백금 담지 카본블랙 촉매 제조 및 활성조사

김종범,이무성,이완진,양갑승,서곤,김종호 全南大學校 觸媒硏究所 2002 觸媒硏究 論文集 Vol.23 No.-

Platinum catalysts supported on carbon were prepared by using various method. The particle size distribution of loaded platinum was examined using transmission electron microscope, and that was discussed relatively to the oxidation treatment of carbon black and loading method of platinum. In addition, the relationship between its particle size distribution and catalytic activities in the deep oxidation reaction of carbon monoxide and the reduction removal of dissolved oxygen by hydrazine. The number of functional groups on carbon black largely increased by the oxidation treatment with nitric acid compared to that with air or hydrogen peroxide. The large number of functional groups were effective for homogeneous loading of platium, dispersing highly homogeneous platinum particles of 2∼3 nm in a diameter by the methanol reduction method. On the other hand, a large amount of platinum could be loaded on carbon balck using an impregnation method, but the particle size distribution of platinum was poor in homogeneity. Platinum could be dispersed with extremely small particles using on ion exchange method, but the loading amount of platinum was very small. The activities of Pt/VX catalysts in the oxidation reaction of carbon monoxide and the redution of dissolved oxygen strongly varied with the number of platinum atoms exposed, regardless of the particle size, indicating that the highest catalytic activity was obtained on the Pt/VX catalyst prepared using the methanol reduction method due to the high dispersion and large loading of platinum.

大都市 都心部의 交通混雜에 따른 混雜費用의 適用方案에 관한 基礎的 硏究

金甲洙,李光鎬 嶺南大學校 環境問題硏究所 1998 環境硏究 Vol.17 No.2

요약문 대도시 지역은 교통시절에 대한 수급불균형으로 인하여 심각한 도시교통문제가 발생하고 있으며, 특히 교통혼잡으로 인한 경제적·사회적 손실이 심화되고 있는 실정이다. 따라서, 본 연구에서는 TDM 기법 중 자가용이용을 억제시키기 위한 도심진입부과금에 대하여 CBD로 유입하는 자가용승용차 중 백화점을 이용하는 운전자를 대상으로, 설문조사를 통한 교통혼잡비용에 따른 운전자들의 행동과 의식에 대한 특성을 파악하고, 또한 운전자가 느끼는 자가용 이용의 포기한계에 대한 걱정 도심진입부과금을 책정하고, 포기한계에 따른 대체교통수단 선택의 특성들을 경제이론을 적용하여 분석하였다. 그 결과는 첫째, 교통수요 억제 측면에 있어서의 TDM 효과는 2천원과 4천원을 혼잡요금으로 부과했을 때가 많은 수요를 억제시켜 가장 적절한 것으로 나타났으며, 둘째, 전환율 측면에서의 TDM 파급효과는 대표적인 대중교통수단인 버스와 지하철로의 전환이 가장 많이 이루어지는 것으로 분석되었으며, 셋째, 한 교통수단만을 고려하여 그 교통수단의 전환율을 높이기 위한 혼잡요금의 인상에 따른 고정된 교통수단의 전환율을 높이기 위한 혼잡요금의 인상에 따른 고정된 교통수단의 전환율 변화를 살펴보았다. Abstract This study analyzed on characterisics of driver′s behavior and consciousness by questionnaire which intended for driver of a passenger car using for private in CBD (Central Bussiness District), on charging for urban area influx which have being researched recent actively, as one of TDM (Transportation Demand Management). It was also appropriated a charge for urban area influx to consciousness of by themselves, to a limit which abandon a passenger car using for private at a certain measure of the charge. The major results of this study can be summarized as follows : On the side of traffic demand restraint, the effect of TDM was appropriated by restraining 20∼30 percentages or more than 40 percentages on a passenger car using for private when congestion pricings was 2,000 won or 4000 won In the case of diversion rate, it was found that a derivative effect of TDM was appeared highly in diversion to bus and subway as represetative of public transportation. In considering only one traffic modes (suppose others are fixed), to increase diversion rate of the traffic modes, change of fixed traffic modes which caused by raising of congestion pricings was analyzed. The result of that case study can ve summarized as follows : At first, It was shown that two traffic modes represent by substitutional relation on considering only bus traffic modes. Secondly, It was shown that two traffic modes represent by supplementary relation. on considering only subway traffic modes

지역경제의 생태학적 평가에 관한 연구 : 낙동강 유역을 중심으로 The case of Nakdong River region, Korea

윤갑식,김홍배,최세호 漢陽大學校 環境工學硏究所 1998 環境科學論文集 Vol.19 No.-

본 연구에서는 수질오염이 산업폐수, 가계하수 그리고 토지유출수의 3가지 요소에 의해서 발생된다는 가정을 바탕으로 환경수준과 경제활동 사이에 존재하는 상반관계를 낙동강유역을 대상으로 분석하였다. 분석에는 다지역 투입산출모형이 이용되는데 이때의 다지역 투입산출표는 행정구역이 아닌 유역권을 기준으로 작성되었고 이를 바탕으로 목표년도(2010)의 낙동강 유역 수질수준을 예측하였다. 또한 수질을 개선하기 위해 두가지 정책 즉, 자체처리시설을 증설하는 정책과 종말처리장을 증설하는 정책을 제시하고 이것을 정책에 소요되는 비용과 정책효과 측면에서 평가하여 지역별 가장 효율적인 정책을 제시하였다. 마지막으로 GRDP에서 수질오염에 의해 발생하는 환경비용을 고려한 ERDP(환경적으로 조정된 지역내 순생산)를 제시하였다. This paper analyzes the trade-off relationship between environmental quality and economic activity, specifically focusing on water pollution of Nakdong-river region, Korea. The analysis begins with the assumption that water is contaminated by three pollutive sources, production sector, household sector and land surface water. Three-region input-output table is constructed based on the Catch basin area not administrative area for analysis. Water polluting level of Nakdong river region in the year 2010 is forecasted taking into account the pollutive sources. Also, two types of environmental policies are presented and assessed in terms of pollution abatement costs and effects. Finally, the interest in this paper stems from recent advances in so-call EDP(environmentally adjusted net domestic product) which reflects environmental costs in GDP. The paper attempts to calculate ERDP(environmentally adjusted net regional domestic product) by incorporating EDP into regional level with the assumption that environmental costs are represented by water pollution abatement costs.

신경회로망을 이용한 한글모음인식에 관한 연구

최승호,김자룡,이기영,최갑석 明知大學校 産業技術硏究所 1989 産業技術硏究所論文集 Vol.8 No.-

In this paper, Recognition of HANGUL Vowel using a neural network is studied. In general, Back-propagation is applied for the speech recognition, but has too much computational time for learning. The method using peak information of speech signal is used for the purpose of reduction of computational time. The speech spectrum of a vowel consists of the sixteen frame and a frame is divided by the sixteen hand and binary code 1,0 is used as input data corresponding to whether peaks exist or not, respectively, on each band in frequency spectrum. The experimental result show that the learning number is reduced remarkably and the recognition rate is improved according to increasing ratio of learning and unlearning data.

중범위 이상 회전근 개 파열 환자의 관절경적 봉합술 : 견봉성형술의 역할 The Role of Acromioplasty

이광원,김갑중,이항호,김병성,김하용,최원식 대한견.주관절학회 2003 大韓肩.주關節學會誌 Vol.6 No.2

Thioacetamide에 의한 BALB/c 마우스 간의 시간별 약물대사효소 억제 양상 : A Time-Course Study

이정운,고우석,김갑호,배연경,하현정,한상섭,천영진,정태천 영남대학교 약품개발연구소 2001 영남대학교 약품개발연구소 연구업적집 Vol.11 No.-

Thioacetamide is a potent hepatotoxicant which requires metabolic activation by cytochrome P450s (P450s) for toxicity. In the present study, the elevation kinetic of serum alanine aminotransferase (ALT) and aspartate aminotransferase (AST) activities by thioacetamide treatment was investigated in male BALB/c mice. Inaddition, the inhibitory effects of thioacetamide on liver microsomal P450 enzymes were further investigated. Thioacetamide at 100 mg/kg/ was treated intraperitoneally for 6, 12, 24, 36, 48 and 72 hr. The blood was collected at the designated time for assaying the serum enzyme activities. To determine the P450 isozyme-specific activities. ethoxyresorufin O-deethylase (EROD), methoxyresorufin O-demethylase (MROD), and benzyloxyresorufin O-debenzylase (BROD) activities were determined for P450 1A1, 1A2 and 2B1, respectively, in liver microsomal fractions. The activities of ALT and AST were started to be elevated 6 hr after thioacetamide treatment andreached the maximun at 36 hr after the treatment. The elevated activities were dramatically recovered at 72 hr. The microscopic exmination of the liver specimen also showed a similar profile of hepatotoxicity. All P450-associated enzyme activities were time-dependently inhibited by the treatiment with thioacetamide. The maximum inhibition of P450 enzymes was observed 36 hr after the treatment. Because the inhibition of P450 enzymes by thioacetamide was time-dependent, our present results suggest that thioacetamide might inhibit P450 enzymes in mechanism-based inactivation.

熱量組成에 따른 白鼠의 Sodium 代謝에 關한 硏究

李琦烈,金甲英,申泰善 연세대학교 대학원 1974 延世論叢 Vol.11 No.1

Albino male rats, weighing from 290-300g, were divided into four dietary groups according to the amounts of carbohydrate, protein and fat in the basal diet. Diet I was a control diet, Diet II, low protein, Diet III, low protein and low fat diet and Diet IV, low fat diet. All rats were provided with 3% sodium chloride solution. The experiment was carried out for 9 weeks during which time the body weight, the food intake, and 3% sodium chloride solution consumption were determined. At the 9th week, the balance study was carried to the analysis of sodium and potassium and other chemical studies. The rats were sacrificed and the kidney, adrenal, liver and spleen were measured, and observed changes of the pathological tissue in the kidney and adrenal. The results were summarized as follows: 1) There was no significant difference found between the experimental Diets II, III, and IV for growth rate, food intakes. 2) The concentration of sodium and potassium in the blood were within the normal range in all diets. 3) The amount of sodium chloride in the urine was signficantly greater in Diets II, III and IV than in the control diet. Diets II, III, IV had a largey amount of sodium solution consumption. 4) Observation of pathological tissue in the experimental diets found a cell proliferation in the glomerlulus of the kidney, while such change was not found in the control diet.

안면경련의 침구치료에 대한 문헌적 고찰

조현석,장준혁,김경호,윤종화,김갑성 동국대학교 한의학연구소 1999 東國韓醫學硏究所論文集 Vol.7 No.2

편측 안면경련은 편측 안면근의 불수의적, 간헐적 수축으로서 심할 경우 안면 근력 약화 및 강직현상등이 나타나기도 하는 질환이다. 서양의학에서 편측 안면경련의 병태생리에 대한 가설은 크게 두가지로 대별되는데, 첫째는 중추성 가설(핵가설)이고, 둘째는 말초성가설이다. 치료방법은 대별하여 내과적 치료와 외과적 치료의 나눌 수 있는데, 외과적 치료가 다양하게 시행되어 왔으며, 근래에는 두개강내 미세혈관 감압술이 시행되고 있다. 韓醫學에서는 眼瞼痙攣울 眼胞振跳, 胞輪振跳라고 하고, 眼眉跳라고도 하며, 그 외 目瞬, 目跳, 眼皮跳 등의 이름으로도 불리운다. 外因으로는 風邪가 經絡에 侵入하는 것이며, 內因으로는 肝血虛한 中의 風邪가 兼하기 때문이다 따라서, 국부경혈 자침과 함께 장부변증에 따라 肝, 膽經 경혈의 사용과 합께 耳鍼T의 시술이 유용할 것으로 사료된다. Hemifacial spasm including blepharospasm is characterized by spontaneous clonic and tonic muscle spasm on one side of the face with synkinesis. Though the etiology of hemifacial spasm is not entirely understood, generally there are two. One is nuclear hypothesis and the other is peripheral hypothesis. There are two ways of treatment of hemifacial spasm. One is internal medicine and the other is operative method. In oriental medicine, hemifacial spasm is very similar to diseases such as Anpojindo(眼胞振跳), Poryunjindo(胞輪振跳), or Anmido(眼眉跳) in symptoms. The diseases such as Anpojindo(眼胞振跳), Poryunjindo(胞輪振跳), Anmido(眼眉跳) is related to the function of liver(肝) and risk factors are regarded as Pung(風). The acupuncture therapy of hemifacial spasm is based on Liver meridian(LV), Gallbladder meridian(GB), And ear-acupuncture is recommended as a good method for hemifacial spasm.

백일해 백신이 Streptozotocin 유발성 당뇨백서의 당대사에 미치는 영향

박상기,문경래,박춘호,김갑승,박영봉,이병래,양남웅 朝鮮大學校 附設 醫學硏究所 1991 The Medical Journal of Chosun University Vol.16 No.1

Streptozotocin(STZ) may produce a permanent form of insulin-dependent diabetes (IDD) in experimental animals. This STZ-induced diabetes has become an useful model to study the pathogenesis of IDD in man primarily because it approximate clinical findings and also because it lends itself easily to controlled manipulation. The diabetogenic activity of STZ, however, is known to be modified by several agents such as nicotinamide, diazoxide, adrenergic blockers and pertussis vaccine (PV). The present study was undertaken to observe the protective effect of PV or boiled pertussis vaccine(bPV; incubating the PV at 80℃ for 30 minutes) against the development of IDD induced by STZ in young rats, and also the effect of PV on the activities of glycolytic & gluconeogeneic enzymes in both liver and muscle of rat. PV at a dose of 1.2×10^(10) microorganism was administrated intrapntoneally on 3days before & 7days after a single injection of STZ (GO㎎/㎏ body wt). The blood glucose and insulin levels were measured at 1st wk, 2nd wk, 4th wk, 6th wk and 8th wk after STZ injection, and the enzyme activities were exemined at 8th wk. The following results were obtained. 1. No significant difference was noted in blood glucose levels between STZ group and STZ+PV or STZ+bPV groups (P>0.05). 2. Blood insulin levels in STZ group decreased significantly from 2nd wk(P<0.05). Compared with STZ group, blood insulin levels in STZ+PV & STZ+bPV groups were higher, but not a significant value except at 2nd wk in STZ+PV grouP (P<0.05). 3. Compared with STZ group, hepatic glycolytic enzyme activities were significantly increased in STZ+PV or STZ+bPV groups, and muscular glycolytic enzyme activities were significantly increased in STZ+PV or STZ+bPV groups. 4. Compared with STZ group, hepatic gluconeogeneic enzyme activities were significantly increased in STZ+PV or STZ+bPV groups. These results suggest that the PV has somewhat protective effects on blood insulin levels and tissue glycolytic enzyme activities in rats, but it could not reduced blood glucose levels significantly, probably because of excessive increase of hepatic gluconeogeneic enzymes.

CROSS 공법을 이용한 폐수의 생물학적 처리에 관한 연구

박광하,심재도,권영두,강동수,김인호,정태명,황갑성 7개 국립대학교 환경연구 논문집 공동발행 위원회 2003 공업기술연구 Vol.3 No.-

This study aims to develop using a continuous removal of organic and settling solid(CROSS) to increase the efficiency of aeration system for wastewater treatment. To solve many problems of the conventional activated-sludge process, authors suggested a new CROSS model in conjunction with aeration systems in 1996. This system is characterized by utilizing an intensive aeration pipe with inlets at the lower portion and outlets at the higher portion in an aeration tank. Through the experiments on CROSS process, the average removal efficiences of BOD, COD_(Mn), SS, T-N and T-P were showed 98.8%, 93.9%, 98.0%, 71.3% and 49.8%. The average DO (Dissolved-Oxygen) concentration was constantly maintained at 8.0 mg/L by the intensive aeration which was accompanied by rapid reduction of BOD. Degradation of the organic matters in sewage then continued for the whole aeration period. The process demonstrated that it was very adaptive without seeding and returning the sludge. Compared to the activated sludge system, the system was very flexible for the continuous flow treatment. This preliminary assessment showed that the porous media in CROSS reactor is viable for the sewage treatment, since the porous media under the intensive aeration achieves acceptable effluent quality.