강도자료의 수 계산

서일환,이진현 한국결정학회 1993 韓國結晶學會誌 Vol.4 No.1

The knowledge on the number of necessary and collectable reflections for the crystal structure analysis is greatly helpful in choosing the conditions for X-ray intensity data collection using automatic four circle diffractometer. In this paper, we represent a method to calculate the total unmber of collectable intensity date in an asymmetric unit.

Specification Scheme of Pig Liquid Manure as Organic Agricultural Substances Used for Organic Farming

서일환,이교석,이자현,민세원,정덕영 한국토양비료학회 2017 한국토양비료학회지 Vol.50 No.5

A more efficient use of nutrients from organic sources can benefit both farmers and water quality in agriculture. In this paper we reviewed information related to the regulations and guidelines of a swine liquid fertilizer topropose an establishment scheme for the official standards of swine manure slurry as a liquid fertilizer fororganic farming. According to the law of establishment and designation of official standard of fertilizers, theliquid fertilizer made with pig liquid manure belongs to the byproduct fertilizer as of one of organic fertilizer. However, the official standards for byproduct fertilizers including the liquid fertilizer set by the RuralDevelopment Administration (RDA), especially for a liquid swine manure fertilizer, should be revised to meetthe goals of laws pursuing the environmentally sound agriculture, especially for organic farming because theterms and relevant standards need additional specific standards alike the standards such as impurities andparameter for declaration in EU. Therefore, it is suggested that official standards for byproduct fertilizersshould be revised with respect to nutrient, salt content as of SAR and Na content instead of NaCl. Also weneed to develop the maximum limit of heavy metals in soil to which the liquid fertilizer can be applied, as wellas application rate depending on EC of the liquid fertilizer.

화합물내에서의 수소원자의 이상적 위치계산

서일환,김경한,오미란,박균하,김문집,Suh Il-Bwan,Kim Kyung-Han,Oh Mi-Ran,Park Koon Ha,Kim Moon-Jib 한국결정학회 1997 韓國結晶學會誌 Vol.8 No.1

화합물내에 존재하는 다음 7가지 수소원자의 이상적인 위치들의 한가지 계산법을 보였다. (1) 3급 C-H, (2) 2급 C-H, (3) 1급 C-H, (4) 방향환 C-H와 N-H, (5) 수산기 O-H, (6) 말단평면내의 2개의 수소 (7) 선형인 X-C-H를 갖는 아세틸렌 C-H. A method for the calculation of the idealized hydrogen positions in the following seven different kinds of compounds has been shown: (1) tertiary C-H, (2) secondary C-H, (3) $CH_3$ group with tetrahedral angles, (4) aromatic C-H or amide N-H, (5) O-H group with X-O-H angle tetrahedral, (6) terminal $X=CH_2$ or $X=NH_2^+$ with the hydrogen atoms in a plane and (7) acetylenic C-H with X-C-H linear.

자율 주행 트랙터 경운경로생성 프로그램 개발

서일환(Il Hwan Seo),서동현(Dong Hyun Seo),김기대(Ki Dae Kim) 충남대학교 농업과학연구소 2010 농업과학연구 Vol.37 No.1

Land consolidation ratio for rice paddy fields reached to 64.7% as of 2008 in Korea, and this also accelerated automation of field machinery. Especially, research on autonomous tractors has been continuously conducted. Tillage is one of the labor-, energy-, and time-consuming field operations. Most important requirements for autonomous tractors would be travelling path planning and electronic system to control the tractor to follow the path. The instruction of computer was required to conduct the tillage operation in field with unmanned traveling tractor. This instruction was coincidently used in the control of the traveling path and the motion of tractor. The objectives of the study were 1) to characterize and model tillage operating sequence, turning pattern, and 2) to develop tillage path formation programs for autonomous tractor and evaluate the performance.

Crystal Structure of 3-Methyl-4-Methoxy-4'-Nitrostilbene

서일환,김문집 한국결정학회 1992 韓國結晶學會誌 Vol.3 No.2

The crystal structure of the title compound was determined from single crystal X-ray dirt fraction study : C16H16NO3, Mr=271.316, orthorh ombic, Aba2, a=15.750(3), b=13.470(2), c=13.356 (2) A, V=2833A, Z=8, Dx=1.26 Mgm-3, λ(MoK a) =0.71069A, r=0.51mm-2, F(000)=1136, T=291 K, R=0.0414 for 728 unique observed [F≥3e(F)] reflections and 240 parameters. The molecule is nearly planar within 0.2 A with the torsion angle -179(2)°for C(4)-C(7)-C(8)-C(9).The into rmolecular interactions are mainly by van der Waals force with the nearest intermolecular distance 3.647A between O(3) and C(4) translated by half unit along band c-axes.

강제환기식 돈사의 환기 효율성 분석을 위한 CFD 모델 개발

서일환,이인복,홍세운,황현섭,유재인,권경석,하태환,김현태,Seo, Il-Hwan,Lee, In-Bok,Hong, Se-Woon,Hwang, Hyun-Seob,Bitog, Jessie Pascul,Yoo, Jae-In,Kwon, Kyung-Suk,Ha, Tae-Hwan,Kim, Hyeon-Tae 한국농공학회 2008 한국농공학회논문집 Vol.50 No.1

When livestock facilities in Korea have been changed larger and denser, rearing conditions have been getting worse and the productivity of animal production have been decreased. Especially in the cold season, the minimized ventilation has generally been operated to save energy cost in Korea resulting in very poor environmental condition and high mortality. While the stability, suitability, and uniformity of the rearing condition are the most important for high productivity, the ventilation configuration is the most important to improve the rearing condition seasonally. But, it is so difficult to analyze the internal air flow and the environmental factors by conducting only field experiment because the weather condition is very unpredictable and unstable as well as the structural specification can not be easily changed by the researchers considering cost and labor. Accordingly, an aerodynamic computer simulation was adopted to this study to overcome the weakness of conducting field experiment and study the aerodynamic itself. It has been supposed that the airflow is the main mechanism of heat, mass, and momentum transfers. To make the simulation model accurately and actually, simplified pig models were also developed. The accuracy of the CFD simulation model was enhanced by 4.4 % of errors compared with the data collected from field experiments. In this paper, using the verified CFD model, the CFD computed internal rearing condition of the mechanically ventilated pig house were analyzed quantitatively as well as qualitatively. Later, this developed model will be computed time-dependently to effectively analyze the seasonal ventilation efficiency more practically and extensively with tracer gas decay theory.

Tris(tetraethylammnnium) [bis(trimetaphosphate $\kappa^3O, O^', O^{"}$)] Vamdate(3-),$[V(P_3O_9)_2](NC_8H_{20})_3$,의 두가지 가능한 공간군

서일환,이진호 한국결정학회 1994 韓國結晶學會誌 Vol.5 No.1

화합물 VP6N3018C243H60의 두 가지 가능한 공간군은 PT,a=14.O22(1), b=12.644(2), c=12.640(1)A, a=80.38(1), β=102.12(1), y =102.16(1), V=2124.1A3, Z=2, u=0.47cm-1,d==1.46g/cm3, Fo>4c IfoI인 3350윤의 독립반사강도에 대하여 R=0.083 과 C2/c, a=19.32(2), b=16.32(2), c=14.02(1)A, β= 105.98(5), V=4348.2A3, Z=4, Fo>4o IFoI인 1590개의 독립반사강도에 대하여 R=0.083 이다. 주간군 Pi의 경우 단위포내에 두 분자가 있는데 각 분자내의 바나둠 원자가 특수치치에 있어 중심대칭에 의하여 한 분자를 이루고 있으므로 단위포내의 비대칭단위는 두개의 bis(timetalhosphate)vanadate 반분자와 3개의 tetraethylammDnium분자로 되어있다. 공문군 C2/c의 경우 bis(trimetaphosphate)vanadate 한분자의 vanadium 원자가 중심대1칭을 갖는 변광단동치에 있으며, 3개의 tetrethylammonium 분자중 한 분자내의 CL2, N2, C25 원자들을 2-회회전대칭축이 지나므로 bis(trimetaphosphate)vanadate 반분자와 tetraethylammonium 3/2 분자가 비대칭단위를 이루고 있다. 두 경우 공히 vanadium원자를 배위하고 있는 6개의 산소원자가 8함체를 이루며 nitrogen원자와 결합하고 있는 4개의 carbon 원자들은 모두 disorder되어 있어 nitrogen원자의 주권에 있는 8개의 carbon 원자들은 불규칙한 12면체를 이루고 있다. Two possible space groups of the comfound, VP6N3018C24H:60, are: P 1, a=14.022(1), b=12.644(2), c= 12.640(1)A, a=8038(1), B=102.12(1), r=102.16(1), V=2124.1A3, Z=2, μ=0.47cm-1, d=1.46g/cm3, R=0.083 for 3350 independent reflections with Fo>4o IFI, and C2/c, a=19.32(2), b=16.32(2), c=14.02(1)A, B=105.98(5), β=105.98(5), V=4248.2A3, Z=4 R=0.083 for 1590 independent reflections with Fo>4c IFoI . In the space group P T, there are two monlecules in a unit cell. Vanadium atoms in the two monlecules occupy the two different special positions such that the complete monlecules are accomplished by the two independent center of symmetry. Therefore two different half molecules of bis(trimetaphosphate)vanadate and three molecules of tetraethylammonium are the asymmetric unit in a unit cell. In the space group C2/c, however, the vanadium atom is located at a special position with centrosymmetry, and a two-fold symmetry axis passes through C2/c, N2 and C25 atoms. Therefore the asymmrtic unit in a unit cell consists of a half molecule of bis(trimetaphosphate)vanadate and one and a half molecules of tetraethylammonium. All the molecular conformations in both space groups are very similar: six oxygen atoms coordinated to a vanadium atom in the bi s(trimetaphosphate)vanadate molecule form an octahedron and the four carbon atoms bonded to a nitrogen atom in the tetraethylammonium molecule are disordered so that the eight carbon atoms around nitrogen atom exhibit an irregular dodecahedral form.

$\alpha$,$\beta$-Diphenylsuccinic Acid의 구조

서일환,윤민중 한국결정학회 1994 韓國結晶學會誌 Vol.5 No.2

C19H20O5, Mr=314.337,삼사정계,PI, a=10.291(2)A, b=11.218(3)A, c=3.059(1)A, α=74.54(2)°,β=1148.84(1)°,r=109.84(2)°,V=883.283(2)A3, λ(Mo Kα)=0.71069A, μ=0.47 mm-1, F(000)=324, 296K, Z=2, Dx=1.18Mgm-3. 1637[F>3σ(F)]개 독립 반사면에 대한 최종 R=0.0580이다. α,β-diphenylsuccinic acid,C16H14O4, 분자들은 O(4)-H˙˙˙O(5)수소결합에 의하여 용체인 acetone과 결합되어 있고 중심대칭관계에 있는 dimer는 분자간의 carboxylic 수소결합 O(1)-H˙˙˙O(2)(-x,-y,-z)에 의하여 결합되어 있다. Dimer간의 가장 가까운 거리 3.288A[O(2)˙˙˙O(2)(-x,-y,-z)]은 분자들의 packing이 van der Waals 력으로 이루어졌음을 보인다. C19H20O5, Mr=314.337, triclinic,PI, a=10.291(2)A, b=11.218(3)A, c=3.059(1)A, α=74.54(2)°, β=1148.84(1)°, r=109.84(2)°, V=883.283(2)A3, λ(Mo Kα)=0.71069A, μ=0.47 mm-1, F(000)=324, 296K, Z=2, Dx=1.18Mgm-3. Final R=0.0580 for 1637[F>3σ(F)]unique refledtions. α,β-diphenylsuccinic acid, C16H14O4, are connedted with the solvent actone by hydrogen bond O(4)-H˙˙˙O(5), forming a dimer related by related by centrosymmentry thorough intermolecualr carboxylic hydrogen bond O(1)-H˙˙˙O(2)(-x,-y,-z). The nearest distance 3.288A[O(2)˙˙˙O(2)(-x,-y,-z)] between the dimers shows that the packing of the dimer is govermed by van der Waals'force.

Structure Factor와 Electron Density간의 관계

서일환 한국결정학회 2000 韓國結晶學會誌 Vol.11 No.4

Structure factor는 위치를 포함한 electron density를 알면 계산되고 역으로 electron density는 phase를 포함한 structure factor를 알면 작도할수 있으므로 structure factor와 electron density는 서로 Fourier transform이다.

De Jong-Bouman Camera를 이용한 진동사진을 촬영하기 위하여 결정방향을 속히 맞추는 방법

서일환,이진호 한국결정학회 1993 韓國結晶學會誌 Vol.4 No.2

Dejong-Bourruncamera를 이용 한진동사진술에서 시료의 방향 수E방법의 이론이 논의되었다. 적도선으로부터 Othlayer의 회절반점들의 편차를 재어서 가하고 감하면 그들의 각각이 수평 및 수직 arc의 수정분이다. A converuent crystal orientation method for oscillation shot ograchy using de Jong Boumancamera is presented The method involves the measuremint of the deviations of resection spots of Oth layer from the equator These deviations are added or subtracted to give the horizontal and vertical arc corrections.