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RISS 인기검색어
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- 저자 : Tan Qiao (검색결과 13 건)
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Tan, Xiaojun,Li, Zhen,Sun, Qiao,Li, Ping,Wang, Weihua Korean Chemical Society 2012 Bulletin of the Korean Chemical Society Vol.33 No.6
The reaction mechanism between cyclopropenylidene and formaldehyde has been systematically investigated employing the MP2/6-311+$G^*$ level of theory to better understand the cyclopropenylidene reactivity with carbonyl compound. Geometry optimization, vibrational analysis, and energy property for the involved stationary points on the potential energy surface have been calculated. Energies of all the species are further corrected by the CCSD(T)/6-311+$G^*$ single-point calculations. It was found that one important reaction intermediate (INTa) has been located firstly $via$ a transition state (TSa). After that, the common intermediate (INTb) for the two pathways (1) and (2) has been formed $via$ TSb. At last, two different products possessing three- and four-membered ring characters have been obtained through two possible reaction pathways. In the reaction pathway (1), a three-membered ring alkyne compound has been obtained. As for the reaction pathway (2), it is the formation of the four-membered ring conjugated diene compound. The energy barrier of the ratedetermining step of pathway (1) is lower than that of the pathway (2), and the ultima product of pathway (2) is more stable than that of the pathway (1).
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Linxiang Tan,Xiaoxia Ke,Xuechun Song,Qiaoqiao Yin,Ru Qiao,Kaiyan Guo,Lanlan Zhu 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.60 No.-
A novel NIR-responsive photocatalyst NaYF4:Yb,Er@SiO2@Zn1 − xMnxO with double-layered core–shell structure was prepared by a three-step reaction. NaYF4:Yb,Er serves as a NIR-to-visible upconverter and provides “visible light” or “necessary energy” to Zn1 − xMnxO. Meanwhile, Mn2+-doping in Zn1 − xMnxO can extend the photoresponse of ZnO to visible-light region and enhance its charge separation. The nanocomposite exhibits good activity for dye decomposition and antibacterial property under NIR irradiation. The “energy absorption – energy conversion – energy transfer – surface reaction” process dominates the overall photocatalytic activity. Based on the standard MTT (abbr. for 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide) assay, NaYF4:Yb,Er@SiO2@Zn1 − xMnxO also exhibits good biocompatibility and low cytotoxicity with human umbilical vein endothelial cells (HUVEC) as model cells.
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Xiaojun Tan,Zhen Li,Qiao Sun,Ping Li,Weihua Wang 대한화학회 2012 Bulletin of the Korean Chemical Society Vol.33 No.6
The reaction mechanism between cyclopropenylidene and formaldehyde has been systematically investigated employing the MP2/6-311+G* level of theory to better understand the cyclopropenylidene reactivity with carbonyl compound. Geometry optimization, vibrational analysis, and energy property for the involved stationary points on the potential energy surface have been calculated. Energies of all the species are further corrected by the CCSD(T)/6-311+G* single-point calculations. It was found that one important reaction intermediate (INTa) has been located firstly via a transition state (TSa). After that, the common intermediate (INTb) for the two pathways (1) and (2) has been formed via TSb. At last, two different products possessing three- and four-membered ring characters have been obtained through two possible reaction pathways. In the reaction pathway (1), a three-membered ring alkyne compound has been obtained. As for the reaction pathway (2), it is the formation of the four-membered ring conjugated diene compound. The energy barrier of the ratedetermining step of pathway (1) is lower than that of the pathway (2), and the ultima product of pathway (2) is more stable than that of the pathway (1).
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Linxiang Tan,Wenjie Wu,Qiaoqiao Yin,Xiaoxia Ke,Ru Qiao,Guoxiu Tong,Lanlan Zhu 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.52 No.-
The dimer-type heterostructured Ag/Zn0.995Ni0.005O microspheres were prepared via two-stepmicrowave-assisted process, which exhibited stronger visible-light-activated antibacterial performancethan visible-light only, ZnO/Vis, Zn0.995Ni0.005O/Vis, or AgNPs/Vis. It is attributed to not only theinteraction of released metal ions with functional groups of vital enzymes and proteins, but also thecollapsing force of reactive oxygen species to the cells. Photoelectrochemical measurements show thatthe photogenerated charges of Ag/Zn0.995Ni0.005O possess longer lifetime and higher separation resultingfrom the synergistic effect between Ni and Ag, which leads to its superior visible-light-drivenantibacterial performance. Gram-negative bacteria are more effectively restrained by Ag/Zn0.995Ni0.005Othan Gram-positive bacteria because of structural difference between their cell walls.
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Wang, Xiao-Qiao,Tan, Chuan Fu,Chan, Kwok Hoe,Xu, Kaichen,Hong, Minghui,Kim, Sang-Woo,Ho, Ghim Wei American Chemical Society 2017 ACS NANO Vol.11 No.10
<P>At present, there are various limitations to harvesting ambient waste heat which include the lack of economically viable material and innovative design features that can efficiently recover low grade heat for useful energy conversion. In this work, a thermal nanophotonic-pyroelectric (TNPh-pyro) scheme consisting of a metamaterial multilayer and pyroelectric material, which performs synergistic waste heat rejection and photothermal heat-to-electricity conversion, is presented. Unlike any other pyroelectric configuration, this conceptual design deviates from the conventional by deliberately employing back-reflecting NIR to enable waste heat reutilization/recuperation to enhance pyroelectric generation, avoiding excessive solar heat uptake and also retaining high visual transparency of the device. Passive solar reflective cooling up to 4.1 degrees C is demonstrated. Meanwhile, the photothermal pyroelectric performance capitalizing on the back-reflecting effect shows an open circuit voltage (V-oc) and short circuit current (I-sc) enhancement of 152 and 146%, respectively. In addition, the designed photoactive component (TiO2/Cu) within the metamaterial multilayer provides the TNPh-pyro system with an effective air pollutant photodegradation functionality. Finally, proof-of-concept for concurrent photothermal management and enhanced solar pyroelectric generation under a real outdoor environment is demonstrated.</P>
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Zhang Yu-Xing,Tan Qiao,Shen Chen-Hui,Wu Jian-Jian,Wu Yi-Kuan,Li Wen-Ze,Jin Lin,Li Guo-Qing 한국응용곤충학회 2022 Journal of Asia-Pacific Entomology Vol.25 No.2
Henosepilachna vigintioctomaculata is one of the most serious defoliates attacking potatoes. However, studies on functional genes have greatly been limited due to the insufficiency of effective and stable endogenous references to normalize RT-qPCR data. In this report, nine housekeeping genes (RPL4, RPL6, RPL13, RPL32, RPS18, ACT, EF1α, GAPDH and α-TUB) involved in different biological processes were selected. Their expression levels under diverse experimental conditions including developmental stages, tissues, temperatures and host plants were determined using RT-qPCR technology. The tested candidate genes were comprehensively ranked based on five alternative stability analysis methods (Ct value, geNorm, NormFinder, BestKeeper and ReFinder). The results revealed that the optimal internal reference genes varied under different experimental conditions. Any gene pair among the five candidates (RPL4, RPL13, RPL32, RPS18 and EF1α) was a suitable reference gene set under different temperatures and on different host plants. A combination of RPL6 and RPL13 was recommended as the best reference gene set across different developmental stages. A pair of RPS18 and EF1α was ranked as the optimal reference gene combination within different tissues. The most suitable reference genes were RPS18 and RPL13 under four different experimental conditions. Our findings not only establish an accurate and reliable normalization of RT-qPCR data, but also lay a solid foundation for further functional gene researches in H. vigintioctomaculata
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Design a Laboratory Rotating Test Bench for the Multi-Channel Dryer Experiment
Sha Wang,Jixian Dong,Changke Tan,Bo Wang,Lijie Qiao,Huan Liu 한국펄프·종이공학회 2019 펄프.종이기술 Vol.51 No.5
The dryer of paper machine has problem in discharging condensate water. When the dryer rotates at a high speed, the condensate water that is not discharged in time will form a water ring, resulting in low drying efficiency and high energy consumption. Thus, based on the multi-channel dryer proposed by others, a series of experiments was carried out on multi-channel dryer under static condition. However, due to the fact that the research condition of condensation and heat transfer of multi-channel dryer is not exactly the same as the actual working condition, the multi-channel dryer has not been introduced to the market. To address the above problems, this paper presented a rotating test bench which can better simulate the actual working condition of dryer and expounded the working principle of the test bench, as well as the design and calculation of rotary device of the test bench. Finite element analysis software was used to analyze the stress on the dryer channel. In order to avoid resonance problems, modal numerical analysis was conducted on the test bench, which provided experimental conditions for the further study of multi-channel dryer.
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A Novel Approach to Cloning and Expression of Human Thymidylate Synthase
Lv, Ying-Tao,Du, Pei-Juan,Wang, Qiao-Yan,Tan, Yuan,Sun, Zong-Bin,Su, Zhong-Liang,Kang, Cong-Min Asian Pacific Journal of Cancer Prevention 2013 Asian Pacific journal of cancer prevention Vol.14 No.12
Thymidylate synthase (TS) catalyzes the transfer of a methyl group from methylenetetrahydrofolate to dUMP to form dTMP. It is a primary target in the chemotherapy of colorectal cancers and some other neoplasms. In order to obtain pure protein for analysis of structure and biological function, an expression vector TS-pET28b (+) was constructed by inserting wild-type human thymidylate synthase (hTS) cDNA into pET28b (+). Then an expression strain was selected after transformation of the recombined plasmid into Rosetta (DE3). Fusion protein with His-tag was efficiently expressed in the form of inclusion bodies after IPTG induction and the content was approximately 40.0% of total bacteria proteins after optimizing expression conditions. When inclusion bodies were washed, dissolved and purified by Ni-NTA under denatured conditions, the purity was up to 90%. On SDS-PAGE and West-blotting, the protein band was found to match well with the predicted relative molecular mass-36kDa. Bioactivity was 0.1 U/mg. The results indicated that high-level expression of wild-type hTS cDNA can be achieved in prokaryotes with our novel method, facilitating research into related chemotherapy.
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The Mixed Kernel Function SVM-based Point Cloud Classification
Chao Chen,Xiaomin Li,Abdelkader Nasreddine Belkacem,Zhifeng Qiao,Enzeng Dong,Wenjun Tan,Duk Shin 한국정밀공학회 2019 International Journal of Precision Engineering and Vol.20 No.5
Measurement and detection of ground information by airborne Lidar are one of the hot topics in the field of intelligent sensing in recent years. This study proposes a new point cloud classification algorithm of Mixed Kernel Function SVM to distinguish different types of ground objects. Firstly, the combined features including the coordinate values, the RGB value, normalized elevation, standard deviation of elevation, and elevation difference of point cloud data were extracted. A mixed kernel function of Gauss and Polynomial was designed. Then, one-versus-rest SVM multiple classifiers was constructed. Finally, the feature of 3D point cloud data was employed to train the SVM classifiers. The overall classification accuracies of test data were 97.69% and 99.13% for two data sets, I and II respectively. In addition, the experimental results have showed that the performance of the proposed method with mixed kernel function SVM was better than standard SVM method with Gaussian kernel function and polynomial kernel function only, which demonstrates the effectiveness of the proposed method.
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