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Assessment of Rheological and Piezoresistive Properties of Graphene based Cement Composites
Sardar Kashif Ur Rehman,Zainah Ibrahim,Mohammad Jameel,Shazim Ali Memon,Muhammad Faisal Javed,Muhammad Aslam,Kashif Mehmood,Sohaib Nazar 한국콘크리트학회 2018 International Journal of Concrete Structures and M Vol.12 No.6
The concrete production processes including materials mixing, pumping, transportation, injection, pouring, moulding and compaction, are dependent on the rheological properties. Hence, in this research, the rheological properties of fresh cement paste with different content of graphene (0.03, 0.05 and 0.10% by weight of cement) were investigated. The parameters considered were test geometries (concentric cylinders and parallel plates), shear rate range (300–0.6, 200–0.6 and 100–0.6 s<SUP>−1</SUP>), resting time (0, 30 and 60 min) and superplasticizer dosage (0 and 0.1% by weight of cement). Four rheological prediction models such as Modified Bingham, Herschel–Bulkley, Bingham model and Casson model were chosen for the estimation of the yield stress, plastic viscosity and trend of the flow curves. The effectiveness of these rheological models in predicting the flow properties of cement paste was verified by considering the standard error method. Test results showed that the yield stress and the plastic viscosity increased with the increase in graphene content and resting time while the yield stress and the plastic viscosity decreased with the increase in the dosage of superplasticizer. At higher shear rate range, the yield stress increased while the plastic viscosities decreased. The Herschel–Bulkley model with the lowest average standard error and standard deviation value was found to best fit the experimental data, whereas, Casson model was found to be the most unfitted model. Graphene reduces the flow diameter and electrical resistivity up to 9.3 and 67.8% and enhances load carrying capacity and strain up to 16.7 and 70.1% of the composite specimen as compared with plain cement specimen. Moreover, it opened a new dimension for graphene-cement composite as smart sensing building construction material.
Kashif Akram,안재준,윤성란,권중호 한국식품과학회 2012 Food Science and Biotechnology Vol.21 No.4
Gamma-irradiated (0, 1, and 10 kGy) ketchup (KTP), barbeque sauce (BBQ), and sweet chili sauce (SWC) were identified using photostimulated-luminescence (PSL) and thermoluminescence (TL) analysis and characterized for physical properties like Brix, consistency, and color. PSL-based screening showed negative results for all nonirradiated samples, while intermediated results were found for irradiated samples. Routine density separation method for mineral extraction provided better TL results; however,alkaline and acid hydrolysis could ease the process with acceptable results. A slight decrease in consistency of all the samples was observed. Brix of KTP remained unchanged,while increase of same was obvious in BBQ and SWC following irradiation. The Hunter L* value of the γ-irradiated sauces decreased except SWC samples, and the a* and b* values showed a general increase compared to the non-irradiated samples. The studied methods have potential to successfully identify and characterize the irradiated sauces for technical and regulatory requirements.
Kashif Ghafoor,Ji Eun Jung,Yong Hee Choi 한국식품과학회 2008 Food Science and Biotechnology Vol.17 No.1
The effect of gellan (GE), xanthan (XA), and λ-carrageenan (LC) on the viscosity, sedimentation, ellagic acid content, and turbidity of grape ‘Campbell Early’ juice (CEJ) was investigated. CEJ samples with 0.15% each of GE, XA, and LC were tested for the above variables after 0, 5, 10, and 20 days of storage. The samples containing GE (0.15%) showed the least amount of sediment formation, the lowest ellagic acid content and turbidity, and a rise in viscosity. Sedimentation in CEJ decreased with increased viscosity due to the addition of gums which also limited the ellagic acid content and turbidity. GE was the most effective additive for the stabilization of CEJ.
Kashif Shaheen Amna,So Yeon Park,Min Choi,Sang Yeon Kim,Ah Young Yoo,Jae Kweon Park 한국해양바이오학회 2018 한국해양바이오학회지 Vol.10 No.1
The aim of this study is to elucidate the biochemical properties of manno-oligosaccharides (MOS) hydrolyzed by extracellular enzyme of Bacillus N3. We strived to characterize the biochemical properties of MOS since N3 can effectively hydrolyzed natural polymannans such as galactomannan (GM) and konjac (glucomannan, KM), respectively. The hydrolysis of GM and KM was applied by the strain N3 in terms of reducing sugars and the highest production of reducing sugars was estimated to be about 750 ㎎/L and 370 ㎎/L respectively, which were quantified after 7 days of cultivation in the presence of both substrates. Hydrolysates derived from the hydrolysis of KM showed the significant antioxidant activity based on DPPH and ABTS radical scavenging activity with increasing of tyrosinase inhibitory activity. On the other hand, hydrolysates derived from the hydrolysis of GM showed only ABTS radical scavenging activity without showing significant changes on tyrosinase inhibitory activity. Our data suggest that those biological characteristics may be depend on the primary structure and the size of MOS, which may be useful as potent additives for diet foods.
Kashif Akram,안재준,김귀란,권중호 한국식품과학회 2012 Food Science and Biotechnology Vol.21 No.2
Photostimulated luminescence (PSL), thermoluminescence (TL), and electron spin resonance (ESR)analyses were performed to identify γ-irradiated (0, 1,2,and 3 kGy) fresh mushrooms (oyster, king oyster, and shiitake mushrooms) during storage at 5oC. PSL analysis gave negative results [<700 photon counts (PCs)] for the nonirradiated and intermediate (700-5,000 PCs) or positive results (>5,000 PCs) for the irradiated samples. The shape,intensity, and occurrence of TL glow curve in a typical temperature range (150-250oC) along with TL ratio (TL1/TL2) provided sufficient information to confirm the irradiation history of samples. Storage resulted in a negligible fading effect on PSL and TL characteristics. X-ray diffraction analysis showed the abundance of feldspar and quartz minerals in the separated dust from mushrooms. In detailed ESR analysis employing different sample pre-treatments,all samples were silent for radiation-specific ESR signals giving only a central signal (g=2.005) that showed an increase in intensity upon irradiation.