Mechanical properties of fiber/graphene epoxy hybrid composites

Tolga Topkaya,Yahya Hışman Çelik,Erol Kilickap 대한기계학회 2020 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.34 No.11

The aim of this study is to determine the effect of graphene nanoparticle (GNP) reinforcement on the mechanical properties of glass fiber reinforced polymer (GFRP), carbon fiber reinforced polymer (CFRP) and aramid fiber reinforced polymer (AFRP) composites commonly used in the space and defense industry. Accordingly, GFRP, CFRP and AFRP composites were produced by using hot pressing method. In addition, hybrid fiber composites were produced by adding 0.1 %, 0.2 % and 0.3 % GNP to these fiber reinforced composites. The tensile strength and modulus of elasticity of the composites were determined. The tensile damage fracture regions were analyzed by scanning electron microscopy (SEM) and energy distribution spectrum (EDS). It was observed that the addition of 0.2 wt. % GNP to GFRP and CFRP composites increased tensile strength and modulus of elasticity. However, the addition of 0.2 wt. % GNP to AFRP composites had no effect on the tensile strength; on the contrary, it partially reduced the tensile strength but increased the modulus of elasticity. On the fracture damage surfaces of the GFRP and CFRP composites and the GNP/GFRP and GNP/CFRP hybrid composites, the fibers were completely separated. On the damage surfaces of AFRP composite and GNP/AFRP hybrid composites, the fibers were deformed but these fibers were not separated from each other. From the EDS analysis, it was observed that the element C increased in the composites with the addition of GNP to the fiber reinforced composites.

Fabrication of SiC Fiber-SiC Matrix Composites by Reaction Sintering

임광영,김영욱,박지연 한국세라믹학회 2008 한국세라믹학회지 Vol.45 No.4

This paper presents a new process for producing SiC fiber-SiC matrix (SiC/SiC) composites by reaction sintering. The processing strategy for the fabrication of the SiC/SiC composites involves the following: (1) infiltration of the SiC fiber fabric using a slurry consisting of Si and C precursors, (2) stacking the slurry-infiltrated SiC fiber fabric at room temperature, (3) cross-linking the stacked composites, (4) pyrolysis of the stacked composites, and (5) hot-pressing of the pyrolyzed composites. It was possible to obtain dense SiC/SiC composites with relative densities of >96% and a typical flexural strength of ~400 MPa. This paper presents a new process for producing SiC fiber-SiC matrix (SiC/SiC) composites by reaction sintering. The processing strategy for the fabrication of the SiC/SiC composites involves the following: (1) infiltration of the SiC fiber fabric using a slurry consisting of Si and C precursors, (2) stacking the slurry-infiltrated SiC fiber fabric at room temperature, (3) cross-linking the stacked composites, (4) pyrolysis of the stacked composites, and (5) hot-pressing of the pyrolyzed composites. It was possible to obtain dense SiC/SiC composites with relative densities of >96% and a typical flexural strength of ~400 MPa.

압력하중 하에서 섬유배열방향과 적층판의 적층순서에 따른 생체 모방 복합재의 파괴 거동에 관한 연구

김명수 한국산업융합학회 2023 한국산업융합학회 논문집 Vol.26 No.1

Recently, fiber-reinforced composites have been widely used in various industrials fields. In this study, the mechanical behavior, especially fracture behavior, of biomimetic fiber-reinforced composites subjected to pressure loading was analyzed using finite element analysis (FEA). The fiber alignments in the biomimetic composites formed a helicoidal structure, wherein a stacking sequence involved a gradual rotation of each ply in the multi-layered laminated composites. For comparison, cross-ply composite samples with fibers arranged at 0° and 90° were prepared and analyzed. In addition, the mechanical behavior was analyzed based on combinations of the stacking sequence of carbon-fiber composites and glass-fiber composites. The FEA results showed that, when compared with the cross-ply samples, the mechanical properties of the biomimetic composites were considerably improved under pressure loading, which was applied to one side of the composites. Thus, the biomimetic helicoidal structure significantly improved the mechanical properties of the composites. Placing materials having high elasticity and strength in the outermost layers (the layer of the side on which pressure was applied and the opposite side layer) of the composites also significantly contributed to improving the mechanical properties of the composites.

Effects of Filler Characteristics and Processing Conditions on the Electrical, Morphological and Rheological Properties of PE and PP with Conductive Filler Composites

김윤희,김지문,김성현,김우년,김동현,이헌상 한국고분자학회 2009 Macromolecular Research Vol.17 No.2

The electrical, morphological and rheological properties of melt and dry mixed composites of polyethylene (PE)/graphite (Gr), polypropylene (PP)/Gr and PP/nickel-coated carbon fiber (NCCF) were investigated as a function of filler type, filler content and processing temperature. The electrical conductivities of dry mixed PP/NCCF composites were increased with decreasing processing temperature. For the melt mixed PP/NCCF composites, the electrical conductivities were higher than those of the melt mixed PE/Gr and PP/Gr composites, which was attributed to the effect of the higher NCCF aspect ratio in allowing the composites to form a more conductive network in the polymer matrix than the graphite does. From the results of morphological studies, the fillers in the dry mixed PP/NCCF composites were more randomly dispersed compared to those in the melt mixed PP/NCCF composites. The increased electrical conductivities of the dry mixed composites were attributed to the more random dispersion of NCCF compared to that of the melt mixed PP/NCCF composites. The complex viscosities of the PP/Gr composites were higher than those of the PP/NCCF composites, which was attributed to the larger diameter of the graphite particles than that of the NCCF. Furthermore, the fiber orientation in the ‘along the flow’ direction during melt mixing was attributed to the decreased complex viscosities of the melt mixed PP/NCCF composites compared those of the melt mixed PP/Gr composites.

Effects of Filler Characteristics and Processing Conditions on the Electrical, Morphological and Rheological Properties of PE and PP with Conductive Filler Composites

Kim, Youn-Hee,Kim, Dong-Hyun,Kim, Ji-Mun,Kim, Sung-Hyun,Kim, Woo-Nyon,Lee, Heon-Sang The Polymer Society of Korea 2009 Macromolecular Research Vol.17 No.2

The electrical, morphological and rheological properties of melt and dry mixed composites of poly ethylene (PE)/graphite (Gr), polypropylene (PP)/Gr and PP/nickel-coated carbon fiber (NCCF) were investigated as a function of filler type, filler content and processing temperature. The electrical conductivities of dry mixed PP/NCCF composites were increased with decreasing processing temperature. For the melt mixed PP/NCCF composites, the electrical conductivities were higher than those of the melt mixed PE/Gr and PP/Gr composites, which was attributed to the effect of the higher NCCF aspect ratio in allowing the composites to form a more conductive network in the polymer matrix than the graphite does. From the results of morphological studies, the fillers in the dry mixed PP/NCCF composites were more randomly dispersed compared to those in the melt mixed PP/NCCF composites. The increased electrical conductivities of the dry mixed composites were attributed to the more random dispersion of NCCF compared to that of the melt mixed PP/NCCF composites. The complex viscosities of the PP/Gr composites were higher than those of the PP/NCCF composites, which was attributed to the larger diameter of the graphite particles than that of the NCCF. Furthermore, the fiber orientation in the 'along the flow' direction during melt mixing was attributed to the decreased complex viscosities of the melt mixed PP/NCCF composites compared those of the melt mixed PP/Gr composites.

Experimental and microstructural evaluation on mechanical properties of sisal fibre reinforced bio-composites

B. Ravi Kumar,S.S. Hariharan 국제구조공학회 2019 Steel and Composite Structures, An International J Vol.33 No.2

The natural fibre composites are termed as bio-composites. They have shown a promising replacement to the current carbon/glass fibre reinforced composites as environmental friendly materials in specific applications. Natural fibre reinforced composites are potential materials for various engineering applications in automobile, railways, building and Aerospace industry. The natural fibre selected to fabricate the composite material is plant-based fibre e.g., sisal fibre. Sisal fibre is a suitable reinforcement for use in composites on account of its low density, high specific strength, and high hardness. Epoxy is a thermosetting polymer which is used as a resin in natural fibre reinforced composites. Hand lay-up technique was used to fabricate the composites by reinforcing sisal fibres into the epoxy matrix. Composites were prepared with the unidirectional alignment of sisal fibres. Test specimens with different fibre orientations were prepared. The fabricated composites were tested for mechanical properties. Impact test, tensile test, flexural test, hardness test, compression test, and thermal test of composites had been conducted to assess its suitability in industrial applications. Scanning electron microscopy (SEM) test revealed the microstructural information of the fractured surface of composites.

Effect of HTT on Bending and Tensile Properties of 2D C/C Composites

S.R. Dhakate,T. Aoki,T. Ogasawara 한국탄소학회 2005 Carbon Letters Vol.6 No.4

Bending and tensile properties of 2D cross-ply C/C composites with processing heat treatment temperature (HTT) are evaluated. C/C composites used are made from two types of PAN based T700 and M40 carbon fibers with phenolic resin as carbon matrix precursor. Both the types of composites are heat treated at different temperatures (ranging from 750 to 2800℃) and characterized for bending and tensile properties. It is observed that, real density and open porosity increases with HTT, however, bulk density does show remarkable change. The real density and open porosity are higher in case T-700 carbon fiber composites at 2800℃, even though the density of M40 carbon fiber is higher. Bending strength is considerably greater than tensile strength through out the processing HTT due to the different mode of fracture. The bending and tensile strength decreases in both composites on 1000℃ which attributed to decrease in bulk density, thereafter with increase in HTT, bending and tensile strength increases. The maximum strength is in T700 fiber based composites at HTT 1500℃ and in M40 fiber based composites at HTT 2500℃. After attending the maximum value of strength in both types of composite at deflection HTT, after that strength decreases continuously. Decrease in strength is due to the degradation of fiber properties and in-situ fiber damages in the composite. The maximum carbon fiber strength realization in C/C composites is possible at a temperature that is same of fiber HTT. It has been found first time that the bending strength more or less 1.55 times higher in T700 fiber composites and in M40 fiber composites bending strength is 1.2 times higher than that of tensile strength of C/C composites.

Mechanical Analysis of Woven Composites at High Strain Rates and Its Application to Predicting Impact Behavior

류한수,임지호,정관수 대한금속·재료학회 2008 METALS AND MATERIALS International Vol.14 No.6

The deformation behavior of woven composites at high strain rates was analyzed using a constitutive equation developed to describe the nonlinear, anisotropic/asymmetric and rate-dependent mechanical behavior of woven composites. The rate-dependent nonlinear behavior of woven composites was characterized at high strain rates (1 s-¹ to 100 s-¹) using a tensile testing method first proposed in this research. The material properties for the developed constitutive equation were determined and subsequently used in a finite element analysis of the deformation behavior of woven composites at high strain rates. Finally, the impact behavior of woven composites was predicted using the constitutive equation and the results were compared with experiments, showing that the current constitutive equation including the characterization method is adequate to describe the deformation behavior of woven composites at high strain rates up to impact level. The deformation behavior of woven composites at high strain rates was analyzed using a constitutive equation developed to describe the nonlinear, anisotropic/asymmetric and rate-dependent mechanical behavior of woven composites. The rate-dependent nonlinear behavior of woven composites was characterized at high strain rates (1 s-¹ to 100 s-¹) using a tensile testing method first proposed in this research. The material properties for the developed constitutive equation were determined and subsequently used in a finite element analysis of the deformation behavior of woven composites at high strain rates. Finally, the impact behavior of woven composites was predicted using the constitutive equation and the results were compared with experiments, showing that the current constitutive equation including the characterization method is adequate to describe the deformation behavior of woven composites at high strain rates up to impact level.

Effect of HTT on Bending and Tensile Properties of 2D C/C Composites

Dhakate, S.R.,Aoki, T.,Ogasawara, T. Korean Carbon Society 2005 Carbon Letters Vol.6 No.4

Bending and tensile properties of 2D cross-ply C/C composites with processing heat treatment temperature (HTT) are evaluated. C/C composites used are made from two types of PAN based T700 and M40 carbon fibers with phenolic resin as carbon matrix precursor. Both the types of composites are heat treated at different temperatures (ranging from 750 to $2800^{\circ}C$) and characterized for bending and tensile properties. It is observed that, real density and open porosity increases with HTT, however, bulk density does show remarkable change. The real density and open porosity are higher in case T-700 carbon fiber composites at $2800^{\circ}C$, even though the density of M40 carbon fiber is higher. Bending strength is considerably greater than tensile strength through out the processing HTT due to the different mode of fracture. The bending and tensile strength decreases in both composites on $1000^{\circ}C$ which attributed to decrease in bulk density, thereafter with increase in HTT, bending and tensile strength increases. The maximum strength is in T700 fiber based composites at HTT $1500^{\circ}C$ and in M40 fiber based composites at HTT $2500^{\circ}C$. After attending the maximum value of strength in both types of composite at deflection HTT, after that strength decreases continuously. Decrease in strength is due to the degradation of fiber properties and in-situ fiber damages in the composite. The maximum carbon fiber strength realization in C/C composites is possible at a temperature that is same of fiber HTT. It has been found first time that the bending strength more or less 1.55 times higher in T700 fiber composites and in M40 fiber composites bending strength is 1.2 times higher than that of tensile strength of C/C composites.

Preparation and characterization of carbon fiber-reinforced thermosetting composites: a review

Fan-Long Jin,Soo-Jin Park 한국탄소학회 2015 Carbon Letters Vol.16 No.2

Carbon fibers (CFs) have a unique combination of properties which allow them to be widely used as reinforcing materials in advanced polymer composites. The mechanical properties of CF-reinforced polymer composites are governed mainly by the quality of interfacial adhesion between the CFs and the polymer matrix. Surface treatments of CFs are generally carried out to introduce chemical functional groups on the fiber surfaces, which provide the ability to control the surface characteristics of CFs. In this study, we review recent experimental studies concerning various surface treatment methods for CFs. In addition, direct examples of the preparation and properties of CF-reinforced thermosetting composites are discussed.