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        Deep desulfurization of model oil by photocatalytic air oxidation and adsorption using Ti(1−x)MxO2 (M=Zr, Ce)

        Wei Zhang,Xin Li,Hong Wang,송영지,Shenghong Zhang,Cuiqing Li 한국화학공학회 2017 Korean Journal of Chemical Engineering Vol.34 No.12

        Deep desulfurization of model oil by photocatalytic air oxidation and adsorption using Ti(1−x)MxO2 (M=Zr, Ce) was investigated. Ti(1−x)MxO2 (M=Zr, Ce) was prepared by urea gelation/co-precipitation method, and characterized by N2 adsorption, XRD and UV-vis spectra. UV irradiation greatly enhanced the adsorptive capacity and selectivity of TiO2-ZrO2 for organosulfur in model oil because organosulfur compounds were first photocatalytically oxidized to sulfoxides and sulfones over TiO2-ZrO2, which were then selectively adsorbed on the bifunctional material due to much higher polarities of generated sulfoxides and sulfones. The Ti/Zr molar ratio and calcination temperature were optimized to 5 : 5 and 500 oC with the sulfur removal of 99.6% after reaction for 2 h under UV irradiation. After adding 25 wt% toluene into model oil, the sulfur removal could still reach 97.2% after reaction for 7 h. TiO2-ZrO2 could be well regenrated by washing with acetonitrile followed by thermal treatment in air.

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        Risk factors associated with impaired ovarian reserve in young women of reproductive age with Crohn’s disease

        ( Yue Zhao ),( Baili Chen ),( Yao He ),( Shenghong Zhang ),( Yun Qiu ),( Rui Feng ),( Hongsheng Yang ),( Zhirong Zeng ),( Shomron Ben-horin ),( Minhu Chen ),( Ren Mao ) 대한장연구학회 2020 Intestinal Research Vol.18 No.2

        Background/Aims: Crohn’s disease (CD) primarily affects young female adults of reproductive age. Few studies have been conducted on this population’s ovarian reserve status. The aim of study was to investigate potential risk factors associated with low ovarian reserve, as reflected by serum anti-Müllerian hormone (AMH) in women of reproductive age with CD. Methods: This was a case-control study. Cases included 87 patients with established CD, and healthy controls were matched by age, height and weight in a 1:1 ratio. Serum AMH levels were measured by enzyme-linked immunosorbent assay. Results: The average serum AMH level was significantly lower in CD patients than in control group (2.47±2.08 ng/mL vs. 3.87±1.96 ng/mL, respectively, P<0.001). Serum AMH levels were comparable between CD patients and control group under 25 years of age (4.41±1.52 ng/mL vs. 3.49±2.10 ng/mL, P=0.06), however, serum AMH levels were significantly lower in CD patients over 25 years of age compared to control group (P<0.05). Multivariable analysis showed that an age greater than 25 (odds ratio [OR], 10.03; 95% confidence interval [CI], 1.90-52.93, P=0.007), active disease state (OR, 27.99; 95% CI, 6.13-127.95, P<0.001) and thalidomide use (OR, 15.66; 95% CI, 2.22-110.65, P=0.006) were independent risk factors associated with low ovarian reserve (serum AMH levels <2 ng/mL) in CD patients. Conclusions: Ovarian reserve is impaired in young women of reproductive age with CD. Age over 25 and an active disease state were both independently associated with low ovarian reserve. Thalidomide use could result in impaired ovarian reserve. (Intest Res 2020; 18:200-209)

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        Creep of stainless steel under heat flux cyclic loading (500-1000°C) with different mechanical preloads in a vacuum environment using 3D-DIC

        Yong Su,Zhiwei Pan,Yongpei Peng,Shenghong Huang,Qingchuan Zhang 국제구조공학회 2019 Smart Structures and Systems, An International Jou Vol.24 No.6

        In nuclear fusion reactors, the key structural component (i.e., the plasma-facing component) undergoes high heat flux cyclic loading. To ensure the safety of fusion reactors, an experimental study on the temperature-induced creep of stainless steel under heat flux cyclic loading was performed in the present work. The strains were measured using a stereo digital image correlation technique (3D-DIC). The influence of the heat haze was eliminated, owing to the use of a vacuum environment. The specimen underwent heat flux cycles (500°C-1000°C) with different mechanical preloads (0 kN, 10 kN, 30 kN, and 50 kN). The results revealed that, for a relatively large preload (for example, 50 kN), a single temperature cycle can induce a residual strain of up to 15000 

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        Sintering-resistant Cu/B/Ca/Al2O3 catalysts for durable hydrogenation of sec-butyl acetate to 2-butanol and ethanol

        Peiyong Sun,Haixing Wang,Xueqing Luo,Changbin Jia,Shenghong Zhang,Zhilong Yao 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.74 No.-

        Quaternary Cu/B/Ca/Al2O3 catalyst extrudates were prepared and optimized for hydrogenation of secbutylacetate (SBA) to 2-butanol and ethanol. The rationally designed catalyst with a B/Cu molar ratio of3/1 exhibited an extraordinary resistance to Cu sintering during the reaction over 1000 h, due to theenhanced interaction by B2O3 between copper species and support. The slight loss in activity after thelong-term test, caused mainly by the partial transformation of surface CaO to calcium acetate, could beeasily recovered by calcination and the following reduction treatments, rendering it feasible to apply thecatalyst to the industrial hydrogenation of SBA.

      • KCI등재

        Surgical management of inflammatory bowel disease in China: a systematic review of two decades

        ( Qiao Yu ),( Ren Mao ),( Lei Lian ),( Siew Chien Ng ),( Shenghong Zhang ),( Zhihui Chen ),( Yanyan Zhang ),( Yun Qiu ),( Baili Chen ),( Yao He ),( Zhirong Zeng ),( Shomron Ben-horin ),( Xinming Song 대한장연구학회 2016 Intestinal Research Vol.14 No.4

        Background/Aims: The past decades have seen increasing incidence and prevalence of inflammatory bowel disease (IBD) in China. This article aimed to summarize the current status and characteristics of surgical management for IBD in China. Methods: We searched PubMed, Embase, and Chinese databases from January 1, 1990 to July 1, 2014 for all relevant studies on the surgical treatment IBD in China. Eligible studies with sufficient defined variables were further reviewed for primary and secondary outcome measures. Results: A total of 74 studies comprising 2,007 subjects with Crohn`s disease (CD) and 1,085 subjects with ulcerative colitis (UC) were included. The percentage of CD patients misdiagnosed before surgery, including misdiagnosis as appendicitis or UC, was 50.8%±30.9% (578/1,268). The overall postoperative complication rate was 22.3%±13.0% (267/1,501). For studies of UC, the overall postoperative complication rate was 22.2%±27.9% (176/725). In large research centers (n>50 surgical cases), the rates of emergency operations for CD (P =0.032) and in-hospital mortalities resulting from both CD and UC were much lower than those in smaller research centers (n≤50 surgical cases) (P =0.026 and P <0.001, respectively). Regarding the changes in CD and UC surgery over time, postoperative complications (P =0.045 for CD; P =0.020 for UC) and postoperative in-hospital mortality (P =0.0002 for CD; P =0.0160 for UC) both significantly improved after the year 2010. Conclusions: The surgical management of IBD in China has improved over time. However, the rates of misdiagnosis and postoperative complications over the past two decades have remained high. Large research centers were found to have relatively better capacity for surgical management than the smaller ones. Higher quality prospective studies are needed in China. (Intest Res 2016;14:322-332)

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