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Formation of ZnO nanostructures grown on Si and SiO2 substrates.
Lee, Seungjin,Park, Eunkyung,Lee, Jongtack,Park, Taehee,Lee, Sang-Hwa,Kim, Jae-Yong,Yi, Whikun American Scientific Publishers 2013 Journal of Nanoscience and Nanotechnology Vol.13 No.9
<P>ZnO nanorods are grown on Si-based substrate by chemical bath deposition method in aqueous solution using zinc nitrate hexahydrate. Various substrates having different surface morphology are used to evaluate their effect on growing ZnO nanorods, such as flat Si(100) wafer, small and large textured-Si wafer, porous silicon, flat SiO2 wafer, small and large textured-SiO2 wafer. The length, diameter, geometry, and coverage density of ZnO nanorods are investigated by field-emission scanning electron microscopy and summarized. SiO2 is a preferred substrate for the growth of ZnO nanorods to Si if the surface morphology of substrate is same, and the textured surface has much higher coverage density (> 95%) than the flat surface. Each nanorod is vertically grown along the c-axis on the top of each pyramid face for textured substrate, and forms the 3D sea sponge-like ZnO structure. The characteristics of ZnO nanorods grown on various substrates are analyzed by grazing-angle X-ray diffraction (XRD) and photoluminescence (PL) measurements.</P>
Lee, Seungjin,Kim, Youngwoong,Wu, Ziang,Lee, Changyeon,Oh, Seung Jin,Luan, Nguyen Thanh,Lee, Junbok,Jeong, Dahyun,Zhang, Kai,Huang, Fei,Kim, Taek-Soo,Woo, Han Young,Kim, Bumjoon J. American Chemical Society 2019 ACS APPLIED MATERIALS & INTERFACES Vol.11 No.48
<P>Aqueous-processed all-polymer solar cells (aq-APSCs) are reported for the first time by developing a series of water/ethanol-soluble naphthalenediimide (NDI)-based polymer acceptors [P(NDIDEG-T), P(NDITEG-T), and P(NDITEG-T2)]. Polymer acceptors are designed by using the backbones of NDI-bithiophene and NDI-thiophene in combination with nonionic hydrophilic oligoethylene glycol (OEG) side chains that facilitate processability in water/ethanol mixtures. All three polymers exhibit sufficient solubility (20-50 mg mL<SUP>-1</SUP>) in the aqueous medium. The P(NDIDEG-T) polymer with shorter OEG side chains is the most crystalline with the highest electron mobility, enabling the fabrication of efficient aq-APSCs with the maximum power conversion efficiency (PCE) of 2.15%. Furthermore, these aq-APSCs are fabricated under ambient atmosphere by taking advantage of the eco-friendly aqueous process and, importantly, the devices exhibit outstanding air-stability without any encapsulation, as evident by maintaining more than 90% of the initial PCE in the air after 4 days. According to a double cantilever beam test, the interfacial adhesion properties between the active layer and electron/hole transporting layers were remarkably improved by incorporating the hydrophilic OEG-attached photoactive layer, which hinders the delamination of the constituent layers and prevents the increase of series resistance, ultimately leading to enhanced durability under ambient conditions. The combination of increased device stability and minimal environmental impact of these aq-APSCs demonstrates them to be worthy candidates for continued development of scalable polymer solar cells.</P> [FIG OMISSION]</BR>
Choi, Hyeongsu,Lee, Jeongsu,Shin, Seokyoon,Lee, Juhyun,Lee, Seungjin,Park, Hyunwoo,Kwon, Sejin,Lee, Namgue,Bang, Minwook,Lee, Seung-Beck,Jeon, Hyeongtag IOP Pub 2018 Nanotechnology Vol.29 No.21
<P>Representative tin sulfide compounds, tin monosulfide (SnS) and tin disulfide (SnS<SUB>2</SUB>) are strong candidates for future nanoelectronic devices, based on non-toxicity, low cost, unique structures and optoelectronic properties. However, it is insufficient for synthesizing of tin sulfide thin films using vapor phase deposition method which is capable of fabricating reproducible device and securing high quality films, and their device characteristics. In this study, we obtained highly crystalline SnS thin films by atomic layer deposition and obtained highly crystalline SnS<SUB>2</SUB> thin films by phase transition of the SnS thin films. The SnS thin film was transformed into SnS<SUB>2</SUB> thin film by annealing at 450 °C for 1 h in H<SUB>2</SUB>S atmosphere. This phase transition was confirmed by x-ray diffractometer and x-ray photoelectron spectroscopy, and we studied the cause of the phase transition. We then compared the film characteristics of these two tin sulfide thin films and their switching device characteristics. SnS and SnS<SUB>2</SUB> thin films had optical bandgaps of 1.35 and 2.70 eV, and absorption coefficients of about 10<SUP>5</SUP> and 10<SUP>4</SUP> cm<SUP>−1</SUP> in the visible region, respectively. In addition, SnS and SnS<SUB>2</SUB> thin films exhibited p-type and n-type semiconductor characteristics. In the images of high resolution-transmission electron microscopy, SnS and SnS<SUB>2</SUB> directly showed a highly crystalline orthorhombic and hexagonal layered structure. The field effect transistors of SnS and SnS<SUB>2</SUB> thin films exhibited on–off drain current ratios of 8.8 and 2.1 × 10<SUP>3</SUP> and mobilities of 0.21 and 0.014 cm<SUP>2</SUP> V<SUP>−1</SUP> s<SUP>−1</SUP>, respectively. This difference in switching device characteristics mainly depends on the carrier concentration because it contributes to off-state conductance and mobility. The major carrier concentrations of the SnS and SnS<SUB>2</SUB> thin films were 6.0?×?10<SUP>16</SUP> and 8.7?×?10<SUP>13</SUP> cm<SUP>−3</SUP>, respectively, in this experiment.</P>
Soil Contamination Survey of Waste Landfill in the Past: ‘D’ District in Gyeonggi-do Province
( Seungjin Oh ),( Minah Oh ),( Jongbin Kim ),( Hyunho Jun ),( Hyungwook Kim ),( Youngjin Lee ),( Yoonsoo Park ),( Jai-young Lee ) 한국폐기물자원순환학회(구 한국폐기물학회) 2016 한국폐기물자원순환학회 춘계학술발표논문집 Vol.2016 No.-
Korea has been continuously extended to surrounding metropolitian area including Seoul city, because of the population growth and densitification of urban space. Several cases that the site of landfill area in the past has replaced and developed the housing site. There is serious contamination in soil and water system around landfill area since waste dumping had been prolonged unsanitarity. The ‘D’ district has been used waste landfill areas in the past. In addition, new town construction for residence is planned for the future. Therefore, the survey was carried out to determine the probability of soil contamination. Soil contamination survey was performed sampling and analysis according to Korea standard method for soil. Analysis parameters were selected as TPH(Total Petroleum Hydrocarbon), Zinc, Fluorine, Copper, Mercury, Arsenic on the basis of result from proceeded overall survey of the site. As a result fluorine contamination has emerged in most investigated points, and some points has TPH and arsenic contamination exceeded the standard measures. Mercury and copper were not detected. Almost of regional classification for land use are arranged by ‘2’ or ‘3’ areas. However, this district would be expected to change the regional classification as ‘1’ area which is for housing site. Therefore, the remediation and detailed investigation aimed at this district should be conducted.