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Mechanistic Studies on the Reaction of Thioxanthylium Ion with Dimedone
안광현,김경태,Kwang Hyun Ahn,Kyongtae Kim Korean Chemical Society 1982 대한화학회지 Vol.26 No.2
티안트렌양이온 자유라디칼의 아세토니트릴 용액에 의해 티오크잔틴이 산화되어 생성된 티오크잔틸이움 이온에 디메돈을 넣어주면 9-(4,4-dimethylcyclohexane-2,6-dionyl)thioxanthylium 과염소산염(2)이 생성되나 순서를 바꾸어 넣어주면 초기에 9-(4,4-dimethylcyclohexane-2,6-dionyl)thioxanthene (1)이 생성되며 이것은 계속 반응하여 2를 만든다. 화합물 2는 물이 섞인 아세톤에서 쉽게 탈 수소화되어 9-(4,4-dimethylcyclohexane-2,6-dionylidene)thioxanthene (3)이 된다. 그러나 물이 섞인 아세토니트릴용액중에서 관찰된 219, 289, 348 nm의 isobestic point는 3이 2와 평형상태로 존재함을 말한다. 3의 380nm 근처에 있는 흡수띠의 위치와 강도는 용매에 따라 변하는데 이것은 용매-용질 사이의 상호작용으로 설명한다. Addition of dimedone to thioxanthylium ion generated from the oxidation of thioxanthene by thianthrene cation radical perchlorate in acetonitrile gave 9-(4,4-dimethylcyclohexane-2,6-dionyl)thioxanthylium perchlorate (2), whereas from the reverse addition between two reactants was obtained initially 9-(4,4-dimethylcyclohexane-2,6-dionyl)thioxanthene (1), which then underwent further reaction to give 2. The compound 2 was readily deprotonated in aq acetone to give 9-(4,4-dimethylcyclohexane-2,6-dionylidene)thioxanthene (3). However, 3 turned out to be in equilibrium with 2 in which three isosbestic points at 219, 289, and 348 nm were recorded in aq acetonitrile. The intensity and the position of the maximum absorption of 3 near 380 nm vary depending on the solvents which has been explained in terms of the solvent-solute interactions.
삼아릴-9-티오크잔테닐포스포니움 과염소산염의 아릴기에 의한 상자기성 벗김 효과
안광현,김경태,Kwang Hyun Ahn,Kyong Tae Kim 대한화학회 1981 대한화학회지 Vol.25 No.3
삼페닐-9-티오크잔텐닐포스포니움 과염소산염과 삼-오르토-메톡시페닐-9-티오크잔텐닐포스포니움 과염소산염과는 대조적으로 삼-n-부틸-9-티오크잔텐닐포스포니움 과염소산염과 삼벤질-9-티오크잔텐닐포스포니움 과염소산염은 각각 ${\delta}5.58$ppm과 ${\delta}5.70$ ppm 에서 methine 양성자에 해당하는 이중상을 보여주었다. 이 값은 9-아릴티오크잔틴의 상응값 (${\delta}5.05$~5.30)보다 다소 큰 값이나 방향족화합물의 양성자의 값과는 분명히 차이가 난다. 이 결과는 삼아릴-9-티오크잔텔닐포스포니움 과염소산염의 methine 양성자가 낮은 장으로 이동한 원인이 전자가 부족한 인원자에 의한 유발 효과때문이 아니라 인에 결합된 세개의 아릴기의 상자기성 벗김 효과에 의한 것임을 의미한다. In contrast with pmr (only multiplets at ${\delta}6.6$∼7.8 ppm) spectrum of triphenyl-9-thioxanthenylphosphonium perchlorate and tri-o-methoxyphenyl-9-thioxanthenylphosphonium perchlorate, tri-n-butyl-9-thioxanthenylphosphonium perchlorate and tribenzyl-9-thioxanthenylphosphonium perchlorate showed a doublet at ${\delta}5.58$ and 5.70ppm, respectively, assigned to a methine proton. This value is slightly larger than the corresponding values (${\delta}5.05$~5.30) of 9-arylthioxanthenes but clearly differentiated from those of aromatic protons. This result implys that the downfield shift of a methine proton of triaryl-9-thioxanthenylphosphonium perchlorate is not due to inductive effects of an electron deficient phosphorus atom but paramagnetic deshielding effects by three aryl groups on phosphorus.
강동완,임승진,안광현,Kang, Dong-Wan,Lim, Seung-Jin,Ahn, Kwang-Hyun 대한턱관절교합학회 2001 구강회복응용과학지 Vol.19 No.2
The purpose of this study is to to analyze the mechanical stress on articular disk of the dentated skull with the condition of unilateral posterior molar missing. For this study, the three dimensional finite element model of human skull scanned by means of computed tomography. (G.E. 8800 Quick, USA) was constructed. The finite element model of jaws is composed of 98,394 elements and 38,321 nodes, and it consists of articular disc, maxilla, mandible, teeth, periodontal ligament and cranium. Boundary condition included rigid restraints at the first molar and endosteal cortical surfaces of the insertion points of temporal bone. The data derived from Nelson's study were used for the loading conditions of mandible during clenchings and for maxilla, new loading and constraint conditions were applied. A clenching task during intercuspal position was modeled to the three dimensional finite element model. The stress level and displacement of articualr disc on the model with unilateral posterior molar missing under bilateral clenching task can be analyzed. During bilateral clenchings, the compressive stress level and diplacement of the articular disk on the side of unilateral posterior molar missing is greater than that on the case with full dentition, whereas a higher stress was found on the disk on the balancing side of the full dentition. Although this kind of study is not enough to explain the role of occlusion as an etiologic factor of TMD, there may be a possibiliy that the condition of posterior molar missings may contribute in part to the TMJ biomechanics.
윤길림(Yoon, Gil Lim),윤여원(Yoon, Yeo Won),안광현(Ahn, Kwang Hyun) 대한토목학회 2012 대한토목학회논문집 C Vol.32 No.6
본 논문에서는 경량화 재료인 기포를 혼합한 기포혼합경량토와 폐타이어 분말을 혼합한 타이어혼합경량토를 연약지반의 개량, 진동차폐재 및 교대의 뒷채움재 등으로 활용하기 위하여 공학적 특성을 조사하였다. 당 연구에서는 목표 습윤단위중량과 시멘트 혼합비 변화에 따른 기포혼합경량토와 타이어혼합경량토의 강도특정과 변형특성을 일축압축시험과 비압밀-비배수 삼축압축시험으로 분석하였다. 동일한 습윤단위중량(13kN/㎥)에서 2종류의 경량혼합토 강도특성을 비교한 결과, 일축압축시험에서는 같은 조건에서 비슷한 압축강도특성를 보였으나 비압밀-비배수 삼축압축시험 결과에서는 타이어 분말의 탄성특성으로 인한 영향으로 타이어혼합경량토가 기포혼합경량토 보다 큰 압축강도를 보였다. 그리고 2종류의 경량혼합토는 습윤단위중량과 시멘트량의 증가에 따라 일축압축강도와 삼축압축강도가 증가하였으나 습윤단위중량 11kN/㎥ 이하의 기포혼합경량토는 일정한 기포혼합비 수준에서는 시멘트량이 증가해도 기포에 의한 간극의 영향으로 경량혼합토의 강도는 증가하지 않거나 저하되는 것으로 나타났다. This paper investigates engineering characteristics of lightweight soils mixed with air foam and tire powder. Lightweight soils could be used as foundation materials, back-fills of reducing vibrating or abutment, and so on. Unconfined and triaxial compression tests were carried out to analyze strength and deformation characteristics of lightweight soils by changing target moist unit weight and cement contents. In comparison with strength characteristics of two different kinds of lightweight soils with same most unit weights (13 kN/㎥), unconfined compression tests showed similar compressive strength, however, triaxial compression tests showed that compressive strength of lightweight soils mixed with waste tire powder was relatively larger strength than that of lightweight soils mixed with air foam because of elasticity of waste tire powder. Also, unconfined and triaxial compressive strengths of most of lightweight soils increase with increases of moist unit weight and cement contents. However, the strength of lightweight soils mixed with air foam under 11 kN/㎥, when moist unit weight exceeds a certain cement contents, decreases even though cement contents increase because of the effect in a void gap of air foam.