그래핀/사파이어 기판상에 스퍼터링 후 열처리된 VO₂박막의 구조 및 광학적 특성변화 연구

김근수,김형근,김예나,한승호,배동재,양우석,Kim, Keun Soo,Kim, Hyeongkeun,Kim, Yena,Han, Seung-Ho,Bae, Dong Jae,Yang, Woo Seok 한국진공학회 2013 Applied Science and Convergence Technology Vol.22 No.2

이산화바나듐($VO_2$)는 써모크로믹(thermochromic) 물질로서 온도변화에 따른 구조적 상전이에 의해 전기적, 광학적 특성을 스위칭 할 수 있는 매력적인 소재이며, 최근 신소재로써 그 연구가 활발한 그래핀 역시, 전기적으로나 광학적으로 그 특성이 우수하여 투명전극에 관한 연구가 아주 활발하게 진행되고 있다. 이에 우리는 $VO_2$와 그래핀 두 가지 소재를 접목했을 경우 나타나는 현상을 그래핀의 층 수와 온도를 변수로 하여 형성된 박막의 구조와 광학적 특성을 측정하고 분석하였다. 본 연구 결과에 따르면 그래핀 필름이 전사된 사파이어 기판 위에 형성된 $VO_2$ 박막의 표면구조 및 특성이 bare 사파이어 기판 위의 $VO_2$ 박막보다 그레인이 작고 밀도가 높아 균일하였으며, IR 영역에서의 광투과도 역시 그래핀 필름이 있을 경우 ~10% 정도 개선됨을 확인하였다. 아울러 평균상전이 온도를 낮출 수 있으며, 상전이 히스테리시스 변화폭 또한 좁아지는 것을 확인하였다. $VO_2$ is an attractive thermochromic material, in which its electrical and optical properties can be switched by the structural phase-transition about $68^{\circ}C$. Recently, graphene is also a rising material which is researched as a transparent electrode because of its superior electrical and optical characteristics. In this respect, we try to fabricate the hybridized films using $VO_2$ and graphene on transparent sapphire substrate and then we investigate a structure and characterize an optical property for the samples as a function of temperature. According to the result of IR-transmittance analysis of $VO_2$ films as a function of temperature, the graphene-supported sapphire substrates are better about 10% than the bare sapphire substrates. The mean phase transition temperatures are also decreased as the number of graphene-layers increased and the hysteresis of phase transitions are narrowed.

전시잡지 해제목록1

김근수,Kim, Geun-Su 한국도서관협회 1970 圖協月報 Vol.11 No.11

이 해제 목록은 제16회 독서주간을 기념하기 위하여 9월 24일부터 30일까지 서울특별시립 종로 도서관에서 본 협회가 개회한 ‘제1회 한국잡지전시회’에서 출품 전시되었던 잡지를 해제한 것으로 해방이후부터 1960년까지 우리나라에서 간행된 것 중 김근수 선생이 소장하고 있는 것만을 실었음을 밝혀둔다.

고서해제-「물명고」와 「물보」 해제

김근수,Kim, Geun-Su 한국도서관협회 1970 圖協月報 Vol.11 No.8

Comparison of Biofilm Formed on Stainless Steel and Copper Pipe Through the Each Process of Water Treatment Plant

김근수,민병대,박수정,오정환,조익환,장석재,김지혜,박상민,박주현,정현미,안태영,정원화,Kim, Geun-Su,Min, Byung-Dae,Park, Su-Jeong,Oh, Jung-Hwan,Cho, Ik-Hwan,Jang, Seok-Jea,Kim, Ji-Hae,Park, Sang-Min,Park, Ju-Hyun,Chung, Hyen-Mi,Ahn, Tae-Yo The Microbiological Society of Korea 2013 미생물학회지 Vol.49 No.4

정수처리 시설에서 급 배수관으로 많이 사용되는 스테인리스관과 동관에 형성되는 생물막의 특성에 대해 16주 동안 조사하였다. 생물막 반응기는 실제 배급수관의 구조와 유사하게 설계하였으며, 정수처리장으로 유입되는 상수원수와 약품혼화 응집수, 침전수, 여과수, 처리수를 사용하였다. 평균 종속영양세균수는 $1.6{\times}10^4CFU/ml$, $5.8{\times}10^3CFU/ml$, $1.8{\times}10^3CFU/ml$, $1.3{\times}10^2CFU/ml$, 1 CFU/ml로 각 처리 과정을 거치면서 감소하였다. 스테인리스관과 동관에 형성된 생물막 세균수는 원수, 응집수, 침전수에서 2주만에 $2.9{\times}10^3CFU/cm^2$ 이상으로 증가하였고, 동관보다 스테인리스관에서 생물막 세균수가 높게 검출되었다. 여과수(평균 잔류염소 0.44 mg/L)에서는 두 관 재질에 따른 생물막 세균수의 명확한 차이는 없었으며, 5주 이후부터 두 관재질 모두 $18CFU/cm^2$ 이하의 생물막 세균이 검출되었다. 정수(평균 잔류염소 0.88 mg/L)에서는 두 관 재질 모두 생물막 세균이 검출되지 않았다. DGGE 분석결과, 원수, 응집수, 침전수에서 스테인리스관은 Sphingomonadaceae가 우점이였고, 동관에서는 Bradyrhizobiaceae와 함께 Sphingomonadaceae도 우점이였다. 여과수의경우, 5주차 이후 스테인리스관과 동관에 형성된 생물막에서 Propionibacterium sp., Sphingomonas sp., Escherichia sp. 등과 유사한 16S rRNA 유전자 서열을 가지는 밴드들이 검출되었다. 종 풍부도 및 다양성은 동관에 비해 스테인리스관이 더 높게 나타났다. Biofilm formed on stainless and copper in water treatment plant was investigated for sixteen weeks. Biofilm reactor was specially designed for this study. It was similar to that of a real distribution pipe. Raw water, coagulated, settled, filtered and treated water were used in this study. The average number of heterotrophic bacteria counts was $1.6{\times}10^4CFU/ml$, $5.8{\times}10^3CFU/ml$, $1.8{\times}10^3CFU/ml$, $1.3{\times}10^2CFU/ml$, 1 CFU/ml, respectively. Density of biofilm bacteria formed on stainless and copper pipes in raw, coagulated and settled water increased above $2.9{\times}10^3CFU/cm^2$ within second weeks while more biofilm bacteria counts were found on the stainless pipe than on the copper pipe. In case of filtered water (free residue chlorine 0.44 mg/L), there was no significant difference in the number of biofilm bacteria on both pipes and biofilm bacteria below $18CFU/cm^2$ were detected on both pipe materials after fifth weeks. Biofilm bacteria were not detected on both pipe materials in treated water (free residue chlorine 0.88 mg/L). According to the results of DGGE analysis, Sphingomonadacae was a dominant species of biofilm bacteria formed on the stainless pipe while the copper pipe had Bradyrhizobiaceae and Sphingomonadaceae as dominant bands. In case of filtered water, a few bands (similar to Propionibacterium sp., Sphingomonas sp., Escherichia sp., and etc.) that have 16S rRNA sequences were detected in biofilm bacteria formed on both pipes after fifth weeks. Stainless pipe had higher species richness and diversity than the copper pipe.

고서해제-순오지

김근수,Kim, Geun-Su 한국도서관협회 1969 圖協月報 Vol.10 No.5

순 Sn 도금에서의 Sn 휘스커 성장제어 기술

김근수,Kim, Keun-Soo 대한용접접합학회 2013 대한용접·접합학회지 Vol.31 No.3

Sn whiskers are one of the serious causes of the failure of electronics. Sn whiskers grow spontaneously from Sn-based, lead-free finished surfaces, even at room temperature. A primary factor of these Sn whiskers growth is compressive stress, which enhances the diffusion of Sn or other elements. The sources of compressive stress are the growth of non-uniform large intermetallic compounds along the interface between the Sn grain boundary and Cu substrate. Recent studies revealed the methods for reducing Sn whisker growth. This paper gives an overview about recent researches for mitigation methods of Sn whisker growth during nearly room temperature storage.

교류형 PDP의 온도에 따른 방전특성

김근수,이석현,Kim, Gun-Su,Lee, Seok-Hyun 한국전기전자재료학회 2009 전기전자재료학회논문지 Vol.22 No.3

In AC-PDP, it is necessary to achieve high luminance efficacy, high luminance and high resolution by adopting technologies such as high Xenon concentration, MgO doping, and long gap. However, it is very difficult to apply above technologies because they reduce driving voltage margin. For example, doping of MgO reduces driving voltage but introduces new problems such as increased temperature dependency of discharge, which result in larger variations in driving margin at different temperatures. In this paper, we present the experimental results of the characteristics of temperature-dependent discharges. In addition, we suggest the mechanism of bright noise, black noise, and high temperature mis-discharge, which depend on temperature-dependent characteristics of MgO.

Tensolin-F^® (3,9-diferuloyl-6-oxopterocarpen)의 단회 독성시험 및 4주 반복투여 독성시험

김근수,박성민,이남진,표형배,채희열,정유리,임춘매,김선희,이혜영,강종구,Kim, Keun-Su,Park, Sung-Min,Lee, Nam-Jin,Pyo, Hyeong-Bae,Chai, Hee-Yul,Jung, Yu-Ri,Lin, Chun-Mai,Kim, Sun-Hee,Lee, Hye-Young,Kang, Jong-Koo 한국독성학회 2007 Toxicological Research Vol.23 No.4

This study was to investigate single and repeated-dose toxicities of Tensolin-$F^{(R)}$, an anti-wrinkle agent, in Sprague-Dawley (SD) rats or ICR mice. In single-dose oral toxicity study, the test materials were administered once by gavage to male and female SD rats at dose levels of 0 and 2,000 mg/kg. No dead animals and abnormal necropsy findings were found in control and Tensolin-$F^{(R)}$ treated group. Therefore, the approximate lethal dose of Tensolin-$F^{(R)}$ was considered to be higher than 2,000 mg/kg in rats. In the 4-week repeated oral toxicity study, the test material was administered once daily by gavage to male and female ICR mice at dose levels of 0, 25, 50 and 100 mg/kg/day for 4-weeks. In the results, no abnormality was observed in mortality, clinical findings, body weight changes, food and water consumptions, opthalmoscopic findings, necropsy findings, histopathological findings. In hematological analysis, there was a trend of increase in reticulocyte at male 25 mg/kg, although such changes were in normal ranges. On the other hand, there was a trend of decrease in hemoglobin at female 50, 100 mg/kg, such changes were in normal ranges. In addition, serum biochemical parameters including sodium, BUN and chloride increased at 25, 50 and 100 mg/kg. Relative organ weights of right testis, brain, lung and left epididymis were increased in 100 mg/kg groups of male rats in contrast to not change in female groups. However, these changes of relative organ weights, hematological and serum biochemical parameters were not accompanied with related signs such as histopathological changes or clinical findings. In conclusion, 4-week repeated oral dose of Tensolin-$F^{(R)}$ to ICR mice did not cause apparent toxicological change at the dose of 25, 50, 100 mg/kg body weight. Consequently the no-observed-adverse-effect level (NOAEL) for Tensolin-$F^{(R)}$ in ICR mice following gavage for at least 4-week is higher than 100 mg/kg/day.

Skarn Formation in Metamorphic Rocks of the Chungju Mine Area

김근수,박맹언,Kim, Gun-Soo,Park, Maeng-Eon The Korean Society of Economic and Environmental G 1995 자원환경지질 Vol.28 No.3

충주 광산 지역은 계명산층과 이를 관입한 중생대 화강암질 암석으로 구성되며, 이들 화강암질 암석중 백악기초(134 Ma) 흑운모 화강암과 계명산층을 구성하는 석영-운모 편암의 접촉부에서 회중석을 수반하는 스카른 광상이 산출된다. 스카른은 구성광물의 공생 특성과 주 구성광물의 양적인 비에 의해 석류석 스카른대, 규회석 스카른대, 녹염석 스카른대 및 녹니삭 스카른대로 분류된다. 석류석의 화학조성은 초기 순수한 안드라다이트 (>Ad96)에서 후기 알루미늄 함량비가 증가하는 안드라다이트-그라슈라(Ad~50)로 점이적인 변화를 나타내며, 녹염석은 $Fe^{3+}$ 의 함량비가 높은 고용체 상(Ps=35)에서 암루미늄 함량비가 높은 고용체 상(Ps=25)으로 변화하는 양상을 띤다. 광물 공생 및 화학 조성상의 특징으로 볼 때 스카른화 작용은 Ca와 Fe의 활동도가 흑운모 화강암의 접촉부에서 높고 Al, Mg, K 및 Si 활동도는 석영-운모 편암내에 발달되는 스카른에서 증가하는 경향을 나타낸다. 녹염석 스카른대에서 산출되는 회중석의 유체포유물 균질화 온도는 $300{\sim}380^{\circ}C$ 이며 NaCl 상당 염농도는 3-8wt. %로, 석영 및 녹염석 유세포유물 균질화 온도는 $300{\sim}400^{\circ}C$이다. 후기 녹니석 스카른대내에서 수반되는 황화광물의 황 동위원소비는(${\delta}^{34}S$) 황철석 $9.13{\sim}9.51%_{\circ}$, 방연석 $5.85{\sim}5.96%_{\circ}$이며, 공존하는 황철석-방연석 광물쌍에 의한 동위 원소 지질온도는 $283{\pm}20^{\circ}C$이다. 이산화탄소 몰분율($X_{CO_2}$)은 $L-CO_2$가 관찰되지 않으며 $H_2O$ 풍부한 유체포유물로 구성되고 있는점과, 안드라다이트 및 규회석의 광물공생 특성과 대비하여 볼때 약 0.01로 추정된다. 광물공생 및 화학조성, 상 안정 관계, 유체포유물 연구, 동위원소 지질온도계등의 연구 결과에 의해 충주광산 지역 스카른화 작용은 $400{\sim}260^{\circ}C$ 온도 조건과 산소분압이 감소($fo_2=10^{-30}{\sim}10^{-25}$)하는 환경에서 진행되었으며, 텅스텐 광화작용은 이러한 스카른 형성 과정 중 온도의 감소($350^{\circ}C$)와 산소분압이 감소($fo_2=10^{-27}$) 하는 조건에서 수반되었다. Tungsten skarns in the Chungju mine which consists mainly of strata-bound type iron ore deposits are found in the vicinity of the contact between the age-unknown Kyemeongsan Formation and granitic rock intrusions of Mesozoic age($134{\pm}2Ma$). Tungsten skarns were formed extensively from alumina and silica-rich schistose rocks by the introduction of calcium and iron from hydrothermal solution. The skarns comprise a metasomatic column and are subdivided into four facies; garnet facies, wollastonite facies, epidote facies and chlorite facies. The skarn process in time-evolutional trend can be divided broadly into the four facies in terms of the paragenetic sequence of calc-silicates and their chemical composition. Skarn and ore minerals were formed in the following sequence; (1) garnet facies, adjacent to biotite granite, containing mainly garnet(>Ad96) and magnetite, (2) wollastonite facies containing mainly wollastonite and garnet(Ad95~60), (3) epidote facies, containing mainly epidote(Ps35~31), quartz, andradite-grossular(Ad63~50), and scheelite, (4) chlorite facies, adjacent to and replacing schist, containing mainly chrolite, muscovite, quartz, calcite, epidote(Ps31~25), hematite and sulfides. The mineral assemblage and mineral compositions. suggest that the chemical potentials of Ca and Fe increased toward the granitic rock, and the component Al, Mg, K, and Si decreased from the host rock to granitic rock. The homogenization temperature and salinity of fluid inclusion in scheelite, quartz and epidote of epidote facies skarn is $300-400^{\circ}C$ and 3-8wt.% eqiv. NaCl, respectively. ${\delta}^{34}S$ values of pyrite and galena associated with chlorite facies skarn is $9.13{\sim}9.51%_{\circ}$ and $5.85{\sim}5.96%_{\circ}$, respectively. The temperature obtained from isotopic com· position of coexisting pyrite-galena is $283{\pm}20^{\circ}C$. Mineral assemblages and fluid inclusion data indicate that skarn formed at low $X_{CO_2}$, approximately 0.01. Temperature of the skarn mineralization are estimated to be in the range of $400^{\circ}C$ to $260^{\circ}C$ and pressure to be 0.5 kbar. The oxygen fugacity($fo_2$) of the skarn mineralization decreased with time. The early skarn facies would have formed at log $fo_2$ values of about -25 to -27, and late skarn facies would have formed at log $fo_2$ values of -28 to -30. The estimated physicochemical condition during skarn formation suggests that the principal causes of scheelite mineralization are reduction of the ore·forming fluid and a decrease in temperature.

경추 전방 잠금식 금속판이 장기적으로 경추에 미치는 영향

김근수,Kim, Keun Su 대한신경외과학회 2001 Journal of Korean neurosurgical society Vol.30 No.4

Objective : Anterior cervical locking plates are the devices for achieving anterior cervical spinal fusion. This study was conducted to evaluate the locking plate system regarding its long-term advantages and disadvantages in the view of interbody fusion rate, hardware-related failures, vertebral change close to the fusion segment and postoperative complications. Method : Eight-six patients, operated from Jan., 1996 to Jun. 1998, were followed-up for more than two years. All of the cases were fused with iliac bone graft and ORION locking plate(Sofamor Danek USA, Inc., Memphis, TN) fixation. The patients were discharged or transferred to rehabilitation department 2-7 days after operation. A comprehensive evaluation of the interbody fusion state, instrument failure, vertebral change and postoperative complications were made by direct interview and cervical flexion-extension lateral plain films. Results : There were 55 male and 31 female with a mean age of 45 years(18-75 years). The mean follow-up period was 29 months(24-43 months). Various disorders that were operated were 40 cervical discs, 6 cervical stenosis including OPLL, 2 infections, and 38 traumas. Fusion level was single in 59 cases, two levels of each disc space in 15 cases, and two levels after one corpectomy in 12 cases. There was no instrument failure. Pseudoarthrosis was observed in two cases(2%) without radiological instability. The other patients(98%) showed complete cervical fusion with stable instrument. Mild settling of interbody graft with upward migration of screws was found in 12 cases(14%). Anterior bony growth at the upper segment was found in 5 cases(6%). Postoperative foreign body sensation or dysphagia was observed in 12 cases(4%), and disappeared within one month in 7 cases and within six months in 4 cases. One patient complained for more than six months and required reoperation to remove paraesophageal granulation tissue. Conclusion : The results show that Orion cervical locking plate has some disadvantages of upward migration of screws, anterior bony growth at the upper segment, or possibility of esophageal compression even though it has advantages of high interbody fusion rate or low instrument failure. Author believe that anterior cervical locking plate in the future should be thinner, and should have short end from the screw hole, and movable screw with adequate stability.