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Control of molecular weight distribution of polyethylene in gas-phase fluidized bed reactors
Mohammad Al-haj Ali,Emadadeen Ali AbdelHamid Ajbar,Khalid Alhumaizi 한국화학공학회 2010 Korean Journal of Chemical Engineering Vol.27 No.1
This paper presents a feasibility study of the broadening of polyethylene molecular weight distribution produced using a multisite Ziegler-Natta catalyst in a fluidized-bed reactor. A nonlinear model predictive control algorithm,applied to a validated model of the reactor, is used for the on-line control of the entire molecular weight distribution of the produced polymer. Control of a target chain-length distribution is achieved by selecting a collection of points in the distribution and using them as set points for the control algorithm. An on-line Kalman filter is used to incorporate infrequent and delayed off-line molecular weight measurements. Through simulation the control algorithm is evaluated, under tracking conditions as well as plant-model mismatch. The results demonstrate that the control algorithm can regulate the entire molecular weight distribution with minimum steady state error. However, the efficiency of this approach is highly dependent on the dynamics of hydrogen inside the reactor.
Integrated fire dynamic and thermomechanical modeling of a bridge under fire
Choi, Joonho,Haj-Ali, Rami,Kim, Hee Sun Techno-Press 2012 Structural Engineering and Mechanics, An Int'l Jou Vol.42 No.6
This paper proposes a nonlinear computational modeling approach for the behaviors of structural systems subjected to fire. The proposed modeling approach consists of fire dynamics analysis, nonlinear transient-heat transfer analysis for predicting thermal distributions, and thermomechanical analysis for structural behaviors. For concretes, transient heat formulations are written considering temperature dependent heat conduction and specific heat capacity and included within the thermomechanical analyses. Also, temperature dependent stress-strain behaviors including compression hardening and tension softening effects are implemented within the analyses. The proposed modeling technique for transient heat and thermomechanical analyses is first validated with experimental data of reinforced concrete (RC) beams subjected to high temperatures, and then applied to a bridge model. The bridge model is generated to simulate the fire incident occurred by a gas truck on April 29, 2007 in Oakland California, USA. From the simulation, not only temperature distributions and deformations of the bridge can be found, but critical locations and time frame where collapse occurs can be predicted. The analytical results from the simulation are qualitatively compared with the real incident and show good agreements.
Integrated fire dynamic and thermomechanical modeling of a bridge under fire
Joonho Choi,Rami Haj-Ali,김희선 국제구조공학회 2012 Structural Engineering and Mechanics, An Int'l Jou Vol.42 No.6
This paper proposes a nonlinear computational modeling approach for the behaviors of structural systems subjected to fire. The proposed modeling approach consists of fire dynamics analysis, nonlinear transient-heat transfer analysis for predicting thermal distributions, and thermomechanical analysis for structural behaviors. For concretes, transient heat formulations are written considering temperature dependent heat conduction and specific heat capacity and included within the thermomechanical analyses. Also, temperature dependent stress-strain behaviors including compression hardening and tension softening effects are implemented within the analyses. The proposed modeling technique for transient heat and thermomechanical analyses is first validated with experimental data of reinforced concrete (RC) beams subjected to high temperatures, and then applied to a bridge model. The bridge model is generated to simulate the fire incident occurred by a gas truck on April 29, 2007 in Oakland California, USA. From the simulation, not only temperature distributions and deformations of the bridge can be found, but critical locations and time frame where collapse occurs can be predicted. The analytical results from the simulation are qualitatively compared with the real incident and show good agreements.
Joonho Choi,Rami Haj-ali,김희선 국제구조공학회 2010 Steel and Composite Structures, An International J Vol.10 No.2
The objective of this study is to formulate a general 3D material-structural analysis framework for the thermomechanical behavior of steel-concrete structures in a fire environment. The proposed analysis framework consists of three sequential modeling parts: fire dynamics simulation, heat transfer analysis, and a thermomechanical stress analysis of the structure. The first modeling part consists of applying the NIST (National Institute of Standards and Technology) Fire Dynamics Simulator (FDS) where coupled CFD (Computational Fluid Dynamics) with thermodynamics are combined to realistically model the fire progression within the steel-concrete structure. The goal is to generate the spatial-temporal (ST) solution variables (temperature, heat flux) on the surfaces of the structure. The FDS-ST solutions are generated in a discrete form. Continuous FDS-ST approximations are then developed to represent the temperature or heat-flux at any given time or point within the structure. An extensive numerical study is carried out to examine the best ST approximation functions that strike a balance between accuracy and simplicity. The second modeling part consists of a finite-element (FE) transient heat analysis of the structure using the continuous FDS-ST surface variables as prescribed thermal boundary conditions. The third modeling part is a thermomechanical FE structural analysis using both nonlinear material and geometry. The temperature history from the second modeling part is used at all nodal points. The ABAQUS (2003) FE code is used with external user subroutines for the second and third simulation parts in order to describe the specific heat temperature nonlinear dependency that drastically affects the transient thermal solution especially for concrete materials. User subroutines are also developed to apply the continuous FDS-ST surface nodal boundary conditions in the transient heat FE analysis. The proposed modeling framework is applied to predict the temperature and deflection of the well-documented third Cardington fire test.
Seyed Mahmoud Mousavi,Mohammad Ali Haj Asgarkhani,Ehsan Saljoughi 한국화학공학회 2013 Korean Journal of Chemical Engineering Vol.30 No.9
Cellulose acetate butyrate/TiO2 hybrid membranes were prepared via phase inversion by dispersing the TiO2 nanoparticles in casting solutions. The influence of TiO2 nanoparticles on the morphology and performance of membranes was investigated. The scanning electron microscope images and experiments of membrane performance showed that the membrane thickness and pure water flux were first increased by adding the TiO2 nanoparticles to the casting solution up to 4 wt% and then decreased with the addition of further nanoparticles to it. The obtained results indicated that the addition of TiO2 in the casting solution enhanced the rejection and permeate flux in filtration of bovine serum albumin solution. Furthermore, increasing the TiO2 nanoparticle concentration in the casting solution increased the flux recovery and consequently decreased the fouling of membrane.
Cañete Oscar M.,El-Haj-Ali Mouhamad,Fereczkowski Michal 대한청각학회 2024 Journal of Audiology & Otology Vol.28 No.2
Background and Objectives: Otoacoustic emissions (OAEs) are low-intensity sounds generated by the cochlea and associated with the function of the outer hair cells. Since OAE measurements do not require active participation of a listener, OAEs are considered an objective measure of cochlear function. While distortion-product OAEs (DPOAEs) are commonly used in clinical practice, limited information is available on the performance of various clinical devices. This study compared two commercial clinical devices, Titan and Eclipse from Interacoustics, and collected normative data for DPOAEs in people with normal hearing. The data collection and analysis were focused on signal and noise amplitudes as well as signal-to-noise ratios (SNRs).Subjects and Methods: Sixty-three participants with normal hearing (age 23.2±2.0 years) were included in the study. DPOAEs were measured at 31 frequencies ranging from 500 to 10,000 Hz.Results: DPOAE amplitude differed across frequencies. Additionally, a high number of unreliable responses were observed at the edge frequencies (<828 Hz and >6,072 Hz). There were no significant differences between the two devices in terms of DPOAE amplitudes, but the recorded-noise levels (amplitude) differed significantly. SNRs of the recorded OAEs were frequency dependent (higher frequencies showed larger SNRs), and significant differences in terms of SNR were found between the two devices.Conclusions: Despite the above-mentioned differences, the OAEs recorded with both devices met the pass criteria for the SNR (≥6 dB) consistently across frequencies, and thus the differences do not compromise the test outcomes. The frequency dependence of the OAE amplitudes and the corresponding SNRs may be relevant for clinical practice.