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PEMFC 용 Pt 담지 촉매의 Pt 담지비에 따른 성능변화
조용훈(Y. H. Cho),조윤환(Y. H. Cho),박현서(H. S. Park),성영은(Y. E. Sung) 한국정밀공학회 2006 한국정밀공학회 학술발표대회 논문집 Vol.2006 No.5월
This study focuses on a determination of amount of Pt in the Pt/C for catalysts of polymer electrolyte membrane fuel cells (PEMFC). PEMFC offer low weight and high power density and being considered for automotive and stationary power applications. The PEMFC behavior is quite complex is influenced by several factors, including catalysts and structure of electrode and membrane type. Catalyst of electrode is important factor for PEMFC. One of the obstacles preventing polymer electrolyte membrane fuel cells from commercialization is the high cost of noble metals to be used as catalyst, such as platinum. To effectively use these metals, they have to be will dispersed to small particles on conductive carbon supports. The optimal amount of Pt in Pt/C was investigated by using polarization curves in single cell with H₂/O₂ operation.
곽호상,이규석,조현익,이정희,조용훈,Kwack, H.S.,Lee, K.S.,Cho, H.E.,Lee, J.H.,Cho, Y.H. 한국진공학회 2008 Applied Science and Convergence Technology Vol.17 No.4
금속 유기화학 증착기 (metal-organic chemical vapor deposition)를 이용하여 사파이어 기판 위에 $Al_{0.3}Ga_{0.7}N$/GaN 및 $Al_{0.3}Ga_{0.7}N/GaN/Al_{0.15}Ga_{0.85}N/GaN$ 이종접합 구조들을 성장하고, 이들 시료의 전자와 정공들 간의 구속 효과를 조사하기 위하여 광학적, 구조적 특성을 비교하였다. 저온 (10 K) photoluminescence 실험으로부터 $Al_{0.3}Ga_{0.7}N$/GaN 단일 이종접합 구조의 경우 3.445 eV에서 단일의 이차원 전자가스 (two-dimensional electron gas; 2DEG) 관련된 발광을 관찰한 반면, $Al_{0.3}Ga_{0.7}N/GaN/Al_{0.15}Ga_{0.85}N/GaN$ 다중 이종접합 구조의 경우 3.445 eV에서 뿐만 아니라, 3.42 eV에서 추가적인 2DEG 관련된 발광을 관찰 할 수 있었다. 이 두 개의 2DEG 관련 신호들의 근원을 조사하기 위하여 $Al_{0.3}Ga_{0.7}N/GaN/Al_{0.15}Ga_{0.85}N/GaN$ 다중 이종접합구조에서의 에너지 밴드 구조를 이론적으로 계산하여 실험과 비교한 결과, 하나의 2DEG에 의한 서로 다른 버금띠로 부터가 아닌 다중 구조에 형성된 두 개의 2DEG로부터의 신호로 해석되었다. We have investigated optical and structural properties of $Al_{0.3}Ga_{0.7}N$/GaN and $Al_{0.3}Ga_{0.7}N/GaN/Al_{0.15}Ga_{0.85}N/GaN$ heterostructures (HSs) grown by metal-organic chemical vapor deposition, by means of Hall measurement, high-resolution X-ray diffraction, and temperature- and excitation power-dependent photoluminescence (PL) spectroscopy. A strong GaN band edge emission and its longitudinal optical phonon replicas were observed for all the samples. At 10 K, a 2DEG-related PL peak located at ${\sim}\;3.445\;eV$ was observed for $Al_{0.3}Ga_{0.7}N$/GaN HS, while two 2DEG peaks at ${\sim}\;3.42$ and ${\sim}\;3.445\;eV$ were observed for $Al_{0.3}Ga_{0.7}N/GaN/Al_{0.15}Ga_{0.85}N/GaN$ HS due to the additional $Al_{0.15}Ga_{0.85}N$ layers. Moreover, the emission intensity of the 2DEG peak was higher in $Al_{0.3}Ga_{0.7}N/GaN/Al_{0.15}Ga_{0.85}N/GaN$ HS than in $Al_{0.3}Ga_{0.7}N$/GaN HS probably due to an effective confinement of the photo-excited holes by the additional $Al_{0.15}Ga_{0.85}N$ layers. The 2DEG-related emission intensity decreased with increasing temperature and disappeared at temperatures above 150 K. To investigate the origin of the new 2DEG peaks, the energy-band structure for multiple AlGaN/GaN HSs were simulated and compared with the experimental data. As a result, the observed high- and low-energy peaks of 2DEG can be attributed to the spatially-separated 2DEG emissions formed at different AlGaN/GaN heterointerfaces.
광학적 방법으로 측정된 양자우물 안의 InAs 양자점의 에너지 준위
남형도,곽호상,송진동,최원준,조운조,이정일,조용훈,최정우,양해석,Nam H.D.,Kwack H.S.,Doynnette L.,Song J.D.,Choi W.J.,Cho W.J.,Lee J.I.,Cho Y.H.,Julien F.H.,Choe J.W.,Yang H.S. 한국진공학회 2006 Applied Science and Convergence Technology Vol.15 No.2
PL (photoluminescence), PLE (PL excitation) 그리고 근 적외선 투과 분광법을 활용하여 InAsGa/GaAs 우물 내 InAs 양자점 구조의 광학적 특성과 전자 버금 띠 구조에 대하여 연구하였다. 투과 스펙트럼과 PLE 스펙트럼으로부터 InAs 양자점 내 세 개의 구속 상태와 InGaAs/GaAs 우물 내에 두 개의 구속 상태가 존재함을 발견하였고, 광전류 스펙트럼에서 관측된 버금 띠 사이 전이들과 연관지어 해석하였다. We investigated the optical property and the electronic subband structure of InAs quantum dots in an InAsGa/GaAs well structure utilizing photoluminescence (PL), PL excitation (PLE) and near infrared transmission spectroscopy. From transmission and PLE spectra, we found three bound states in the InAs quantum dot and two bound states in InGaAs/GaAs quantum well, and correlated to the results of intersubband transitions observed in photocurrent spectrum.
이강인(K. I. Lee),박민수(M. S. Park),조용훈(Y. H. Cho),조윤환(Y. H. Cho),성영은(Y. E. Sung),주종남(C. N. Chu) 한국정밀공학회 2006 한국정밀공학회 학술발표대회 논문집 Vol.2006 No.5월
Mobile fuel cell is highlighted in these days because mobile fuel cell can contain more energy than existing batteries. Nowadays mobile devices like cellular phone, PMP(portable multi-media player), notebook, and etc. need more energy. But exiting batteries like Li-ion or Ni-MH batteries are not going to satisfy such demands. In this paper, mobile fuel cell is developed. Its size is 50*70*8㎜ and it is made of aluminium plates. The fuel cell type is PEM and the fuel is pure hydrogen and oxygen.