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Kim, T.H.,Shibata, T.,Kojima, S.,Shin, D.M.,Hwang, Y.H.,Ko, J.H. Elsevier 2014 CURRENT APPLIED PHYSICS Vol.14 No.7
The vitrification process of racemic RS- and enantiomorphic S-ibuprofen was studied by using Brillouin light scattering and modulated differential scanning calorimetry (DSC). The sound velocity and the attenuation coefficient of both compounds were determined for the first time in the glassy, supercooled liquid and liquid states. The sound velocity and the hypersonic damping were similar between the two ibuprofen pharmaceuticals over the whole investigated temperature range including glassy, supercooled liquid and liquid states. The thermal expansion coefficient of the RS-ibuprofen was smaller than that of the S-ibuprofen, which suggests that the intermolecular force of the former is slightly stronger than the latter. The thermal relaxation times derived from the modulated DSC were consistent with the dielectric relaxation times in both RS- and S-ibuprofens. The fragility index of S-ibuprofen just above the glass transition was determined to be 73, which was smaller compared to the value of RS-ibuprofen, 89. This difference in the fragility indicates that the decrease in the fragility of S-ibuprofen compared to the racemic one may improve its stability of the amorphous state below the glass transition temperature against crystallization.
Measurement of High Energy Neutron Induced Cross Sections for Chromium
S. Sekimoto,T. Utsunomiya,H. Yashima,H. Joto,S. Shibata,K. Ninomiya,D. Satoh,Y. Iwamoto,T. Omoto,R. Nakagaki,N. Takahashi,A. Shinohara,T. Shima,M. Hagiwara,H. Matsumura,K. Nishiizumi,Y. Matsushi,H. Ma 한국물리학회 2011 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.59 No.23
Reaction cross sections for Cr induced by neutrons at 287 MeV were measured by using ^7Li(p,n) reaction at N0 beam line in the Research Center for Nuclear Physics (RCNP), Osaka University. To estimate quasi-monoenergetic neutron-induced cross sections, the Cr sample was irradiated on the two angles of 0° and 30° for the axis of the primary proton beam. Proton-induced reaction cross sections for Cr at 300 MeV were also measured. The measured cross section data in the ^(nat)Cr(n,x) and ^(nat)Cr(p,x) reactions are compared with the literature values and the JENDL high-energy file. Furthermore, those in the ^(nat)Cr(n,x) reactions are also compared with those in the ^(nat)Cr(p,x) reaction.
Effect of Additive Elements on Electrochemical Behavior of Passive Films on Fe-18Cr Alloy
Fujimoto, S.,Umemura, H.,Kurihara, M.,Tsuchiya, H.,Shibata, T. 한국부식방식학회 2002 Corrosion Science and Technology Vol.31 No.1
Electrochemical behaviour of Fe-18Cr-X (X: Al, Si, Ti, Mn, Ni, Cu, Zr, Nb, Mo, and W, 0.5-4 at.%) alloy thin films deposited on Si wafer by ion beam sputtering technique was examined in order to discuss the effect of alloying elements which are completely dissolved in the alloy. Polarisation curves measured in 0.1 krnol m" H2S04 revealed that active dissolution was suppressed by Ni, Nb, Mo, Cu and Ti, but was almost not affected by Al, Si, Mn. Pitting corrosion resistance in acid chloride solutions was extremely improved by Nb, Mo, Ti. On the other hand, Al, Si, Mn exhibited almost no change in pitting potential. Reactivation in sulphuric acid was suppressed by Mo, Nb, Ni, Ti, but not affected or slightly enhanced by Si and Mn. It is noticeable that addition of Nb is especially beneficial for preventing both pitting corrosion and reactivation. The corrosion behaviour of Fe-Cr alloys are discussed in terms of the stability of passive film which is influenced by minute additives incorporated in the film.
SAWADA-SATOH, S.,AKIYAMA, K.,NIINUMA, K.,NAGAI, H.,KINO, M.,D'AMMANDO, F.,KOYAMA, S.,HADA, K.,ORIENTI, M.,HONMA, M.,SHIBATA, K.M. The Korean Astronomical Society 2015 天文學論叢 Vol.30 No.2
We present a kinematic study of the parsec-scale radio jet in OJ 287, one of the most studied BL Lac objects, during ${\gamma}$-ray flares, to explore the relation between parsec-scale radio jet activity and ${\gamma}$-ray emission. The 22-GHz light curve of OJ 287 show three obvious flare events around 2011 May, 2011 October, and 2012 March. The second radio flare occurred during the ${\gamma}$-ray flaring period, and the third radio flare seemed to precede the ${\gamma}$-ray flare by one month. One jet component moved outward with respect to the core component with an apparent superluminal speed (~ 11c) from 2010 November to 2011 November. Then it changed direction, moving apparently inward in 2011 November, when the ${\gamma}$-ray flare occurred. The observed apparent inward motion of the jet at 22 GHz could be caused by a new jet component, unresolved at 22 GHz, in the innermost region.