광산수의 탈염을 위한 축전식 탈염기술의 적용

이동주,강문성,이상호,박진수,Lee, Dong-Ju,Kang, Moon-Sung,Lee, Sang-Ho,Park, Jin-Soo 한국전기화학회 2014 한국전기화학회지 Vol.17 No.1

본 연구에서 광산수의 재활용을 위해 축전식 탈염공정을 적용하였다. 이를 위해 이온교환폴리머를 코팅한 탄소 전극을 활용하였는데 본 성능을 관찰하기 위해 이온교환폴리머를 코팅하지 않은 탄소 전극으로 광산수의 탈염 운전을 수행하고 비교분석하였다. 또한, 광산수의 높은 농도가 축전식 탈염공정에 미치는 영향을 조사하기 위해 저농도의 기수(NaCl 200 ppm)를 활용한 운전 성능 비교 역시 수행하였다. 연구 결과 이온교환폴리머를 코팅한 탄소 전극을 활용한 광산수 탈염 효율 및 제거양 모두 그렇지 않은 전극에 비해 높았고 에너지 소모량은 더 적게 나타났다. 이는 높은 비패러데이 전류, 높은 염농도에 따른 낮은 용액 저항, 전극 기공 내에서의 이중층 중첩효과에 기인하는 것으로 판단되었다. 또한, 이온교환폴리머를 코팅한 전극을 활용한 기수 탈염 운전 결과 낮은 염농도에 따라 용액의 저항이 높아지고, 제거 대상의 염의 양이 낮아 광산수에 비해 매우 높은 효율을 보였으나, 제거양은 매우 낮음을 알 수 있었다. In this study, capacitive deionization (CDI) was introduced for desalination of mining water. Ion-exchange polymer coated carbon electrodes (IEE) were used in CDI to desalt mining water. The CDI performance using the IEE for desalination of mining water was carried out and then was compared with that using general carbon electrodes without ion-exchange polymer coating (GE). Moreover, to investigate the effect of the concentration of influent solutions on CDI performance, the CDI performance using the IEE for desalination of brackish water (NaCl 200 ppm) was also performed and analyzed. As a result, the higher salt removal efficiency, rate and the lower energy consumption in the CDI process using the IEE and mining water were obtained compared with those using the GE and mining water. It is mainly due to higher non-Faradaic current, low ohmic resistance of the influent, overlapping effect of electric double layers in micropore of the electrode. In addition, the CDI process using the IEE and brackish water shows much higher salt removal efficiency and lower salt removal rate than that using the IEE and mining water. This results from the lower concentration (i.e., higher ohmic resistance) and salt amount of the influent.

겨울철에 흔한 정형외과적 손상

이동주,Lee, Dong-Ju 한국건강관리협회 2002 건강소식 Vol.26 No.12

고려시대의 불교회화

이동주,최순우,황수영,안휘준 ( Dong Ju Lee,Sun U Choi,Su Young Hwang,Hwi Joon Ahn ) 일지사 1979 韓國學報 Vol.5 No.1

축전식 탈염 공정을 위한 메조포러스 탄소 전극

이동주,박진수,Lee, Dong-Ju,Park, Jin-Soo 한국전기화학회 2014 한국전기화학회지 Vol.17 No.1

다공성의 활성탄소와 상대적으로 입자크기가 더 작은 carbon black을 여러 비율로 혼합하여 다양한 적층배열 구조를 갖는 축전식 탈염용 전극을 제조하였고 활성탄소만 존재하는 전극과 비교 분석하였다. 연구 결과 carbon black의 양이 증가할수록 탄소체의 배열 구조가 조밀해지는 것을 관찰하였고, mesopore가 약 10% 증가하는 것으로 나타났다. 순환전압전류법을 이용하여 축전용량을 살펴보았을 때 carbon black만으로는 이온흡착에 대한 영향이 거의 없지만 활성탄소체와 혼합하여 carbon black의 양이 증가할수록 비축전용량 역시 증가하는 것을 관찰하였다. 최종적으로 셀에 전극을 채용하여 탈염실험을 수행한 결과, carbon black의 양이 가장 많이 함유된 전극의 탈염 성능이 가장 우수하였고, pH의 변화의 폭이 가장 좁았다. 또한, 축전된 전하의 분석을 통해 비페러데이 전류의 비율이 증가하는 것으로 나타나 페러데이 반응에 대한 영향이 감소하는 것을 관찰하였다. 이는 carbon black의 첨가로 전극의 적층배열 구조가 변형함으로써 mesopore의 비율이 증가해 페러데이 반응에 의한 영향이 감소하였고, 탈염 성능 역시 증가하는 것을 알 수 있었다. Carbon electrodes for capacitive deionization were fabricated through mixing two different carbon powders (activated carbon powder, carbon black) with different particle sizes to investigate physical or electrochemical properties and finally desalination performances of the electrodes with various compositions of two carbon powders in weight and were compared with the electrode consisting of activated carbon. As a result, the electrode structure became more packed as increasing the amount of carbon black and resulted in 10% increase in mesopore fraction. The specific capacitance obtained from cyclic voltammograms of various electrodes showed that the electrode containing carbon black only had 107.4 F/g, while the specific capacitance of the electrode having more amount of carbon black increased and was higher than the one having no carbon black. The results of desalination runs in a capacitive deionization cell exhibited that the electrode having the highest amount of carbon black (1 wt%) in this study had the highest desalting efficiency, and no significant pH variation was observed during the runs. It was analyzed using accumulated charge that the fraction of non-Faraday current increased as the amount of carbon black increased in the electrodes. It can be concluded that the addition of carbon black changed the electrode structure resulting in an increase in the fraction of mesopore and finally enhanced the desalting efficiency by decreasing Faraday current.

학술정담 공재 (恭齋) 윤두서의 (尹斗緖) 회화

이동주,최순우,안휘준 ( Dong Ju Lee,Soon Woo Choi,Hwi Jun Ahn ) 일지사 1979 韓國學報 Vol.5 No.4

연속섬유가 보강된 2상 복합재료의 종방향 전단계수 해석

이동주,정태현,Lee, Dong-Ju,Jeong, Tae-Hyeon 대한기계학회 1996 大韓機械學會論文集A Vol.20 No.9

Longitudinal shear modulus of continuous fiber reinforced 2-phase composites is predicted by theoretical and numerical analysis methods. In this paper, circular, hexagonal and rectangular shapes of reinforced fiber are considered using unit cell concept. And fiber array is regular rectangular and hexagonal fiber arrangement. Longitudinal shear modulus is a function of fiber distribution pattern and fiber volume change. It is found that the rectangular array has a higher longitudinal shear modulus than the hexagonal one. Also, the rectangular fiber shape in lower fiber volume fraction and the circular fiber shape in higher fiber volume fraction show the higher longitudinal shear modulus. And it has been found that the theoretical and numerical predictions of the longitudinal shear modulus give a good agreement with the experimental data at lower fiber volume fraction. Both the distance and stress transfer between the fibers are discussed as the major determing factors.

전자기 및 광학 센서를 적용한 무기체계의 강수 운용규격 설정을 위한 한반도 강수량 분포에 관한 연구

이동주,김재하,Lee, Dong-Ju,Kim, Jai-Ha 한국군사과학기술학회 2010 한국군사과학기술학회지 Vol.13 No.2

When a weapon system is developed, climate elements such as temperature, rainfall, and so on have an effect on development costs and a developing period. Therefore, effects of environment and climate must be examined throughly before the design of weapon systems and be applied to their developments. And so, operational and storage requirements for weapon systems are determined and are applied to related tests through analyzing not only environmental factors such as vibration, shock, and so on, but also climate factors. In this paper, the distribution and the frequency of occurrence of rainfall were analyzed and were suggested as a good guide to determine standards of tests for weapon systems when it's raining.

표준화 포럼 탐방 - 5G 포럼

이동주,Lee, Dong-Ju 한국정보통신기술협회 2018 TTA저널 Vol.2018 No.-

하이브리드 환기시스템의 운영 및 제어방식

이동주,Lee Dong-Ju 대한설비공학회 2006 설비저널 Vol.35 No.5

컨테이너 운반선 해치-커버 제작시 전 굽힘 변형 거동에 관한 연구

이동주,김경규,신상범,Lee, Dong-Ju,Kim, Gyung-Gyu,Shin, Sang-Beom 대한용접접합학회 2010 대한용접·접합학회지 Vol.28 No.4

The purpose of this study is to establish the control method of the global bending distortion caused by fabrication process of hatch-cover in a container ship. In order to do it, the transitional behavior of global bending distortion in the deck of hatch-cover during fabrication process was measured by 3-dimensional measuring instrument. From the results, the principal factor controlling the global bending distortion was identified as the bending moment associated with the longitudinal shrinkage force and transverse shrinkage caused by welding and flame heating and the change of the centroid axis of hatch-cover in each fabrication process. Therefore, in this study, with the predictive equations of the longitudinal shrinkage force and transverse shrinkage caused by welding and flame heating and the simplified thermo elastic method, the predictive method for the global bending distortion was established and verified by comparing with the measured result. Based on the results, the amount of reverse bending distortion of main stiffeners was determined to prevent the global bending distortion of hatch-cover.