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Sankar Ganesh, R.,Sharma, S.K.,Sankar, S.,Divyapriya, B.,Durgadevi, E.,Raji, P.,Ponnusamy, S.,Muthamizhchelvan, C.,Hayakawa, Y.,Kim, D.Y. ELSEVIER 2017 Current Applied Physics Vol.17 No.3
<P>Nanocrystalline BiFeO3 (BFO) powder was synthesized by sol-gel method and subsequent annealed at 100-500 degrees C. The microstructural analysis of BFO nanopowder confirmed the perovskite like structure of spherical nanoparticles annealed at 500 degrees C. The Raman spectrum of BFO nanoparticles showed the rhombohedrally structure with the space group of R3c. The XPS spectrum of BFO nanopowder showed the peaks of Bi, Fe, and O at the binding energy of 158.8, 711.75 and 529.2 eV, respectively. The piezoelectric properties of BFO nanoparticles were evaluated by making the sandwiched structure of graphene/BiFeO3-PDMS/graphene. The fabricated piezoelectric device demonstrated an output voltage of 0.4 V by applying the normal pressure from human finger on the device. (C) 2016 Elsevier B.V. All rights reserved.</P>
R. Sankar Ganesh,Sanjeev K. Sharma,S. Sankar,B. Divyapriya,E. Durgadevi,P. Raji,S. Ponnusamy,C. Muthamizhchelvan,Y. Hayakawa,김득영 한국물리학회 2017 Current Applied Physics Vol.17 No.3
Nanocrystalline BiFeO3 (BFO) powder was synthesized by sol-gel method and subsequent annealed at 100e500 C. The microstructural analysis of BFO nanopowder confirmed the perovskite like structure of spherical nanoparticles annealed at 500 C. The Raman spectrum of BFO nanoparticles showed the rhombohedrally structure with the space group of R3c. The XPS spectrum of BFO nanopowder showed the peaks of Bi, Fe, and O at the binding energy of 158.8, 711.75 and 529.2 eV, respectively. The piezoelectric properties of BFO nanoparticles were evaluated by making the sandwiched structure of graphene/ BiFeO3-PDMS/graphene. The fabricated piezoelectric device demonstrated an output voltage of 0.4 V by applying the normal pressure from human finger on the device.
Sankar Ganesh, R.,Sharma, Sanjeev K.,Abinnas, N.,Durgadevi, E.,Raji, P.,Ponnusamy, S.,Muthamizhchelvan, C.,Hayakawa, Y.,Kim, Deuk Young Elsevier Sequoia S.A 2017 Materials chemistry and physics Vol.192 No.-
<P><B>Abstract</B></P> <P>Nanostructured bismuth titanate (Bi<SUB>4</SUB>Ti<SUB>3</SUB>O<SUB>12</SUB>) or BTO powders were synthesized by the combustion method. The crystalline phase of BTO nanopowders was evaluated from X-ray diffraction (XRD) and further confirmed by selected area electron diffraction (SAED) pattern. The SEM and TEM micrographic images clearly showed the nanosheets like morphology of BTO nanopowder. The EDS spectrum of BTO nanopowder showed the elemental peaks of O, Bi and Ti at 0.53 keV, 2.41 keV and 4.49 keV, respectively. FTIR band peaks were observed at 815 and 595 cm<SUP>−1</SUP> corresponding to the stretching vibrations of BiO and TiO. The red shift in optical absorption of BTO was observed and the bandgap decreased from 3.18 to 3.08 eV as the calcined temperature increased from 600 to 800 °C. The sandwich structure, called the nanogenerator, Graphene/BTO-PDMS/Graphene (G/BTO/G), was fabricated on graphene coated polymethyl methacrylate (PMMA) substrates, which produced a peak voltage (10 mV) by applying the pressure from human's finger. The switching mechanism of BTO nanosheets was observed to be dependent on the polarity and intrinsic dipole formation.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Bi<SUB>4</SUB>Ti<SUB>3</SUB>O<SUB>12</SUB> (BTO) nanosheets synthesized from a simple combustion method. </LI> <LI> SEM & TEM images confirmed the nanosheets structure with a hexagonal shape. </LI> <LI> XRD and SAED pattern of BTO nanosheets confirmed the orthorhombic crystal structure. </LI> <LI> Flexible G/BTO/G nanogenerator fabricated by sol-gel method. </LI> <LI> Peak voltage was observed to be 10 mV by applying pressure from human's finger. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>
Photocatalytic properties of Mn-doped NiO spherical nanoparticles synthesized from sol-gel method
Sankar, S.,Sharma, Sanjeev K.,An, Namhyun,Lee, Hwauk,Kim, Deuk Young,Im, Young Bin,Cho, Yung Duk,Ganesh, R. Sankar,Ponnusamy, S.,Raji, P.,Purohit, L.P. Elsevier 2016 OPTIK -STUTTGART- Vol.127 No.22
<P><B>Abstract</B></P> <P>Mn-doped NiO (NiO:Mn) nanopowders were synthesized from an inexpensive sol-gel method. The XRD peak profile analysis of NiO:Mn nanopowders confirmed the cubic structure. The spherical nanoparticles of NiO:Mn were evaluated from the SEM and TEM analysis and the grain size decreased as the Mn concentration increased. The average crystallite size decreased from 35.44nm to 30.5nm and the bandgap increased from 3.79eV to 3.95eV as the Mn concentration increased from 0wt.% to 4wt.%. The photocatalytic properties of NiO:Mn nanopowders were measured for the lowest and highest Mn dopant concentrations (Mn: 0 & 4wt.%) by using the methylene blue dye under UV illumination. The NiO:Mn (Mn: 4wt.%) nanoparticles showed the highest photocatalytic activity due to the highest activation sites. Therefore, it is revealed that the Mn: 4wt.% nanoparticles are observed to be more suitable for the photocatalytic activity of methylene blue dye degradation.</P>
Ganesh, R. Sankar,Sharma, Sanjeev K.,Durgadevi, E.,Navaneethan, M.,Ponnusamy, S.,Muthamizhchelvan, C.,Hayakawa, Y.,Kim, Deuk Young Elsevier 2017 Materials research bulletin Vol.94 No.-
<P><B>Abstract</B></P> <P>Size and structure tunability of polyvinyl pyrolidone (PVP) capped cadmium sulfide (PVP-capped CdS) flowers were synthesized by controlling the reaction time. XRD pattern indicated a phase transition from the cubic zinc blend to the hexagonal phase of CdS powder as the reaction time increased. As per the microstructure analysis with respect to the reaction time, the spherical nanoparticles were transformed in to the flower like morphology consisting of sword like nanorods and confirmed by the bright field images of TEM, while, HR-TEM images showed the uniform lattice spacing. UV-spectra exhibited a red shift due to the excitations of CdS nanoparticles. The near band edge (NBE) peak of PVP-capped CdS was completely diminished which indicated to sulphur vacancies on the surface of flowers. The photocatalytic activity of PVP-capped CdS flowers was detected the fast degradation of Rhodamine B (RhB) dye (95% for 120min) by irradiation of visible light.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Synthesis of un-capped and PVP-capped CdS microstructures by Hydrothermal. </LI> <LI> Growth of both the flower and dendrite microstructures controlled by the growth time. </LI> <LI> Phase transition of CdS from cubic zinc blend to hexagonal by the growth time. </LI> <LI> CdS flowers enhanced the photocatalytic performance of RhB under visible light. </LI> <LI> PVP-capped CdS showed the highest degradation of 95% of RhB within 120min. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>
V. Siva Shankar,R. Siddheswaran,R. Sankar,R. Jayavel,P. Murugakoothan 한국물리학회 2009 Current Applied Physics Vol.9 No.5
Sodium bitartrate monohydrate (SBTMH) a new organometallic nonlinear optical material, with molecular formula, [C4H5NaO6 . H2O] has been synthesized at ambient temperature. Spectral, thermal and optical techniques have been employed to characterize the new material. Bulk single crystals of size 13 × 4 ×4㎣ of SBTMH have been grown by slow cooling method. The unit cell parameters of the grown crystal were determined by single crystal XRD. Functional groups present in the sample were identified by FTIR spectral analysis. Thermal stability of SBTMH was determined using TGA/DTA. The grown crystals exhibit nonlinear properties. The dielectric response of the crystal with varying frequencies was studied. The optical transparency range and the lower cut-off wavelength of the material were identified from the UV–vis–NIR absorption spectrum. Sodium bitartrate monohydrate (SBTMH) a new organometallic nonlinear optical material, with molecular formula, [C4H5NaO6 . H2O] has been synthesized at ambient temperature. Spectral, thermal and optical techniques have been employed to characterize the new material. Bulk single crystals of size 13 × 4 ×4㎣ of SBTMH have been grown by slow cooling method. The unit cell parameters of the grown crystal were determined by single crystal XRD. Functional groups present in the sample were identified by FTIR spectral analysis. Thermal stability of SBTMH was determined using TGA/DTA. The grown crystals exhibit nonlinear properties. The dielectric response of the crystal with varying frequencies was studied. The optical transparency range and the lower cut-off wavelength of the material were identified from the UV–vis–NIR absorption spectrum.
R. Anandan,K.H. Sabeena Farvin,S. Hari Senthil Kumar,K.S. Shiny,Suseela Mathew,T.V. Sankar,P.G. Viswanathan Nair 한국식품영양과학회 2006 Journal of medicinal food Vol.9 No.4
We studied the cardioprotective effect of squalene on isoprenaline-induced myocardial infarction in male al-bino rats with respect to changes in the levels of lipid components in plasma and heart tissue. Prior administration of 2% squa-lene in feed for 45 days significantly reduced the isoprenaline-induced elevation in the levels of cholesterol, triglycerides, andfree fatty acids in plasma and heart tissue of rats following myocardial infarction. It exerted an anitlipidemic effect by re-ducing the level of low-density lipoprotein cholesterol with a parallel rise in the level of high-density lipoprotein cholesterolin plasma of experimental rats. A tendency to prevent the isoprenaline-induced depletion of phospholipids in the myocardiumof experimental rats was also observed. In the present study, the pretreatment with squalene significantly counteracted the iso-prenaline-induced lipid peroxidation and maintained the rats at near normal status. The results of the present study indicatethat the overall cardioprotective effect of squalene is probably related to an inhibition of lipid accumulation by its hypolipi-demic properties and/or its antioxidant properties.
Implementation of Adaptive Fuzzy Logic Control Based MPPT for Photovoltaic System
A. Bharathi Sankar,R. Seyezhai 보안공학연구지원센터 2016 International Journal of u- and e- Service, Scienc Vol.9 No.10
Recently, photovoltaic (PV) system has emerged as a promising renewable energy source to meet out the increasing energy demand. This PV cell has to optimally operate at a particular point to deliver maximum power called maximum power point (MPP). This paper presents an adaptive fuzzy logic control (AFLC) for the maximum power point tracking (MPPT) algorithm for photovoltaic power generation system. The main idea of the proposed algorithm is the application of fuzzy controller with an adaptive gain as a maximum power point tracker. It adjusts the duty cycle of the boost converter as well as controller’s gain. The performance of AFLC is compared with the conventional fuzzy controller for varying irradiance. Simulation studies of AFLC are carried out in MATLAB. The experimental results show the effectiveness and feasibility of the proposed controller and the results were verified. The results reveal that the adaptive FLC can quickly track change of MPP in different light intensity and deliver more power compared to the classical fuzzy logic controller.
Current Status and Development of Submerged Friction Stir Welding: A Review
Rathinasuriyan Chandran,E. Pavithra,R. Sankar,V. S. Senthil Kumar 한국정밀공학회 2021 International Journal of Precision Engineering and Vol.8 No.2
Submerged Friction Stir Welding is a modification of the friction stir welding process in which the water as the coolant is employed to standardize the temperature. It is considered as a green and environmentally friendly welding technology because of low energy consumption, no gas emission, and no need for consumable material. It is applied to structural purposes like oil platforms and pipelines, or in industrial and laboratories for enhancing the weld strength. This review paper is classified into three categories, the first one studies the preceding experimental investigations, the second one is modelling/optimization, and the third one is current status and development of submerged friction stir welding. The experimental results of the previous research findings in submerged friction stir welded sample with performance characteristics, tensile properties, microhardness, fracture analysis and corrosion resistance, macro/microstructure analysis on the various materials are discussed. This review articles concludes with recommendations for future research exertion