRONIC MATERIALS LETTERS Vol.18 No.5
This work used a simple electrochemical reduction method to secondary construct the reduced nickel base (rNi Base) on nickel foam with a nano-core structure. The secondarily constructed base has a large specific surface area, which can increase the mass utilization of the active material. The rNi Base was used as a base for the reduction of nickel on Na+, K+, and NH+4, respectively. MnO2 was electrodeposited under three different cation pre-intercalation treatments, and the mechanism of the effect of different monovalent cations to guide the growth of MnO2 materials was investigated. Finally, rNi/MnO2&Na+ electrode with a special nano cauliflower structure was obtained. The special nanostructure of the electrode enhances its electrochemical performance, possessing 598 F g− 1 ultra-high specific capacitance at a current density of 1 A g− 1 and a high specific capacitance of 307.5 F g− 1 at a high current density of 20 A g− 1, and high specific capacitance maintenance rate of 92.7% after 500 cycles of charging and discharging at a current density of 2 A g− 1. In addition, the symmetrical supercapacitor assembled with this electrode has a very high specific capacitance (401.1 F g− 1 at a current density of 1 A g− 1) and energy density (80.22Wh kg− 1 at a power density of 599.99 W kg− 1).
Optimal Structure Design of Multi-functional Folding Drawing Board based on TRIZ Theory
Jiang Jin-gang,Xu Xiao-lei,Wang Zhao,Liu Yun-feng,Cui Shi-jia,Sun Jing-hao 보안공학연구지원센터 2015 International Journal of Hybrid Information Techno Vol.8 No.2
In drawing area, aiming at the problems of drawing breadth and angle cannot be adjusted individually and not convenient to carry, a kind of multi-functional folding drawing board is designed by us. The appearance of the multi-functional folding drawing board is kind of drawing board, some light materials like basswood and rigid plastics are used in main structure of the drawing board to make it light and convenient to carry. The main structure can be folded and it is suitable for A1 and A2 drawings. In the designing procedure, dip angle adjusted mechanism by worm wheel and gear, magnetic pull-in mechanism, leading rail, slide-way, drawer, tool library, paper bag and horn locks are applied based on modularity designing theory. Finite element analysis of key components of drawing board is analyzed.
Chen, Jin-Lian,Sun, Shi-Zhong,Miao, Cui-Ping,Wu, Kai,Chen, You-Wei,Xu, Li-Hua,Guan, Hui-Lin,Zhao, Li-Xing The Korean Society of Ginseng 2016 Journal of Ginseng Research Vol.40 No.4
Background: Biocontrol agents are regarded as promising and environmental friendly approaches as agrochemicals for phytodiseases that cause serious environmental and health problems. Trichoderma species have been widely used in suppression of soil-borne pathogens. In this study, an endophytic fungus, Trichoderma gamsii YIM PH30019, from healthy Panax notoginseng root was investigated for its biocontrol potential. Methods: In vitro detached healthy roots, and pot and field experiments were used to investigate the pathogenicity and biocontrol efficacy of T. gamsii YIM PH30019 to the host plant. The antagonistic mechanisms against test phytopathogens were analyzed using dual culture, scanning electron microscopy, and volatile organic compounds (VOCs). Tolerance to chemical fertilizers was also tested in a series of concentrations. Results: The results indicated that T. gamsii YIM PH30019 was nonpathogenic to the host, presented appreciable biocontrol efficacy, and could tolerate chemical fertilizer concentrations of up to 20%. T. gamsii YIM PH30019 displayed antagonistic activities against the pathogenic fungi of P. notoginseng via production of VOCs. On the basis of gas chromatography-mass spectrometry, VOCs were identified as dimethyl disulfide, dibenzofuran, methanethiol, ketones, etc., which are effective ingredients for antagonistic activity. T. gamsii YIM PH30019 was able to improve the seedlings' emergence and protect P. notoginseng plants from soil-borne disease in the continuous cropping field tests. Conclusion: The results suggest that the endophytic fungus T. gamsii YIM PH30019 may have a good potential as a biological control agent against notoginseng phytodiseases and can provide a clue to further illuminate the interactions between Trichoderma and phytopathogens.