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架橋이온 交換전분에 의한 廢水의 金屬이온 除去 및 回收
河基龍,金宗植 啓明大學校 産業技術硏究所 1986 産業技術硏究所 論文報告集 Vol.8 No.-
A series of water insoluble cation exchange starches(ICESs) were prepared by saponification of crosslinked starch-g-polyacrylonitrile copolymer wwhich were prepared by the grafting of acrylonitrile to crosslinked starch by ceric ion. These starch products contain-COOH group which is effective in removing heavy metal cations such as ?? from industrial waste effluents. Increasing-COOH group content of ICESs in increased the amount of heavy metal removed. In the regeneration of ICESs, only small amount of ICESs were lost during extraction of the metal ions from the complexes by 2% hydrochloric acid, so that recovered ICESs can be used repeatedly to remove heavy metal cations from wastewater.
강원도산 참당귀와 일본산 일당귀의 생리 활성 성분 탐색
함문선,김성수,홍종수,이진하,정을권,박영식,이현용 한국미생물생명공학회 ( 구 한국산업미생물학회 ) 1996 한국미생물·생명공학회지 Vol.24 No.5
참당귀와 일당귀를 에탄올로 추출하였고 이들 추출물들을 디에틸 에테르층과 물층으로 분획하였다. 두 개의 분획물들은 Ames mutagenicity test에서 MNNG(0.5 ㎍/plate)에 대한 강한 항돌연변이 효과를 나타내었다. 디에틸 에테르 분획물들은 MNNG의 돌연변이원성을 78%에서 80%까지 억제시켜 가장 강한 돌연변이 유발 억제효과를 보여주었다. 각각의 에탄올 추출물(1㎍/㎕)들은 사람의 다양한 암세포들의 성장을 억제시켰다. 특히, 디에틸 에테르 분획물들은 간암 세포의 생육을 90%에서 95%까지 억제시켜 가장 강한 항암효과를 보여주었다. 그러나 수층 분획물들은 암세포의 생육에 대하여 거의 억제활성을 나타내지 않았다. 에탄올 추출물들은 인체의 정상 간세포에 대하여 거의 세포독성을 나타내지 않았다. 참당귀의 디에틸 에테르 분획물들은 일당귀와 비교하여 20% 미만의 세포독성을 보여주었다. 참당귀와 일당귀 디에틸 에테르 분획물들의 0.5㎍/㎕ 첨가는 T세포와 B세포의 생육의 3~4배 정도 증가에 의한 면역활성을 보여주었다. 또한 참당귀의 디에틸 에테르 분획물(0.7㎍/㎕)이 ACE 활성을 98%까지 억제시켜 혈압을 조절할 수 있음도 증명되었다. TLC로부터, 두 개의 디에틸 에테르 분획물들은 참당귀와 일당귀의 활성 성분중의 하나로 알려진 umbelliferon을 함유함을 알 수 있었다. The ethanol extracts from Anglica gigas Nakai and Angelica acutiloba Kitagawa were fractionated to diethyl ether and aqueous partitions. Both partitions had strong antimutagenic effect on the MNNG (N-methyl-N-nitro-N-nitrosoguanidine) by Ames mutagenicity of MNNG with inhibition of 78~80%. The ethanol extracts from both species showed the inhibitory effect on the growth of several human cancer cell lines. Especially, the diethyl ether fraction from ethanol extracts was most effective on human hepatocellular carcinoma cells, inhibiting 90~95% of cell growth. However, the aqueous fractions had least inhibition activity on many cancer cells. There was little cytotoxicity on human normal liver cell by ethanol extracts. Diethyl ether fraction from Angelica gigas Nakai ethanol extract had cytotoxicity les than 20% on human normal liver cells, compared with that from Angelica acutiloba Kitagawa ethanol exract. The adding of 0.5 (g/ℓ) of diethyl ether fractions of Angelica gigas Nakai or Angelica acutiloba Kitagawa increased immune activity by enhacing human B and T cells up to three to four times. It was proven that diethyl ether fraction (0.7 g/ℓ) from Angelica gigas Nakai could control blood pressure by suppressing angiotensin converting enzyme activity up to 98%. From TLC, it was appeared that both of diethyl ether partitions had umbelliferon, known to one of active substances from Angelica gigas Nakai and Angelica acutiloba Kitagawa.
Weed increase by soil-disturbing in soybean planting system with cover crop and conservation tillage
Jong-Ho Seo,Seong-Hee Lee,Yeoung-Up Kwon,Jin-Chul Shin,Won-Ha Yang,Tae-Shik Park 한국작물학회 2007 한국작물학회 학술발표대회 논문집 Vol.2007 No.11
Environment-friendly soybean planting system has been being required in the upland field with high slope and heavy rain in summer season. Changes of weed amount and soybean yield by rye cover crop and conservation tillage were investigated. Soil-disturbing at conservation tillage before soybean planting increased numbers and dry weights of weeds germinated in late spring such as Echinochloa crusgalli P. Beauv (barnyardgrass) and Portulaca oleracea L. (common purslane) regardless of herbicide spray even though the weed, Chenopodium ficifolium Smith germinated before soil-disturbing were higher at non-disturbing soil. Higher weed amounts at plots of strip-tillage (30cm rototilling) compared to minimum tillage (10cm rototilling) was mainly due to the weed increase by soil-disturbing. Soybean yields at plots with rye cover crop, particularly early maturity rye cover crop, were lower than those at plots without rye cover crop, which was due to lower soybean seedling stand by heavy rye residue. More researches are required for the higher soybean yield at the minimum tillage with rye cover crop in which weed amounts were low.