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Highly Efficient Photocatalytic Studies on Bi36 Fe2 O57 Ceramic Synthesized by Chemical Route
Manish Kumar Verma,Vinod Kumar,Upakar Patel,Vishnu Shankar Rai,Anup Kumar,Arup Kumar De,Aditya Kumar Prajapati,Dinesh Prajapati,Kedar Sahoo,Tapas Das,N. B. Singh,K. D. Mandal 한국전기전자재료학회 2023 Transactions on Electrical and Electronic Material Vol.24 No.5
Bi36 Fe2 O57 (BFO) polycrystalline ceramic was synthesized by economical chemical route. The single-phase formation of BFO ceramic was confirmed by powder X-ray diffraction studies. Nanosized formation of BFO ceramics established by XRD and TEM analysis. The bimodal distribution of grain size is observed with size ranging from 50 to 600 nm. It observed that the Bi36 Fe2 O57 photocatalyst exhibited higher catalytic activity for the degradation of Methylene Blue (MB) under visible-light irradiation The oxidation state of elements present in the BFO ceramic, was confirmed by XPS studies. The pseudocapacitive nature of BFO ceramic was observed by cyclic Voltammetry. The dielectric constant of BFO ceramic was found 375 at 1 kHz at 300 K. The dielectric loss was found 0.51 at 100 kHz and 300 K.
Kumar Arvind,Kumar Manish,Chandra Sati Prakash,Srivastava Manish Kumar,Ghosh Surajit,Kumar Shiv 한국물리학회 2021 Current Applied Physics Vol.32 No.-
Control on the size of copper oxide (CuO) in the nano range is a highly motivating approach to study its multifunctional nature. The present investigation reports a sol-gel derived Ni doped CuO nanoparticles (Cu1- xNixO). Rietveld refinement of the XRD spectra confirms the formation of single monoclinic phase of Cu1-xNixO nanoparticles having crystallite size within the range of 19–21 nm. Raman spectra show the presence of characteristics Raman active modes and vibrational bands in the Cu1-xNixO samples that corroborate the monoclinic phase of the samples as revealed by refinement of XRD data. The estimated band gap of pure CuO is found to be ~1.43 eV, which decreases with the increase of dopant concentration into CuO matrix. This result is in line with estimated crystallite size. Magnetization curves confirm the weak ferromagnetic nature of Cu1-xNixO nanoparticles which reveal the DMS phase. This weak magnetic nature may be induced in the samples due to the exchange interaction between the localized magnetic d-spins of Ni ions and carriers (holes or electrons) from the valence band of pristine CuO lattice. Replacement of Cu+2 by Ni+2 ions into the host CuO lattice induces the magnetization. The quantified value of squareness ratio (S < 0.5) confirms the inter-grain magnetic interactions in the Cu1-xNixO nanoparticles which is also the reason of weak induced magnetization.
Pavan Kumar,Manish Kumar Chatli,Nitin Mehta,Om Prakash Malav,Akhilesh Kumar Verma,Devendra Kumar,Manjeet Rathour 한국축산식품학회 2018 한국축산식품학회지 Vol.38 No.3
The present study was undertaken to assess the efficacy of sapota powder (SP) as natural preservatives and its better utilization in food processing with the incorporation of various levels of SP (2, 4, and 6%) by replacing lean meat. Based on the sensory attributes, pork patties with 4% incorporation of SP was found optimum and selected for further storage studies with control under aerobic and modified atmosphere packaging at refrigeration temperature (4±1℃) for 42 days for assessing its antioxidant and antimicrobial efficiency. During entire storage period, indicators of lipid oxidative parameters such as thiobarbituric acid reactive substances (TBARS), free fatty acids (FFA) and peroxide value (PV) followed an increasing trend for control as well as treated products; however, treated product showed a significantly (p<0.05) lower value than control. A significantly lower (p<0.05) microbial count in treated patties than control was noted during entire storage. The sensory attributes are better retained in treated product as compared to control and even on 42nd day, overall acceptability of treated patties was found to fall in moderately acceptable category (5.95 in aerobic packets and 5.91 in modified atmosphere packets). Therefore SP has potential to enhance antioxidant and antimicrobial properties of pork patties during storage.
Kumar, Manish,Javid, Amjed,Han, Jeon Geon American Chemical Society 2017 Langmuir Vol.33 No.10
<P>Surface energy (SE) is the most sensitive and fundamental parameter for governing the interfacial interactions in nanoscale carbon materials. However, on account of the complexities involved of hybridization states and surface bonds, achieved SE values are often less in comparison with their theoretical counterparts and strongly influenced by stability aspects. Here, an advanced facing-target pulsed dc unbalanced magnetron-sputtering process is presented for the synthesis of undoped and H/N-doped nanocrystalline carbon thin films. The time-dependent surface properties of the undoped and H/N-doped nanocrystalline carbon thin films are systematically studied. The advanced plasma process induced the dominant deposition of high-energy neutral carbon species, consequently controlling the intercolumnar spacing of nanodomain morphology and surface anisotropy of electron density. As a result, significantly higher SE values (maximum = 79.24 mJ/m(2)) are achieved, with a possible window of 79.24-66.5 mJ/m(2) by controlling the experimental conditions. The intrinsic (size effects and functionality) and extrinsic factors (atmospheric exposure) are resolved and explained on the basis of size-dependent cohesive energy model and long-range van der Waals interactions between hydrocarbon molecules and the carbon surface. The findings anticipate the enhanced functionality of nanocrystalline carbon thin films in terms of selectivity, sensitivity, and stability.</P>
Quality Characteristics of Low-fat Ground Pork Patties Containing Milk Co-precipitate
Kumar, Manish,Sharma, B.D. Asian Australasian Association of Animal Productio 2003 Animal Bioscience Vol.16 No.4
The optimum level of fresh granulated low-calcium (0.2%) skim milk co-precipitate, as fat substitute in low-fat ground pork patties was determined on the basis of physico-chemical, cooking and sensory properties. Low-fat ground pork patties (<10% total fat), formulated with 15 per cent water, 4 per cent added fat, 1.5 per cent salt and 4-10 per cent milk co-precipitate, were evaluated for proximate composition, cooking characteristics and compared with control patties with 15 % added fat. The moisture and protein content of raw and cooked low-fat patties were significantly (p<0.05) higher than control. The incorporation of milk co-precipitate in low-fat patties improved cooking yield, fat and moisture retention and reduced shrinkage. The sensory properties of low-fat patties were comparable with control patties. The overall acceptability of low-fat patties formulated with 7% milk co-precipitate was significantly (p<0.05) higher than patties with 10% level and non-significantly (p<0.05) higher than low-fat patties containing 4% milk co-precipitate and control. Instrumental Texture Profiles of developed low-fat patties and control patties were comparable with slight increases in hardness and gumminess of the low-fat product. The developed low-fat ground pork patties (7% milk co-precipitate) had lower TBA values, better microbiological and sensory refrigerated storage stability than high-fat control patties packaged in air permeable films for 21 days.
Techniques for Formulation of Nanoemulsion Drug Delivery System: A Review
Manish Kumar,Ram Singh Bishnoi,Ajay Kumar Shukla,Chandra Prakash Jain 한국식품영양과학회 2019 Preventive Nutrition and Food Science Vol.24 No.3
Nanoemulsion drug delivery systems are advanced modes for delivering and improving the bioavailability of hydrophobic drugs and the drug which have high first pass metabolism. The nanoemulsion can be prepared by both high energy and low energy methods. High energy method includes high-pressure homogenization, microfluidization, and ultrasonication whereas low energy methods include the phase inversion emulsification method and the self-nanoemulsification method. Low energy methods should be preferred over high energy methods as these methods require less energy, so are more efficient and do not require any sophisticated instruments. However high energy methods are more favorable for food grade emulsion as they require lower quantities of surfactant than low energy methods. Techniques for formulation of nanoemulsion drug delivery system are overlapping in nature, especially in the case of low energy methods. In this review, we have classified different methods for formulation of nanoemulsion systems based on energy requirements, nature of phase inversion, and self-emulsification.
Mapping AUTOSAR Methodology to COTS-based V-Process Model
Manish Kumar,Jiyong Park,Seongsoo Hong 한국자동차공학회 2009 한국자동차공학회 부문종합 학술대회 Vol.2009 No.4
AUTOSAR is an automotive software platform standard created by European automobile manufacturers and their first tier suppliers to standardize software infrastructure. This standard has reached a stage where it can be exploited by the industries. But to exploit the standard, we need a well-defined development process model suited for AUTOSAR. In this paper, we propose a complete software development process model, keeping in mind the existing best practices of the industries. We have also used the COTS-based development since it reduces development time and ensures reliability.
Manish Kumar,Ashwani Kumar,K.S Sandhu 보안공학연구지원센터 2016 International Journal of Hybrid Information Techno Vol.9 No.10
Renewable sources integration is gaining importance in electrical utilities all over the world. The liberization of power sector in competitive regime, the share of renewable energy sources is increasing and it is essential to carry out the impact of clean energy on the system performance In this paper, analysis has been carried out with the PV-based distribution generation in the power system network. A Mixed Integer Nonlinear Programming (MINLP) approach has been utilized for determining optimal location and number of distributed generators considering minimization of fuel cost of conventional and solar PV power. The pattern of nodal real and reactive power prices have been obtained with and without PV integration. The results are also obtained for, loss reduction, fuel cost saving and voltage profile. The impact of different load models as PQ load and Zip load model has been studied. The proposed MINLP based optimization approach has been applied for IEEE24 bus reliability test system.