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A sensitive fluorescent probe for the polar solvation dynamics at protein-surfactant interfaces
Singh, P.,Choudhury, S.,Singha, S.,Jun, Y.,Chakraborty, S.,Sengupta, J.,Das, R.,Ahn, K. H.,Pal, S. Royal Society of Chemistry 2017 Physical chemistry chemical physics Vol.19 No.19
<P>Relaxation dynamics at the surface of biologically important macromolecules is important taking into account their functionality in molecular recognition. Over the years it has been shown that the solvation dynamics of a fluorescent probe at biomolecular surfaces and interfaces account for the relaxation dynamics of polar residues and associated water molecules. However, the sensitivity of the dynamics depends largely on the localization and exposure of the probe. For noncovalent fluorescent probes, localization at the region of interest in addition to surface exposure is an added challenge compared to the covalently attached probes at the biological interfaces. Here we have used a synthesized donor-acceptor type dipolar fluorophore, 6-acetyl-(2-((4-hydroxycyclohexyl)(methyl) amino) naphthalene) (ACYMAN), for the investigation of the solvation dynamics of a model protein-surfactant interface. A significant structural rearrangement of a model histone protein (H1) upon interaction with anionic surfactant sodium dodecyl sulphate (SDS) as revealed from the circular dichroism (CD) studies is nicely corroborated in the solvation dynamics of the probe at the interface. The polarization gated fluorescence anisotropy of the probe compared to that at the SDS micellar surface clearly reveals the localization of the probe at the protein-surfactant interface. We have also compared the sensitivity of ACYMAN with other solvation probes including coumarin 500 (C500) and 4-(dicyanomethylene)-2-methyl-6-(p-dimethylamino-styryl)-4H-pyran (DCM). In comparison to ACYMAN, both C500 and DCM fail to probe the interfacial solvation dynamics of a model protein-surfactant interface. While C500 is found to be delocalized from the protein-surfactant interface, DCM becomes destabilized upon the formation of the interface (protein-surfactant complex). The timescales obtained from this novel probe have also been compared with other femtosecond resolved studies and molecular dynamics simulations.</P>
Neutral beam injector system for Steady State Tokamak -1
S. K. Mattoo,A.K. Chakraborty,B. Prajapati,BVSNNP Sridhar,C. Rotti,Ch. Chakrapani,G. Patel,M. Bandyopadhyay,M.J. Singh,M.R. Jana,N.P. Singh,P. Bharati,P.J. Patel,P.K. Jayakumar,R. Onali,S. Ramababu,S. 한국물리학회 2006 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.49 No.III
This paper discusses the experimental results obtained from the various components developed for a 1.7 MW neutral beam injector (NBI). Several technologies related to fabrication of back plate, extractor grids, high-current filament feedthru’s, heat-transfer elements, ceramic insulators, cryopumps, rectangular vessels and power supplies have been developed in collaboration with the Indian industry. Control experiments on the prototype plasma box are described.
IMPROVED THEORETICAL MODELING OF A CYCLONE SEPARATOR AS A DIESEL SOOT PARTICULATE EMISSION ARRESTER
P. K. BOSE,K. ROY,N. MUKHOPADHYA,R. K. CHAKRABORTY 한국자동차공학회 2010 International journal of automotive technology Vol.11 No.1
Particulate matter is considered to be the most harmful pollutant emitted into air from diesel engine exhaust, and its reduction is one of the most challenging problems in modern society. Several after-treatment retrofit programs have been proposed to control such emission, but to date, they suffer from high engineering complexity, high cost, thermal cracking,and increased back pressure, which in turn deteriorates diesel engine combustion performance. This paper proposes a solution for controlling diesel soot particulate emissions by an improved theoretical model for calculating the overall collection efficiency of a cyclone. The model considers the combined effect of collection efficiencies of both outer and inner vortices by introducing a particle distribution function to account for the non-uniform distribution of soot particles across the turbulent vortex section and by including the Cunningham correction factor for molecular slip of the particles. The cut size diameter model has also been modified and proposed by introducing the Cunningham correction factor for molecular slip of the separated soot particles under investigation. The results show good agreements with the existing theoretical and experimental studies of cyclones and diesel particulate filter flow characteristics of other applications.
Iron ore grindability improvement by microwave pre-treatment
P. Kumar,B.K. Sahoo,S. De,D.D. Kar,S. Chakraborty,B.C. Meikap 한국공업화학회 2010 Journal of Industrial and Engineering Chemistry Vol.16 No.5
The influence ofmicrowave pre-treatment on grindability of iron ore (Orissa, India) was investigated by grindability tests. SEM analysis characterized the micro-fractures in microwave treated sample. This may be due to the thermal stress cracking resulted from microwave energy pre-treatment. XRD analysis showed the crystalline content of the sample. It was found that the microwave treated iron ore has peak more than that of untreated ore, i.e. the crystallinity increased with the microwave exposure time. The calculation of HGGI indicated increase in the ease of grinding or decrease in grindability index of the microwave treated ore. Grindability test showed that the microwave treated iron ore grinds much more rapidly initially than the untreated ore. The results showed that the breakage function of both microwave untreated and treated iron ore is dependent of the particle size. The grindability increased significantly as a result of microwave pre-treatment with the specific rate of breakage (Si) increasing by an average of 50%. It was concluded that microwave assisted grinding produced good results particularly for grinding characteristics. 2010 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
ON SOME RECURSION RELATIONS FOR HORN'S HYPERGEOMETRIC FUNCTIONS OF THREE VARIABLES
P. Agarwal,A. SHEHATA,S. I. MOUSTAFA,K. CHAKRABORTY 장전수학회 2021 Proceedings of the Jangjeon mathematical society Vol.24 No.2
The principal aim of this paper to study the recursion formulas for the Horns hypergeometric functions of three variables. Earlier in [Shehata, A.; and Moustafa, S.I. Some new results for Horn's hypergeometric functions Γ1 and Γ2. Journal of Mathematics and Computer Science, (2021), 23 (1), 26{35.], and Pathan et al. [Pathan, M.A.; Shehata, A.; and Moustafa, S.I. Certain new formulas for the Horns hypergeometric functions. Acta Uni- versitatis Apulensis, (2020)] have studied the new results for Horns hypergeometric functions. Motivated by the above works here we will derive some contiguous relation for the families of Horn hypergeometric functions GA, GB, GC, GD and G C of three variables. After that we will establish the differential reclusion relations and differential operators for GA, GB, GC, GD and G* C of three variables, respectively.
Breast cancer metastasis: Putative therapeutic role of vascular cell adhesion molecule-1
Sharma, R.,Sharma, R.,Khaket, T. P.,Dutta, C.,Chakraborty, B.,Mukherjee, T. K. Springer Science + Business Media 2017 CELLULAR ONCOLOGY Vol.40 No.3
<P>Conclusions This study focuses on recent progress on the role of VCAM-1, an important glycoprotein belonging to the immunoglobulin (Ig) superfamily of cell surface adhesion molecules in breast cancer angiogenesis, survival and metastasis. Targeting VCAM-1, expressed on the surface of breast cancer cells, and/or its specific ligand VLA-4/alpha 4 beta 1 integrin, expressed on cells at the site of metastasis, may be a useful strategy to reduce breast cancer cell invasion and metastasis. Various approaches to therapeutically target VCAM-1 and VLA-4 are also discussed.</P>
S. Maitra,P.K. Chakraborty,R. Mitra,T.K. Nath 한국물리학회 2020 Current Applied Physics Vol.20 No.12
We report here the cost-effective synthesis of Magnesium Cobalt Oxide (MgCoO2) sample by the sol-gel synthesis route labeled as MCO - 3. In presence of aqueous 1 M Lithium Sulphate (Li2SO4) electrolyte, we obtained a capacitance of 56 F/g, an energy density of 38 Wh/kg and a capacitance retention of 92.53 % (at 5 A/g) after undergoing 1000 charge-discharge cycles. For the aqueous 1 M Sodium Perchlorate (NaClO4) electrolyte system, we found the capacitance, energy density and capacitance retention of 47 F/g, 31 Wh/kg and 91.41% (at 3.5 A/g for 1000 charge-discharge cycles), respectively. These results establish MgCoO2 as suitable electrode material in aqueous lithium-ion and sodium-ion supercapacitor devices. Further, MCO - 3 in the presence of aqueous 1 M Potassium Hydroxide (KOH) electrolyte showed an overpotential of 400 mV and a Tafel slope of 174 mV/dec, making it a suitable candidate for alkaline Hydrogen Evolution Reaction (HER) electrocatalyst.
Bandyopadhyay, U.K.,Sahu, P.K.,Raina, S.K.,Santhakumar, M.V.,Chakraborty, N.,Sen, S.K. Korean Society of Sericultural Science 2000 International Journal of Industrial Entomology Vol.1 No.1
A study was conducted to examine the relationship between abiotic factors and the population of white-fly (Dialeuropora decempuncta) in mulberry field. The study reveals that relationship between abiotic factors and the whitefly population is very much existent like other pests in other agricultural crops. Duration and time of distinct occurrence of whitefly in mulberry is influenced by the abiotic conditions of field. Abiotic parameters of previous month are more important in influencing the intensity of the pest than the current abiotic factors. Not all the abiotic factors are equally important but factors like minimum temperature, fluctuation in temperature during the days minimum relative humidity, fluctuation in relative humidity and rainfall are the major important lactors in influencing the intensity of the pest under consideration.