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Gas Barrier성 SEBS (Styrene Ethylene Butadiene Styrene Copolymer)-Clay 하이브리드 막의 제조 및 물성
남상용,염봉열,민병렬,김영진,Nam Sang Yong,Yeom Bong Yeol,Min Byoung Ryul,Kim Young Jin 한국막학회 2005 멤브레인 Vol.15 No.1
본 연구에서는 SEBS와 여러 가지의 유기화물로 처리된 MMT (montmorillonite) type의 clay를 이용하여 SEBS-clay 하이브리드 막을 용융삽입법으로 제조하였다. clay의 함량은 5 phr (per hundred resin)로 고정하였다. internal mixer를 사용하여 clay를 SEBS에 분산시켰으며, 제조된 SEBS-clay 하이브리드에서 clay의 특성피크가 완전히 박리되거나 이동하는 XRD 결과로부터 clay의 층간거리가 넓어지는 고분자의 clay 층간삽입을 확인하였다. Clay의 종류에 따라서 제조된 SEBS-clay 하이브리드 막의 가스투과도, 기계적 물성 및 열적 성질을 측정하였다. SEBS-clay 하이브리드 막은 clay 자체의 도입과 층간거리의 확대로 기체분자의 tortuosity를 증가시켜서 가스투과도를 저하시키는 것을 확인하였다. SEBS-clay hybrid membranes were prepared by melt intercalation method with internal mixer. In the hybrid, the amount of clay content was fixed to 5 phr. MMT was intercalated or exfoliated by the ionomer and it was confirmed by X-ray diffraction method. D-spacing of the characteristic peak from MMT plate in SAXD was moved and diminished. Gas permeability, mechanical properties and thermal properties of the SEBS-clay hybrid membranes were investigated. Gas permeability through the SEBS-clay hybrid membranes decreased due to increased tortuosity made by intercalation of clay in SEBS.
무모쥐의 피부화상에 대한 실크피브로인 필름 피복제의 치유 효능
최영희(Young Hee Choi),김민규(Min Gyu Kim),안동현(Dong Hyun Ahn),홍수희(Soo Hee Hong),이재용(Jae-Yong Lee),김해성(Hae Sung Kim),김흥철(Heung Cheol Kim),남상용(Sang Yong Nam),임건빈(Garbeen Yim) 대한외과학회 2010 Annals of Surgical Treatment and Research(ASRT) Vol.79 No.6
Purpose: The aim of this study was to examine the effects of silk fibroin film on wound healing of cutaneous burn in hairless mice by using microscopic findings and stem cell markers (nestin, cytokeratin 15) and ki-67 proliferation marker. Methods: Each mouse received two burns at the dorsal area by applying a metal rod heated with boiling water. Burn wound sites were dressed with Silk Fibroin Film and duoderm (SF group), Aquacel hydrofiber and duoderm (AC group) and duoderm only (Control group). All groups were covered externally with duodermas adhesive bands. Those mice were sacrificed at zero, two, seven, fourteen and twenty one days after burn. Histological findings and immunohistochemical staining for stem cell markers were observed. Results: In SF group, inflammatory cell infiltration, formation of granulation tissue and inflammatory foci are greater than in AC and control group. Those factors appear to enhance mesenchymal stem cell markers such as nestin. Finally mesenchymal tissue regeneration was enhanced. In addition, the length of ki-67 expressed re-generating epithelium, which appeared to be associated with epithelial regeneration, was the longest in SF group. Conclusion: The results show that the wound healing effect of SF is the best among other treatment materials including AC in the experimental group and duoderm in the control group through mesenchymal regeneration and epithelial regeneration which are essential factors for wound healing.
리튬이온전지용 난연성 첨가제(TCP, TFPP)의 전기화학적 특성
안세영,김기택,김현수,남상용,Ahn, Se-Young,Kim, Ke-Tack,Kim, Hyun-Soo,Nam, Sang-Yong 한국전기전자재료학회 2007 전기전자재료학회논문지 Vol.20 No.9
Flame retardant(FR) properties were investigated with tricredyl phosphate(TCP) and tris(pentafluorophenyl)phosphine(TFPP) as additives for lithium-ion batteries. Thermal stability was improved with additives in $Li/LiNi\frac{1}{3}Mn\frac{1}{3}Co\frac{1}{3}O_2$ cells comparing to non-additive electrolytes. Oxygen evolution reaction of the cathode material was delayed to up $55^{\circ}C$, from $275^{\circ}C\;to\;330^{\circ}C$. Electrolytes with the 1 wt.% additives provided good FR properties while the resonable battery performance is maintained.
수송 전 Diniconazole과 D-mannitol, D-sorbitol, Wax의 혼용 살포에 따른 접목 선인장 산취의 품질과 표피의 변화
박선미(Seon-Mi Park),남상용(Sang-Yong Nam),이병철(Byung-Chul Lee),이부영(Bu-Young Yi) (사)한국생물환경조절학회 2011 생물환경조절학회지 Vol.20 No.2
본 연구는 품질증진제 처리가 산취(Chamaecereus silvestrii) ‘희망’의 모구품질과 표피 변화에 미치는 영향을 연구하였다. 생체중은 D-sorbitol 처리구보다 D-mannitol 처리구에서 감소율이 낮아 효과적이었다. Diniconazole 200ppm처리는 산취의 자구생육을 어느 정도(수치화) 억제하여 장기수송(50일)에 더 적합하였으며 자구색의 발현 어느 정도(수치화)에도 효과적이었다. 산취 모구의 표피구조는 비모란에 비해 하피 발달이 저조하고 어느 정도(수치화) 단층이며 세포벽도 얇아 어느 정도 (수치화) 수송조건에 불리하였는데 생육의 억제효과가 높은 diniconazole 200ppm + D-mannitol 10,000ppm과 발색효과가 좋은 diniconazole 200ppm + wax 살포가 저장 중의 품질 유지에 적합하다고 판단된다. This research has been carried out to examine the effects of quality promoting agents on global quality and epidermal changes of Chamaecereus silvestrii ‘Hee-mang’ for quality maintenance of the transportation. D-sorbitol than D-mannitol treatment was effective in a lower reduction of fresh weight in C. sil-vestrii transportations. Application of diniconazole 200 ppm suppressed growth of C. silvestrii. However, it enabled the possibility of long-term plant transportation (up to 50 days) and color formation was also effective. As for epidermis structure of C. silvestrii, hypodermis development was lower compared to Gymnoca-lycium friedrichii and its long-term transportation became poor quality due to single layered, thin cell wall. Application of diniconazole 200 ppm + D-mannitol 10,000 ppm showed higher growth suppressing effects and diniconazole 200 ppm + wax treatment showed better color formation suitable for quality maintenance and storage purposes for C. silvestrii.