Systematic Study of Selective Solvents in Pseudo-Heterojunction Organic Solar Cells

( Zhe Sun ),양창덕 한국공업화학회 2023 한국공업화학회 연구논문 초록집 Vol.2023 No.0

Dibenzoheptazethrene Isomers with Different Biradical Characters: An Exercise of Clar’s Aromatic Sextet Rule in Singlet Biradicaloids

Sun, Zhe,Lee, Sangsu,Park, Kyu Hyung,Zhu, Xiaojian,Zhang, Wenhua,Zheng, Bin,Hu, Pan,Zeng, Zebing,Das, Soumyajit,Li, Yuan,Chi, Chunyan,Li, Run-Wei,Huang, Kuo-Wei,Ding, Jun,Kim, Dongho,Wu, Jishan American Chemical Society 2013 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY - Vol.135 No.48

<P><I>Clar’s aromatic sextet rule</I> has been widely used for the prediction of the reactivity and stability of polycyclic aromatic hydrocarbons with a <I>closed-shell</I> electronic configuration. Recent advances in <I>open-shell</I> biradicaloids have shown that the number of aromatic sextet rings plays an important role in determination of their ground states. In order to test the validity of this rule in singlet biradicaloids, the two soluble and stable dibenzoheptazethrene isomers <B>DBHZ1</B> and <B>DBHZ2</B> were prepared by different synthetic approaches and isolated in crystalline form. These two molecules have different numbers of aromatic sextet rings in their respective biradical resonance forms and thus are expected to exhibit varied singlet biradical character. This assumption was verified by different experimental methods, including nuclear magnetic resonance (NMR), electron spin resonance (ESR), superconducting quantum interference device (SQUID), steady-state and transient absorption spectroscopy (TA), and X-ray crystallographic analysis, assisted by unrestricted symmetry-broken density functional theory (DFT) calculations. <B>DBHZ2</B>, with more aromatic sextet rings in the biradical form, was demonstrated to possess greater biradical character than <B>DBHZ1</B>; as a result, <B>DBHZ2</B> exhibited an intense one-photon absorption (OPA) in the near-infrared region (λ<SUB>abs</SUB><SUP>max</SUP> <I>=</I> 804 nm) and a large two-photon absorption (TPA) cross-section (σ<SUP>(2)</SUP><SUB>max</SUB> = 2800 GM at 1600 nm). This investigation together with previous studies indicates that Clar’s aromatic sextet rule can be further extended to the singlet biradicaloids to predict their ground states and singlet biradical characters.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jacsat/2013/jacsat.2013.135.issue-48/ja410279j/production/images/medium/ja-2013-10279j_0012.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/ja410279j'>ACS Electronic Supporting Info</A></P>

P2CP: A New Cloud Storage Model to Enhance Performance of Cloud Services

Zhe SUN,Jun SHEN,Ghassan BEYDOUN 한국경영정보학회 2011 한국경영정보학회 학술대회논문집 Vol.2011 No.06

Validity Analysis of Spray Model by Comparing Simulated with Measured Spray Liquid and Vapor Phase

( Zhe Sun ),( Xue Dong ),( Peng Yin ),( Tianyun Li ),( David L. S. Hung ),( Min Xu ) 한국액체미립화학회 2017 한국액체미립화학회 학술강연회 논문집 Vol.2017 No.-

Gasoline direct injection (GDI) Engine is proved to be a key technology to save energy and reduce emissions, which improves the overall engine performance. Spray injection affect the fuel-air mixing directly and computational fluid dynamics(CFD)software is utilized to model the macroscopic shape of the spray and the vapor mass. In this paper, the liquid and vapor phase of the spray of a one-hole injector was studied both experimentally and numerically. The structure and concentration distribution of the vapor phase of the spray, vapor mass and spray penetration were measured using laser induced exciplex fluorescence (LIEF) technique in a constant volume chamber. The simulations were performed by the CONVERGE software. Both the spray penetration and Sauter Mean Diameter (SMD) employed in the simulation were calibrated with the in-chamber measurements. The comparison of vapor concentration between the simulated results and the measured results acquired from the chamber suggest that the evaporation model of the single component fuel has significant influence on the simulated results. In addition, an analysis based on the present evaporation model has been made in this study. The results show that the 2-D plane and local line distributions of vapor concentration in simulation do not best match those from the experiments. It is found to get higher vapor concentration in the simulation model, suggesting that the relationship between vapor concentration and evaporation rate should be considered and further verified.

Synthesis of 8-Alkoxy-4,5-dihydro-[1,2,4]triazole[4,3-a]quinoline-1-ones and Evaluation of their Anticonvulsant Properties

Sun, Xian-Yu,Jin, Yun-Zhe,Li, Fu-Nan,Li, Gao,Chai, Kyu-Yun,Quan, Zhe-Shan The Pharmaceutical Society of Korea 2006 Archives of Pharmacal Research Vol.29 No.12

A series of 8-alkoxy-4,5-dihydro-[1,2,4]triazole[4,3-a]quinoline-1-one derivatives were synthesized using 7-hydroxy-3,4-dihydro-2(1H)-quinolone as the starting material. Their anticonvulsant activities were evaluated by the maximal electroshock test (MES) and the subcutaneous pentylenetetrazole test (sc-PTZ), and their neurotoxicities were measured by the rotarod neurotoxicity test (Tox). The tests demonstrated that 8-hexyloxy-4,5-dihydro-[1.2.4]triazole[4.3-a]quinoline-1-one (4e) and 8-heptyloxy-4,5-dihydro-[1,2,4]triazole[4, 3-a]quinoline-1-one (4f) were the most potent anticonvulsants, with 4e having $ED_{50}$ values of 17.17 mg/kg and 24.55 mg/kg and protective index ($PI=TD_{50}/ED_{50}$) values of 41.9 and 29.3 in the MES and sc-PTZ tests, respectively, and 4f having $ED_{50}$ values of 19.7 mg/kg and 21.2 mg/kg and PI values of 36.5 and 33.9 in the MES and sc-PTZ tests, respectively. The PI values of 4e and 4f were many fold better than that of the marketed drugs phenytoin, carbamazepine, phenobarbital and valproate, which have PI values in the range of 1.6-8.1 in the MES test and <0.22-5.2 in the sc-PTZ test. Structure-activity relationships were also discussed.

중국의 정권별 스포츠정책의 특성에 관한 연구

손성철(Sun Cheng-Zhe) 한국체육과학회 2010 한국체육과학회지 Vol.19 No.4

This study was designed to examine sports policies in the Deng Xiaoping era and Zhang era after social reformation and market opening and to compare them with sports policies in the Mao Zedong era that were implemented for constructing socialism. The results of this study are as following. Firstly, in the Deng Xiaoping era, school sports policies had developed in many ways based on four educational purposes, since they escaped from sports systems of Soviet Russia. Secondly, they reformed competition systems to enhance competition levels as an elite sports policy. The National Sports Commission put many efforts into constructing managemental systems of each region by classifying each competition to make each game develop in harmony. As the result, in 1984, China was emerged as the power of sports, placing four in the LA Olympic. Thirdly, through development of elite sports and reformation of administration systems of popular sports groups, each company, social organization and people started organizing groups for sports activities and systems to cultivate popular sports leaders who taught each sport game were constructed through a positive investment in sports facilities. Fourthly, in the Zhang era, Chinese government strengthened sanitary projects of school sports systems by constructing and developing socialism, succeeding to sports policies developed under the Deng Xiaoping regime. Fifthly, professional sports first appeared with development of the sports industry. Sixthly, since sports acts of People`s Republic of China were enacted in 1995 as popular sports policies, the nation got rights to legally participate in various sports activities. The new sports policies made a big contribution to making the environment that the nation and society jointly could share and enjoy popular sports in China.

중국의 개혁개방 이전의 체육정책에 관한 연구

손성철(Sun Cheng-Zhe),황의룡(Hwang Eui-Ryong) 한국체육과학회 2011 한국체육과학회지 Vol.20 No.1

This study focuses on sports policy of Mao Zedong period in order to analyze development of Sports in China and the results are as follows. First, sports policy of Mao Zedong government is based on sports policy of Soviet Union and implemented National Sports Policy which is characterized by socialism such as centralization and planned economy. Its implementation reinforced physical education in schools and contributed on development of elite sports and public sports. Second, by active and planned dissemination of sports led by the government, the infrastructure of Chinese sports was established which was devastated in the early period of foundation of Chinese government. It not only contributed on development of school sports, elite sports and public sports but also gave pride to the people by promoting the national prestige by sports. Third, planned guidance of sports by the government impeded the development of sports itself and a number of issues were raised as a result. Especially, by the 'Great Leap Forward' and 'Cultural Revolution' reformed the ideas of socialism and priorities the will of people, which resulted on Chinese sports policy being operated by abnormal systems.

재한 중국 유학생들의 고혈압 관련 영양지식과 식생활 실천에 관한 연구

손철(Sun, Zhe),조우균(Cho, Wookyoun) 한국영양학회 2015 Journal of Nutrition and Health Vol.48 No.5

본 연구는 2014년 9월 8일부터 10월 14일까지 국내 3개월 이상 거주한 만 19세 이상의 대학교에 재학 중인 중국 유학생 276명을 대상으로 고혈압 및 나트륨 관련 영양지식, 고염가공식품 섭취빈도, 고혈압예방 식생활 실천도, 식행동 변화단계를 조사하여 영양지식과 고혈압 예방 실천도와 의 관계를 분석한 결과는 다음과 같다. 조사대상자의 고혈압 관련 영양지식 점수는 총 50점 만점 중 평균 40.62점으로 나타났다. ‘개인의 혈압은 언제, 어디서나 항상 일정하다.’의 정답률이 95.7%로 가장 높은 반면 ‘고혈압은 유전적 소인이 있는 질병이다.’가 44.6%로 가장 낮았다. 나트륨 관련 영양지식 점수는 총 30점 만점으로 평균 24.00점으로 나타났다. ‘음식 조리 시 소금을 전혀 넣지 않으면 나의 나트륨 섭취량은 0이다.’와 ‘나트륨 섭취를 많이 할수록 건강에 좋다.’는 항목의 정답률이 89.5%로 가장 높게 나타났으며. ‘국, 찌개 등의 국물을 적게 먹는 것은 혈압의 조절에 도움이 된다.’가 56.2%로 가장 낮은 정답률을 보였으나 나트륨 관련 영양지식의 전 항목의 정답률은 50%이상인 것으로 나타났다. 고염가공식품 섭취빈도는 김치류가 6.34점으로 가장 많이 섭취하는 것으로 나타났으며, 고혈압 예방 실천도는 5점 만점 중 총 평균은 3.10점으로 나타났다. 고혈압 예방 실천 항목에서 ‘담배를 피우지 않는다.’의 평균점수 (4.03점)가 가장 높게 나타났으며 ‘정기적으로 혈압을 측정하고 의사의 진찰을 받는다.’가 2.47점으로 가장 낮게 나타났다. 고혈압 예방 식행동 변화단계 분포는 고려단계 (47.1%), 행동단계 (32.2%), 고려전단계 (20.7%) 순으로 고려단계가 가장 많은 것으로 나타났다. 고혈압 예방 식행동 변화단계에 따른 고혈압 관련 영양지식, 나트륨 관련 영양지식과 고혈압 예방 실천도는 고려전단계에서 가장 낮고, 행동단계에서는 가장 높게 나타났다. 식행동 변화단계가 고려전단계에서 행동단계로 갈수록 영양지식과 식생활 실천도의 점수가 상승하는 경향이 있었다. 고혈압 및 나트륨 관련 영양지식과 식생활 실천도의 상관관계를 분석한 결과, 영양지식과 고혈압 예방 실천도가 유의한 정 (+)의 상관관계가 있었고, 고염가공식품 섭취빈도와 유의한 부 (?)의 상관관계가 있는 것으로 나타났다. 이상의 결과를 종합하면 고혈압 및 나트륨 관련 영양지식의 점수가 높을수록 고혈압 예방 실천도의 점수가 높았고, 고염가공 식품섭취빈도가 낮았다. 영양지식 점수가 높을수록 식행동 변화의 단계 중 고려전단계나 고려단계보다는 행동단계의 점수가 유의적으로 높았다. 그러므로 중국 유학생들의 건강 식생활 실천을 위해서는 고혈압과 나트륨 관련 영양지식을 교육하고, 한국음식에 대한 이해를 높임과 동시에 건강 식생활 실천을 효과적으로 할 수 있는 교육프로그램을 개발하여 고염가공식품의 섭취빈도를 낮추고, 주기적인 식생활 평가를 통한 유학생 지원 방안을 모색해야 할 것이다. Purpose: The purpose of this study was to investigate the effects of hypertension relevant nutrition knowledge on practices for prevention of hypertension in Chinese college students studying in South Korea. Methods: We conducted a survey of 276 Chinese students studying more than three months in Korean universities who were aged 19 and older about hypertension and sodium relevant nutrition knowledge, intake of salty processed food, hypertension prevention practices, and stages of behavior change for hypertension. Results: The average score on the questionnaire for hypertension relevant nutritional knowledge was 40.62 out of 50 points, and the average score for sodium relevant nutritional knowledge was 24 out of 30 points. Kimchi was the most frequently eaten salty processed food. The average score for hypertension prevention practices was 3.10 out of 5 points. The behavior change stages for prevention of hypertension were contemplation (47.1%), action (32.2%), and pre-contemplation (20.7%). The students received high scores on nutrition knowledge and showed significantly higher scores on the action stage than on pre-contemplation or contemplation. Nutritional knowledge of hypertension and sodium showed positive correlation with hypertension prevention practices, whereas negative correlation with salty processed food intake. Conclusion: Development of an education program for Chinese students in Korea on hypertension and sodium relevant nutritional knowledge is needed so that they can practice for prevention of hypertension.

Synthesis of 8-Alkoxy-4,5-dihydro-[1,2,4]triazole[4,3-a]quinoline-1-ones and Evaluation of their Anticonvulsant Properties

Xian-Yu Sun,Yun-Zhe Jin,Fu-Nan Li,Gao Li,Kyu-Yun Chai,Zhe-Shan Quan 대한약학회 2006 Archives of Pharmacal Research Vol.29 No.12

A series of 8-alkoxy-4,5-dihydro-[1,2,4]triazole[4,3-a]quinoline-1-one derivatives were synthesized using 7-hydroxy-3,4-dihydro-2(1H)-quinolone as the starting material. Their anticonvulsant activities were evaluated by the maximal electroshock test (MES) and the subcutaneous pentylenetetrazole test (sc-PTZ), and their neurotoxicities were measured by the rotarod neurotoxicity test (Tox). The tests demonstrated that 8-hexyloxy-4,5-dihydro-[1.2.4]triazole[4.3- a]quinoline-1-one (4e) and 8-heptyloxy-4,5-dihydro-[1,2,4] triazole[4,3-a]quinoline-1-one (4f) were the most potent anticonvulsants, with 4e having ED50 values of 17.17 mg/kg and 24.55 mg/kg and protective index (PI = TD50/ED50) values of 41.9 and 29.3 in the MES and sc-PTZ tests, respectively, and 4f having ED50 values of 19.7 mg/kg and 21.2 mg/kg and PI values of 36.5 and 33.9 in the MES and sc-PTZ tests, respectively. The PI values of 4e and 4f were many fold better than that of the marketed drugs phenytoin, carbamazepine, phenobarbital and valproate, which have PI values in the range of 1.6-8.1 in the MES test and <0.22-5.2 in the sc-PTZ test. Structure-activity relationships were also discussed.

Numerical study of the run-up of a solitary wave after propagation over a saw-tooth-shaped submerged breakwater

Sun, Jiawen,Ma, Zhe,Wang, Dongxu,Dong, Sheng,Zhou, Ting The Society of Naval Architects of Korea 2020 International Journal of Naval Architecture and Oc Vol.12 No.1

A numerical model is established to investigate the run-up of a solitary wave after propagating over a triangular saw-tooth-shaped submerged breakwater. A rectangular-shaped submerged breakwater is simulated for comparison. Several factors, including the submerged depth, the lagoon length and the beach slope, are selected as independent variables. The free surface motions and velocity fields of the solitary wave interacting with the submerged breakwater are discussed. The results show that the submerged depth and lagoon length play significant roles in reducing the run-up. The influence of the beach slope is not significant. At the same submerged depth, the triangular saw-tooth-shaped submerged breakwater has only a slightly better effect than the rectangular-shaped submerged breakwater on the run-up reduction. However, a calmer reflected wave profile could be obtained with the rougher surface of the saw-tooth-shaped submerged breakwater. The study conclusions are expected to be useful for the conceptual design of saw-tooth-shaped submerged breakwaters.