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Wei Zhang,Hongbin Zhang,Liping Yang,Yi Tang,Ping Tang 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.109 No.-
To improve the low crystallization rate and long molding cycle of Poly(ethylene terephthalate) (PET), series of PET nanocomposites incorporated small quantities of zeolites with different topologies were blended by melt compounding. The nucleation influence of 3-dimensional zeolites Y, ZSM-5 and 2- dimensional zeolite MCM-22P on the crystallization manner of PET was analyzed by non-isothermal and isothermal crystallization, quantitative evaluation of nanoparticle dispersion and morphology of nanoparticles. The results show that all PET/zeolite nanocomposites exhibit higher crystallization temperature and faster crystallization rate than PET due to large specific surface area of zeolites and their superior dispersion in the PET matrix. Among them, PET/MCM-22P nanocomposites remarkably improved the crystallization behavior, thermal stability and oxygen barrier properties, which is related to the layered morphology of MCM-22P and hydrogen bond interactions between MCM-22P and PET. It is revealed that MCM-22P can provide more heterogeneous nucleation sites for PET by exfoliation in melting compounding. Furthermore, the nucleation mechanism induced by MCM-22P was investigated by the means of Mozhishen method, Avrami equation and theory of Hoffman-Lauritzen. The results indicate that the incorporation of MCM-22P can decrease the free energy of nucleation and fold surface in PET crystallization process, thus improving the crystallinity.
One-Step Synthesis of Immobilized BiOCl Film with Excellent Adsorption Capacity for Dyes
Hongbin Chen,Wangmiao Fu,Xiang Yu,Yi Zhu,Hui Meng,Jinpeng Tang,Yuanming Zhang 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2015 NANO Vol.10 No.8
A facile one-step method was developed for the first time to fabricate BiOCl film on Cu substrate by simply dipping the Cu substrate in the mixed solution containing HCl, glycol, H2O2 and BiCl3. This method shows the advantages of a simple technique, uniform and controllable morphology, as well as easy mass production. The absorption capacity of BiOCl film was investigated by adsorption of Rhodamine B and Congo red (CR) and their maximum adsorption capacities were 1667 mg g-1 and 1429 mg g-1, respectively. The negative values of free energy and the positive values of enthalpy suggested that the adsorption were spontaneous and endothermic, respectively. Moreover, both adsorptions were matched with the pseudo-second-order equation. This film could be reused and the recycle rates for Rhodamine B and CR were still about 95% and 75% after five cycles, respectively. The adsorption mechanism revealed that hydrogen bond mainly accounted for the adsorption of dyes.
Hongbin Yang,Shuo Shao,Tongyu Zhu,Chaocheng Zhao,Shuren Liu,Bobo Zhou,Xiaoyu Hou,Yang Zhang,Wanli Kang 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.79 No.-
Low elastic polymer microsphere (L-EPM) has been proposed as a functional polymer microsphere theseyears. L-EMP has the excellent deformation ability in the porous medium due to the low storage modulus. Herein, one kind of L-EPM with storage modulus (G0) of 23.6 Pa was prepared by inverse suspensionpolymerization. The shear resistance of L-EPM was researched by using coreflooding experiment andhigh shear rate emulsifier. The conformance control behavior of L-EPM was investigated by using doubleparallel sandpackflooding experiment. The results showed that L-EPM was a kind of swollen particle gelwith three-dimensional net structure and contained amide, carboxyl, and sulfonate groups. Themechanism of water swelling property was mainly due to the formation of hydrogen bonds, hydrolysis ofhydrophilic groups and the diffusion caused by osmotic pressure difference. Compared with high elasticpolymer microspheres (H-EPM) and low elastic preformed particle gel (L-PPG), L-EPM had better shearresistance in the porous medium and the well casing perforation. In addition, the critical shear points ofL-EPM was proposed in this work. Due to the better shear resistance and deformation ability, theconformance control behavior of L-EPM showed that L-EPM was a promising conformance control agentin the heterogeneous reservoirs.
Fault Analysis for Power Network Equipment Based On Association Rule Clustering Algorithm
Zhang Hu,Li Feng,Wang Hongbin 보안공학연구지원센터 2016 International Journal of Hybrid Information Techno Vol.9 No.8
In order to improve the fault positioning accuracy of distributed generation power distribution network, it puts forward fault positioning method of distribution network equipment based on blended data association rule data mining method. Based on fuzzy rough set theory, it studies classification rule mining method on hybrid data, through the introduction of the rule to obtain the a generalized threshold of the algorithm, and control the scale and complexity of the obtained rule set, so as to improve the classification efficiency of rough set method of knowledge discovery on the failure data and get the fault positioning feature of distribution network, finally adopts the support vector machine (SVM) to make fault classification, and tests the performance of the algorithm with simulation experiment. The simulation results show that, this paper can be quickly and accurately to locate fault power section, and the fault positioning accuracy is higher than other fault positioning methods of distribution network.
Hongbin Li,Wenying Shi,Shuo Mei,Jinchao Li,Qiyun Du,Longwei Qin,Haixia Zhang 한국섬유공학회 2019 Fibers and polymers Vol.20 No.2
Poly(p-phenylene terephthalamide) (PPTA), as the raw polymer material of Aramid fiber-1414, has high modulus and high strength which is commonly used in the reinforced composites. However, the general blending often accompany the microphase incompatibility in polymer matrix. In this study, PPTA molecules were incorporated into poly(vinylidene fluoride) (PVDF) membrane matrix through in situ polycondensation of p-phenylene diamine (PPD) and terephthaloyl chloride (TPC) in PVDF solution and PPTA/PVDF molecular composite membranes were prepared via the subsequent nonsolvent induced phase separation (NIPS) process. The anti-compaction properties of resulted PPTA/PVDF molecular composite membranes were systematically investigated including the variations of bursting pressure and membrane thickness, porosity, pure water flux under different pressures. The results suggested that membrane comprehensive anticompaction properties were improved with the increasing of PPTA content in PVDF membrane matrix. Combining the variation trends of membrane anti-compaction properties with morphologies, the compaction-deformation evolution processes of two membrane pore types (sponge-like and finger-like pores) were proposed at the end.
Energy-Efficient Base Station Sleep Scheduling in Relay-Assisted Cellular Networks
( Hongbin Chen ),( Qiong Zhang ),( Feng Zhao ) 한국인터넷정보학회 2015 KSII Transactions on Internet and Information Syst Vol.9 No.3
We Relay-assisted cellular network architecture has been developed to cover cell-edge users and to improve capacity. However, the deployment of relay stations (RSs) in cellular networks may increase the total energy consumption. Though energy efficiency has become a major concern in cellular networks, little work has studied the energy efficiency of relay-assisted cellular networks by sleep scheduling. In this paper, a distributed base stations (BSs) sleep scheduling scheme in relay-assisted cellular networks is proposed. The goal is to maximize the energy efficiency under the spectral efficiency constraint. Firstly, whether the BSs should be sleeping or active is determined by the traffic profile. Then, the transmission powers of the active BSs are optimized within the game-theoretic framework, by using an interior-point method, so as to maximize the energy efficiency. Simulation results demonstrate that the effectiveness of the proposed scheme is superior to that turning on all the BSs without sleep scheduling.
Xinyue Zhang,Bushi Dai,Shucheng Ren,Zenan Hu,Xin Zheng,Yao Wang,Hongbin Sun,Dun Niu,Linshan Wang 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.5
Due to the complexity of the contaminations in wastewater, a universal adsorbent that takes many sorts of pollutant is desired. A multi-functioning magnetic Fe3O4-cored magnesium-aluminum layered double oxide (Fe3O4@LDO) composite was prepared and employed as an adsorbent for removing F-, Sb(III) and MO from water, respectively, which are three typical contaminants with different molecule sizes as water contamination. The effect of pH contact time and initial concentrations of pollutants on the removal rates of each contaminant were investigated. Fe3O4@LDO composite showed excellent adsorption performance for all of the three molecules F-, Sb(III) and MO, and their maximum adsorption capacities are as high as 258, 391, and 506mg/g, respectively. The adsorption process of F-, Sb(III) and MO on Fe3O4@LDO fitted well to Langmuir model and pseudo-second-order kinetic model. The adsorption mechanisms of F-, Sb(III) and MO on Fe3O4@LDO were investigated. We discovered that iron ions diffused from Fe3O4 nanospheres contributed to the good performance of the absorbent.