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- 검색키워드
- 저자 : Ruina Liu (검색결과 4 건)
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Yiqiang Li,Xin Chen,Zheyu Liu,Ruina Liu,Wentao Liu,Han Zhang 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.101 No.-
Polymeric surfactant can simultaneously thicken aquous phase and reduce water–oil interfacial tension(IFT), which makes it present a great application prospect in the oilfield taword enhanced oil recovery(EOR). There are two kinds of polymeric surfactant with different molecular structures are commonlyused to realize the salt resistance, thermal endurance and shear resistance. However, the influence ofthe molecular structure of polymeric surfactant on their properties related on EOR are not well understood. In the work, we synthesized two kinds of polymeric surfactants with different molecular structurewhich respectively named intermolecular association molecule (IAM) and rigid chain molecule (RCM). Their physico-chemical properties, porous media transportation and EOR are compared with a series ofexperiments. It is found that the hydrodynamic characteristic sizes and retention of IAM are higher thanthose of RCM via the membrane filtration test and nuclear magnetic resonance (NMR) scan. These featuresmake IAM have a larger resistance factor and residual resistance factor than RCM and hydrolyzedpolyacrylamide (HPAM) in the same viscosity. Compare to HPAM with shear thinning, RCM presents aNewtonian fluid region and IAM presents a shear thickening region when the shear rate is lower than1 s 1. The spatial structure of IAM can pack oil drop into its network, which make it easy to form oilin-water-in-oil (O/W/O) emulsions. Moreover, the concentration and water–oil ratio (WOR) rarely affectthe stability of IAM emulsions once the intermolecular association generated. The increamental oil recoveryfactor of IAM is 17.5% after water flooding in the three-layer core flooding experiments with the permeabilityof 500 mD, 1500 mD and 3000 mD at 55℃, which is higher than that of 14.5% for RCM and11.4% for HPAM.
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Meng Xin,Tian Jing,Liu Shuai,Li Ruina,Sun Jian,Liu Wenjun 한국자동차공학회 2023 International journal of automotive technology Vol.24 No.3
To evaluate the influence of polyoxymethylene dimethyl ethers (PODE) on particulate matter (PM) chemical features, PM samples emitted from diesel fuel and PODE/diesel blends at volume ratios of 10 %, 20 %, and 30 % (P10, P20, and P30) were characterized using gas chromatography-mass spectrometry, X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectroscopic (FT-IR). Results showed that adding PODE in diesel fuel could increase the proportions of the lower carbon-atom-number components and the contents of oxygen-containing compounds in the soluble organic fractions extracted from PM samples. The ratio of oxygen to carbon (O/C), the functional groups, and the nanostructure of dry soot obtained from XPS showed that the O/C rose as the PODE volume ratio increased. The graphitization degree of dry soot decreased in the order: diesel fuel > P10 > P30 > P20. The relative content of hydroxyl functional groups exhibited the same trend, while the relative content of carbonyl functional groups exhibited an opposite trend with the graphitization degree. Moreover, according to FT-IR, both the branching degree and the relative content of hydrocarbon functional groups of aliphatics are influenced by the graphitization degree of dry soot. A turning point at P20 observed by analysis results above indicated that the chemical characteristics of PM could be affected not only by fuel properties but also by the process of fuel combustion and PM formation.
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Xingfang Xiao,Lipei Ren,Shujun Wang,Qian Zhang,Yawei Zhang,Ruina Liu,Weilin Xu 한국섬유공학회 2020 Fibers and polymers Vol.21 No.9
Luminescent lanthanide metal-organic frameworks (ln-MOFs) is a promising materials for sensing. However,seeking ideal method to scale up in mass production and can be uniform on flexible substrate is still a great challenge. In thisstudy, a novel and efficient process was employed for the fabrication of flexible and environmental copper ion-sensingmaterials using cotton fabric as a substrate. The micro-nanoscale Europium metal-organic frameworks (Eu-MOFs) wasprepared through adding blocking reagent, and then cotton fabric was coated with the Eu-MOFs by hot pressing. The resultsshow that controllable dense micro-nanoscale Eu-MOFs film was coated on the cotton fabric with different dipping and hotpressing times. The method is fast, simple, low-cost and suitable for production. The Eu-MOFs coated cotton fabric exhibitsgood photoluminescent properties. The selective sensing ability of Eu-MOFs coated fabric for Cu2+ over many other metalions (K+, Cd2+, Ca2+, Pb2+, Na+, Zn2+, Ni2+, Mg2+, Al3+ and Co2+) is verified by emission spectra, and by the fact that thefluorescence intensity of the fabric significantly decreased with an increase in the concentration of Cu2+ (10-6-10-1 mol/L). This method provides a new path for the controllable production of MOFs-coated functional textiles for differentapplications, such as anti-counterfeiting, UV-protection, superhydrophobic, and sensing materials in the textile industry.
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